(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS

ChemicalBook > CAS DataBase List > (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS

(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS

Reaction

Product Name: (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS
CAS No.: 850253-53-1
Chemical Name: (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS
Synonyms: (R)-DM-SEGPHOS;(R)-DM-SEGPHOS(R);(R)-DM-SEGPHOS®(R)-(+)-DM-SEGPHOS(regR);(R)-(+)-DM-SEGPHOS®(R)-(3,5-xylyl)2PC7H4O2C7H4O2P(3,5-xylyl)2;(R)-(+)-DM-SEGPHOS(regR) (R)-(+)-DM-SEGPHOS;(R)-(+)-DM-SEGPHOS(regR)(R)-(+)-DM-SEGPHOS(regR);(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole;5,5'-bis(bis(3,5-dimethylphenyl)phosphino)-4,4'-bibenzo[d][1,3]dioxole
CBNumber: CB81180983
Molecular Formula: C46H44O4P2
Formula Weight: 722.8
MOL File: 850253-53-1.mol

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(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS Property

Melting point:: 256-261 °C
Boiling point:: 816.9±65.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
color: off white to pale yellow
optical activity: [α]20/D +60, c = 0.1 in chloroform

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Safety

WGK Germany: 3
HS Code: 2932.99.7000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692476
Product name: (R)-DM-SEGPHOS?
Packaging: 100mg
Price: $34.32
Updated: 2024/03/01

TCI Chemical

Product number: D4499
Product name: (R)-(+)-DM-SEGPHOS[R]
Purity: >95.0%(HPLC)
Packaging: 200mg
Price: $69
Updated: 2024/03/01

TCI Chemical

Product number: D4499
Product name: (R)-(+)-DM-SEGPHOS[R]
Purity: >95.0%(HPLC)
Packaging: 1g
Price: $195
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0478
Product name: (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-DM-SEGPHOS(R)
Packaging: 250mg
Price: $48
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0478
Product name: (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-DM-SEGPHOS(R)
Packaging: 1g
Price: $142
Updated: 2024/03/01

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(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS Chemical Properties,Usage,Production

Reaction

Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
Copper catalyzed enantioselective [3 + 2] cycloaddition as a route to γ–amino ketones and 3-pyrrolidinones.
Palladium catalyzed enantioselective addition of malonates to dihydroisoquinolines.
Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone. See 44-0098 for Ru catalyst.
Diastereoand enantioselective ruthenium-catalyzed hydrohydroxyalkylation of 2-silyl-butadienes.
Asymmetric [2+2+2] cycloaddition.
Linear selective C-H activation.

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS Suppliers

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View Lastest Price from (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.

Product: (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS 850253-53-1
Price: US $0.00-0.00/g
Min. Order: 1g
Purity: 98%
Supply Ability: 1500g
Release date: 2024-03-07

Career Henan Chemical Co

Product: (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS 850253-53-1
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000kg
Release date: 2020-01-13

850253-53-1, (R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOSRelated Search:

(R)-DTBM-SEGPHOS (S)-(-)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DM-SEGPHOS (R)-SEGPHOS N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-Methylbenzyloxy)ethylaMino)-ethyl]-4-Methylbenzene sulfonaMide(chloro)rutheniuM(II) (R,R)-Ts-DENEB 1333981-84-2 Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl} [(2R)-(-)-1-(4-Methoxyphenyl)- 1 (4-Methoxyphenyl-kC)-3- Methyl-1,2-butanediaMine]rutheniuM(II) (R)-RUCY XylBINAP (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS

(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(R)-DM-SEGPHOS

(R)-DM-SEGPHOS(R)

(R)-(+)-DM-SEGPHOS(regR)

(<i>R</i>)-(+)-DM-SEGPHOS<sup>&reg

(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole, min. 98% (R)-(+)-DM-SEGPHOS(R)

1,1'-[(4R)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-bis(3,5-dimethylphenyl)phosphine]

(R)-DM-SEGPHOS

(R)-(+)-DM-SEGPHOS(regR) (R)-(+)-DM-SEGPHOS

(R)-(3,5-xylyl)2PC7H4O2C7H4O2P(3,5-xylyl)2

Phosphine,1,1'-(4R)-[4,4'-bi-1,3-benzodioxole]-5,5'-diylbis[1,1-bis(3,5-dimethylphenyl)-

(R)-(+)-4,4'-Bis[di(3,5-xylyl)phosphino]-3,3'-bi(1,2-methylenedioxybenzene)

(R)-(+)-DM-SEGPHOS(regR)(R)-(+)-DM-SEGPHOS(regR)

5,5'-bis(bis(3,5-dimethylphenyl)phosphino)-4,4'-bibenzo[d][1,3]dioxole

(R)-DM-SEGPHOS&reg

(R)-(+)-5,5'-Bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole

1,1'-[(4R)-[4,4'-Bi-1,3-benzodioxole]-5,5'-diyl]bis[1,1-bis(3,5-dimethylphenyl)phosphine

850253-53-1