Reaction
ChemicalBook > CAS DataBase List > (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

Reaction
Product Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
CAS No.
284472-79-3
Chemical Name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Synonyms
95%,ee99%;(S)-PipPhos;97% (S)-PipPhos;3,4-a']dinaphthalen-4-yl)piperidine,(S)-PipPhos;3,4-a']dinaphthalen-4-yl)piperidine,97% (S)-PipPhos;3,4-a']dinaphthalen-4-yl)piperidine,min.97%(S)-PipPhos;-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl);1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine;1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine;(S)-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)piperidine
CBNumber
CB81180998
Molecular Formula
C25H22NO2P
Formula Weight
399.43
MOL File
284472-79-3.mol
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Property

Melting point:
206-213 °C
Boiling point:
597.5±33.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
1.67±0.20(Predicted)
form 
Powder
color 
white
Sensitive 
moisture sensitive
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-1234
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
Packaging
100mg
Price
$42
Updated
2024/03/01
Strem Chemicals
Product number
15-1234
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
Packaging
500mg
Price
$168
Updated
2024/03/01
Strem Chemicals
Product number
15-1234
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
Packaging
2g
Price
$504
Updated
2024/03/01
Matrix Scientific
Product number
094615
Product name
1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine
Purity
95+%
Packaging
1g
Price
$756
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0001798
Product name
(S)-PIPPHOS
Purity
95.00%
Packaging
1G
Price
$780.15
Updated
2021/12/16
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties,Usage,Production

Reaction

  1. Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
  2. Ligand used in asymmetric hydrogenation of 2-substituted N-protected indoles using Rhodium-based catalysts. 

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Suppliers

Accela ChemBio Inc.
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+1-858-6993322
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Aladdin Scientific
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Riedel-de Haen AG
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Strem Chemicals, Inc.
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Matrix Scientific
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International Laboratory Limited
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admin@intlab.org
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284472-79-3, (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-aRelated Search:


  • (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
  • 97% (S)-PipPhos
  • 1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine
  • (S)-PipPhos
  • 1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-piperidine
  • (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine 97%
  • -1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)
  • 1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin- 4-ylpiperidine,99%e.e.
  • 3,4-a']dinaphthalen-4-yl)piperidine,(S)-PipPhos
  • (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine ((S)-PipPhos)
  • 3,4-a']dinaphthalen-4-yl)piperidine,min.97%(S)-PipPhos
  • (S)-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)piperidine
  • Piperidine,1-(11bS)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-
  • 1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylpiperidine
  • (S)-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)piperidine
  • (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)piperidine
  • 1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine
  • 95%,ee99%
  • 3,4-a']dinaphthalen-4-yl)piperidine,97% (S)-PipPhos
  • 284472-79-3
  • Chiral Phosphine
  • CPN