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Ethylene thiourea

Product Name
Ethylene thiourea
CAS No.
96-45-7
Chemical Name
Ethylene thiourea
Synonyms
ETU;na-22;2-MERCAPTOIMIDAZOLINE;imidazolidine-2-thione;2-IMIDAZOLIDINETHIONE;ETHYLENETHIOUREA;2-Imidazolidinetione;ACCEL-BF;Mercaptoimidazoline;2-Imidazoline-2-thiol
CBNumber
CB8102852
Molecular Formula
C3H6N2S
Formula Weight
102.16
MOL File
96-45-7.mol
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Ethylene thiourea Property

Melting point:
196-200 °C(lit.)
Density 
1.41~1.45
vapor pressure 
<1 hPa (25 °C)
refractive index 
1.5500 (estimate)
Flash point:
252 °C
storage temp. 
Store below +30°C.
solubility 
8g/l
form 
Powder
pka
15.01±0.20(Predicted)
color 
White
Odor
wh. to pale green crystals, faint amine odor
Water Solubility 
19 g/L (20 ºC)
Merck 
14,3803
BRN 
106275
Boiling point:
240°C (1010 hPa)
InChIKey
PDQAZBWRQCGBEV-UHFFFAOYSA-N
LogP
-0.67 at 20℃
CAS DataBase Reference
96-45-7(CAS DataBase Reference)
NIST Chemistry Reference
2-Imidazolidinethione(96-45-7)
IARC
3 (Vol. Sup 7, 79) 2001
EPA Substance Registry System
Ethylene thiourea (96-45-7)
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Safety

Hazard Codes 
T
Risk Statements 
61-22-48/23/25-40
Safety Statements 
53-45
RIDADR 
2811
WGK Germany 
2
RTECS 
NI9625000
HazardClass 
6.1(b)
PackingGroup 
III
HS Code 
29332990
Hazardous Substances Data
96-45-7(Hazardous Substances Data)
Toxicity
LD50 orally in rats: 1832 mg/kg (Graham, Hansen)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
I504
Product name
2-Imidazolidinethione
Purity
98%
Packaging
1kg
Price
$212
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20696
Product name
2-Imidazolidinethione
Purity
for synthesis
Packaging
250g
Price
$57.5
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20696
Product name
2-Imidazolidinethione
Purity
for synthesis
Packaging
1kg
Price
$172
Updated
2024/03/01
Sigma-Aldrich
Product number
45531
Product name
2-Imidazolidinethione
Purity
PESTANAL , analytical standard
Packaging
250mg
Price
$49.3
Updated
2024/03/01
Sigma-Aldrich
Product number
03940
Product name
2-Imidazolidinethione
Purity
purum, ≥98.0% (HPLC)
Packaging
100g
Price
$127
Updated
2024/03/01
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Ethylene thiourea Chemical Properties,Usage,Production

Description

Ethylenethiourea, a thiourea derivative, is a rubber chemical. It has caused contact dermatitis mainly in rubber workers.

Chemical Properties

Ethylene thiourea is a white to light green, needle-like crystalline solid with a faint amine odor. It is very soluble in hot water;slightly soluble in cold water, methanol, ethanol, ethylene glycol, pyridine, acetic acid, and naphtha; and insoluble in acetone, ether, chloroform, and benzene.When heated to decomposition, ethylene thiourea emits toxic fumes of nitrogen oxides (NOx) and sulfur oxides (SOx).

Ethylene thiourea is available in the United States as crystals, as a powder, as an 80% dispersion of the powder in oil, or encapsulated in a matrix of compatible elastomers.

Uses

2-Imidazolidinethione is a pesticide used in production of fruits and vegetables. It is also used as a new contrast agent for MRI studies based on proton chemical exchange dependent saturation transfe r. 2-Imidazolidinethione is also a corrosion inhibitor due to the adsorption of the mol. species.

Uses

elastomer accelerator;chlorinated polyethylene (CPE) rubber vulcanizing accelerator agent.
Ethylene thiourea is used primarily as an accelerator for vulcanizing polychloroprene (Neoprene®) and polyacrylate rubbers. Neoprene rubbers are used almost exclusively in industrial applications,e.g.. for mechanical and automotive products, in wire and cable production, in construction,and in adhesives. Polyacrylate rubbers are used in products such as seals, o-rings, and gaskets for automotive and aircraft applications. Ethylene thiourea is used in the manufacture of ethylene-bisdithiocarbamate pesticides, such as Maneb®, Mancozeb®, Metiram®,and Zineb®.Ethylene thiourea is also used in electroplating baths, as an intermediate in antioxidant production, in dyes, pharmaceuticals,and synthetic resins. However, there is no evidence that the compound is used commercially for any of these purposes (IARC V.7, 1974; Sax, 1987).

