ChemicalBook > CAS DataBase List > (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS
Reaction- Product Name
- (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS
- CAS No.
- 850253-53-1
- Chemical Name
- (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS
- Synonyms
- (R)-DM-SEGPHOS;(R)-DM-SEGPHOS(R);(R)-DM-SEGPHOS®(R)-(+)-DM-SEGPHOS(regR);(R)-(+)-DM-SEGPHOS®(R)-(3,5-xylyl)2PC7H4O2C7H4O2P(3,5-xylyl)2;(R)-(+)-DM-SEGPHOS(regR) (R)-(+)-DM-SEGPHOS;(R)-(+)-DM-SEGPHOS(regR)(R)-(+)-DM-SEGPHOS(regR);(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole;(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole
- CBNumber
- CB81180983
- Molecular Formula
- C46H44O4P2
- Formula Weight
- 722.8
- MOL File
- 850253-53-1.mol
More
Less
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS Property
- Melting point:
- 256-261 °C
- Boiling point:
- 816.9±65.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- off white to pale yellow
- optical activity
- [α]20/D +60, c = 0.1 in chloroform
More
Less
Safety
- WGK Germany
- 3
- HS Code
- 2932.99.7000
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 692476
- Product name
- (R)-DM-SEGPHOS?
- Packaging
- 100mg
- Price
- $34.32
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D4499
- Product name
- (R)-(+)-DM-SEGPHOS[R]
- Purity
- >95.0%(HPLC)
- Packaging
- 200mg
- Price
- $69
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D4499
- Product name
- (R)-(+)-DM-SEGPHOS[R]
- Purity
- >95.0%(HPLC)
- Packaging
- 1g
- Price
- $195
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0478
- Product name
- (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-DM-SEGPHOS(R)
- Packaging
- 250mg
- Price
- $48
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0478
- Product name
- (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-DM-SEGPHOS(R)
- Packaging
- 1g
- Price
- $142
- Updated
- 2024/03/01
More
Less
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS Chemical Properties,Usage,Production
Reaction
- Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
- Copper catalyzed enantioselective [3 + 2] cycloaddition as a route to γ–amino ketones and 3-pyrrolidinones.
- Palladium catalyzed enantioselective addition of malonates to dihydroisoquinolines.
- Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
- Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. See 44-0098 for Ru catalyst.
- Diastereoand enantioselective ruthenium-catalyzed hydrohydroxyalkylation of 2-silyl-butadienes.
- Asymmetric [2+2+2] cycloaddition.
- Linear selective C-H activation.
Uses
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS Suppliers
- Tel
- --
- Fax
- --
- nfo@alkemi.be
- Country
- Belgium
- ProdList
- 2201
- Advantage
- 58
More
Less
View Lastest Price from (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS manufacturers
XINXIANG RUNYU MATERIAL CO., LTD.
- Product
- (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS 850253-53-1
- Price
- US $0.00-0.00/g
- Min. Order
- 1g
- Purity
- 98%
- Supply Ability
- 1500g
- Release date
- 2024-03-07
Career Henan Chemical Co
- Product
- (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS 850253-53-1
- Price
- US $7.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2020-01-13
850253-53-1, (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOSRelated Search:
(R)-DTBM-SEGPHOS
(S)-(-)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DM-SEGPHOS
(R)-SEGPHOS
N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2
Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP
(S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS
(S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS