ChemicalBook > CAS DataBase List > (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Reaction- Product Name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
- CAS No.
- 284472-79-3
- Chemical Name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
- Synonyms
- 95%,ee99%;(S)-PipPhos;97% (S)-PipPhos;3,4-a']dinaphthalen-4-yl)piperidine,(S)-PipPhos;3,4-a']dinaphthalen-4-yl)piperidine,97% (S)-PipPhos;3,4-a']dinaphthalen-4-yl)piperidine,min.97%(S)-PipPhos;-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl);1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine;1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine;(S)-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)piperidine
- CBNumber
- CB81180998
- Molecular Formula
- C25H22NO2P
- Formula Weight
- 399.43
- MOL File
- 284472-79-3.mol
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Property
- Melting point:
- 206-213 °C
- Boiling point:
- 597.5±33.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 1.67±0.20(Predicted)
- form
- Powder
- color
- white
- Sensitive
- moisture sensitive
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
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N-Bromosuccinimide Price
Strem Chemicals
- Product number
- 15-1234
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
- Packaging
- 100mg
- Price
- $42
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1234
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
- Packaging
- 500mg
- Price
- $168
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1234
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos
- Packaging
- 2g
- Price
- $504
- Updated
- 2024/03/01
Matrix Scientific
- Product number
- 094615
- Product name
- 1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine
- Purity
- 95+%
- Packaging
- 1g
- Price
- $756
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CCH0001798
- Product name
- (S)-PIPPHOS
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $780.15
- Updated
- 2021/12/16
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties,Usage,Production
Reaction
- Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
- Ligand used in asymmetric hydrogenation of 2-substituted N-protected indoles using Rhodium-based catalysts.
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials
Raw materials
Preparation Products
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Suppliers
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284472-79-3, (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-aRelated Search:
(R)-MONOPHOS
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)[(1R)-1-PHENYLETHYL]AMINE
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(R)-MONOPHOS
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a