Uses

Accelerator in the curing of polychloroprene (neoprene) and polyacrylate rubber; intermediate in the manufacture of antioxidants, insecticides, fungicides, dyes, pharmaceuticals, and synthetic resins

Definition

ChEBI: Ethylenethiourea is a member of imidazolidines.

General Description

White to pale green crystals or an off-white solid. Odorless when pure, but technical product may have an amine odor.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

Ethlenethiourea may be sensitive to prolonged exposure to light. Incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. May react with acids to liberate hydrogen sulfide.

Hazard

Questionable carcinogen.

Health Hazard

Ethylene thiourea (ETU) is an antithyroid substance and animal carcinogen.

Fire Hazard

Ethylene thiourea is combustible.

Flammability and Explosibility

Non flammable

Contact allergens

Ethylene thiourea, a thiourea derivative, is a rubber chemical. It caused contact dermatitis mainly in rubber workers.

Potential Exposure

Ethylene thiourea is used extensively as an accelerator in the curing of polychloroprene (Neoprene) and other elastomers; as a vulcanizing accelerator in rubber processing; in electroplating baths. In addition, exposure to ethylene thiourea also results from the very widely used ethylene bisdithiocarbamate fungicides. Ethylene thiourea may be present as a contaminant in the ethylene bisdithiocarbamate fungicides and can also be formed when food containing the fungicides is cooked

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 24- 48 h after breathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor orauthorized paramedic may consider administering a corticosteroid spray.

Carcinogenicity

Ethylene thiourea is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

storage

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, well-ventilated area away from strong oxidizers, acids, acidanhydrides, acrolein. Store in a refrigerator or a cool, dryplace. A regulated, marked area should be establishedwhere this chemical is handled, used, or stored in compliance with OSHA Standard 1910.1045.

Shipping

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

Purification Methods

Crystallise it from EtOH or amyl alcohol. [Beilstein 24 III/IV 22.]

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, acid anhydrides, and acrolein

Waste Disposal

Incineration in a furnace equipped with afterburner and scrubber.

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Ethylene thiourea Suppliers

Wuhan yalong new materials co. LTD
Tel
027-86643577 15377507605
Fax
027-86643577
Email
1057540201@qq.com
Country
China
ProdList
136
Advantage
58
Hubei zhonglong Kangsheng Fine Chemical Co., Ltd
Tel
027-027-83850178 18162590268
Fax
027-83850178
Email
1984393783@qq.com
Country
China
ProdList
3722
Advantage
58
Greenspring Biotechnology (Jiangsu) Co., Ltd.
Tel
0523-87726088 13705266400
Fax
0523-87653988
Email
sun1@sunmy.com
Country
China
ProdList
116
Advantage
58
Shanghai klamar Reagent Co., LTD
Tel
4001650900 13817534909
Email
3003940895@qq.com
Country
China
ProdList
10721
Advantage
58
Hubei Shinader new materials Co., Ltd.
Tel
13667241402
Email
shinader@163.com
Country
China
ProdList
36
Advantage
58
Wuhan Silworld Chemical Co.,Ltd
Tel
027-85613400 15827173649
Fax
027-85613419
Email
info@silworldchemical.com
Country
China
ProdList
325
Advantage
58
Wuhan EnTai Technology Development Co,.Ltd
Tel
86-27-82330560
Fax
86-27-82330547
Email
2536851935@qq.com
Country
China
ProdList
347
Advantage
69
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
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View Lastest Price from Ethylene thiourea manufacturers

HebeiShuoshengImportandExportco.,Ltd
Product
Ethylene thiourea 96-45-7
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-12
Asia Chem I and E (Jiangsu) Co Ltd
Product
2-Imidazolidinethione (Ethlenethiourea) 96-45-7
Price
US $20.93/Kg/Drum
Min. Order
25Kg/Drum
Purity
99.50%HPLC
Supply Ability
10tons/month
Release date
2021-09-23
Hebei Longbang Technology Co., Ltd
Product
Ethylene thiourea 96-45-7
Price
US $5.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-13

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