ChemicalBook > CAS DataBase List > (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
Reactions- Product Name
- (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
- CAS No.
- 442905-33-1
- Chemical Name
- (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
- Synonyms
- (R)-Xyl-P-Phos;(S)-XYLYL-P-PHOS;(R)-XYLYL-P-PHOS;CTH-(S)-XYLYL-P-PHOS;CTH-(R)-XYLYL-P-PHOS;min.cth-(r)-xylyl-p-phos;(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS&;(R)-(+)-2,2'',6,6''-Tetramethoxy-4,4''-bis(di(3,5-xylyl)phosphi;(S)-(-)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE;(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
- CBNumber
- CB8116202
- Molecular Formula
- C46H50N2O4P2
- Formula Weight
- 756.85
- MOL File
- 442905-33-1.mol
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(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Property
- Melting point:
- 190-194°C
- Boiling point:
- 791.1±60.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- -1.76±0.38(Predicted)
- form
- Powder
- color
- white to pale yellow
- optical activity
- [α]20/D +125°, c = 1 in chloroform
- Water Solubility
- Sparingly soluble in water.
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-36
- WGK Germany
- 3
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 676004
- Product name
- (R)-(+)-2,2′,6,6′-Tetramethoxy-4,4′-bis(di(3,5-xylyl)phosphino)-3,3′-bipyridine
- Purity
- 97%
- Packaging
- 100mg
- Price
- $101
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 676004
- Product name
- (R)-(+)-2,2′,6,6′-Tetramethoxy-4,4′-bis(di(3,5-xylyl)phosphino)-3,3′-bipyridine
- Purity
- 97%
- Packaging
- 500mg
- Price
- $408
- Updated
- 2023/06/20
Alfa Aesar
- Product number
- 044613
- Product name
- (R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine
- Packaging
- 0.1g
- Price
- $73.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 044613
- Product name
- (R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine
- Packaging
- 0.5g
- Price
- $243.65
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-5210
- Product name
- (R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine, min. 97% CTH-(R)-Xylyl-P-PHOS
- Packaging
- 100mg
- Price
- $74
- Updated
- 2024/03/01
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(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Chemical Properties,Usage,Production
Reactions
- Chiral ligand for ruthenium- catalyzed asymmetric hydrogenation of aromatic ketones.
- Chiral ligand for iridium-catalyzed asymmetric hydrogenation of quinolines.
- Chiral ligand for copper- catalyzed asymmetric hydrosilylation of ketones.
- Synthesis of new chiral 2-functionized-1,2,3,4-tetrahydroquinoline derivatives via asymmetric hydrogenation of substituted quinolines.
- Rhodium-biphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives.
Chemical Properties
White solid
Uses
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine is used in asymmetric hydrogenation.It acts as a ligand used in the asymmetic hydrogenation of β-keto esters, 2-arylacrylates, aryl ketones , and other substrates. Other applications include it is used widely as a Catalyst, when combined with Rh, Ru and Ir precursor.
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Preparation Products And Raw materials
Raw materials
Preparation Products
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(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE Suppliers
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- .international@thermofisher.com
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- United Kingdom
- ProdList
- 2932
- Advantage
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- United Kingdom
- ProdList
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442905-33-1, (R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINERelated Search:
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
2-HYDROXY-6-METHOXYPYRIDINE
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DIPHENYLPHOSPHINO)-3,3'-BIPYRIDINE
2,6-Dimethoxypyridine
(R)-(+)-2,2',6,6'-TETRAMETHOXY-4,4'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3'-BIPYRIDINE
(R)-XYL-P-PHOS RUTHENIUMCL2 (R,R)-DPEN
[3,3']BIPYRIDINYL