4-Isopropoxylphenylboronic acid

Product Name: 4-Isopropoxylphenylboronic acid
CAS No.: 153624-46-5
Chemical Name: 4-Isopropoxylphenylboronic acid
Synonyms: FS000901;AKOS BRN-0675;542474_ALDRICH;CHEMBRDG-BB 4009733;4-Isopropoxyphenylboronic;1-Borono-4-isopropoxybenzene;4-Isopropoxyphenylboronic aci;4-Isopropoxylphenylboronicaci;P-ISOPROPOXYPHENYLBORONIC ACID;4-ISOPROPOXYPHENYLBORONIC ACID
CBNumber: CB8129493
Molecular Formula: C9H13BO3
Formula Weight: 180.01
MOL File: 153624-46-5.mol

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4-Isopropoxylphenylboronic acid Property

Melting point:: 150-154°C
Boiling point:: 321.9±44.0 °C(Predicted)
Density: 1.10±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: DMSO (Slightly), Methanol (Slightly)
pka: 8.78±0.17(Predicted)
form: Powder
color: White to off-white or light tan
InChI: 1S/C9H13BO3/c1-7(2)13-9-5-3-8(4-6-9)10(11)12/h3-7,11-12H,1-2H3
InChIKey: CJUHQADBFQRIMC-UHFFFAOYSA-N
SMILES: CC(C)Oc1ccc(cc1)B(O)O
CAS DataBase Reference: 153624-46-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/37/39-36-24/25
WGK Germany: 3
HazardClass: IRRITANT
HS Code: 29319090
Storage Class: 13 - Non Combustible Solids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: I0806
Product name: 4-Isopropoxyphenylboronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $208
Updated: 2024/03/01

Usbiological

Product number: 280704
Product name: 4-Isopropoxyphenylboronic acid
Packaging: 25g
Price: $388
Updated: 2021/12/16

TRC

Product number: I823420
Product name: 4-Isopropoxyphenylboronic acid
Packaging: 100g
Price: $450
Updated: 2021/12/16

Synthonix

Product number: I3909
Product name: 4-Isopropoxyphenylboronic acid
Purity: 98%
Packaging: 1g
Price: $5
Updated: 2021/12/16

Oakwood

Product number: 045291
Product name: 4-Isopropoxyphenylboronic acid
Purity: 97%
Packaging: 5g
Price: $15
Updated: 2021/12/16

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4-Isopropoxylphenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

White to off-white or light tan powder

Uses

Reactant for:• ;Microwave-mediated click-chemistry synthesis of glyco-porphyrin derivatives with in vitro photo-cytotoxicity for application in photodynamic therapy1• ;Palladium-catalyzed oxidative cross-coupling reactions2• ;Ruthenium-catalyzed hydrogenation reactions3• ;Stereoselective rhodium-catalyzed arylation4• ;Palladium acetate catalyzed C-glycosidation5

Uses

suzuki reaction

Uses

4-Isopropoxyphenylboronic Acid is used to synthesize potent cytotoxic analogues of the marine alkaloid Lamellarin D. It is also used to synthesize cyclooxygenase-2 (COX-2) inhibitors.

General Description

Contains varying amounts of anhydride

Synthesis

A pentane solution of tert-butyllithium (1.28 M, 51.5 mL, 66.0 mmol) was added dropwise to a solution of 4-isopropoxybromobenzene (5.61 g) in THF (150 ) at -78 C under an argon atmosphere. mL) to a solution of 4-isopropoxybromobenzene (5.61 g) in THF (150 ). The mixture was stirred for 1 hour. Trimethyl borate (5.02 mL, 45.0 mmol) was was added to the mixture as a pure liquid. Stir the mixture at -78 C for 1 hour. Allow the reaction mixture to warm to room temperature. Stir the reaction mixture for another 1 hour. Quench the mixture with saturated NH4Cl Quench the mixture with saturated NH4Cl aqueous solution. Evaporate the mixture under reduced pressure. Adjust the pH of the residue to 3 by adding 3 M aqueous HCl. Extract the mixture with dichloromethane. Wash the extract with brine. Dry the extract with Na2SO4. Na2SO4 to dry the extract. Evaporate the extract under reduced pressure. The residual solid was washed with hexane. Filter the solid to obtain 4-isopropoxyphenylboronic acid.

4-Isopropoxylphenylboronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Isopropoxylphenylboronic acid Suppliers

Americas 1 China 157 Europe 4 France 1 Germany 6 India 6 Japan 3 Russia 1 Switzerland 1 Ukraine 1 United Kingdom 12 United States 41 Global 234

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View Lastest Price from 4-Isopropoxylphenylboronic acid manufacturers

HebeiShuoshengImportandExportco.,Ltd

Product: 4-Isopropoxylphenylboronic acid 153624-46-5
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-02

Hebei Longbang Technology Co., Ltd

Product: 4-Isopropoxylphenylboronic acid 153624-46-5
Price: US $6.00/kg
Min. Order: 1kg
Purity: More than 99%
Supply Ability: 2000KG/Month
Release date: 2024-05-23

Hebei Jingbo New Material Technology Co., Ltd

Product: 4-Isopropoxylphenylboronic acid 153624-46-5
Price: US $8.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 200000
Release date: 2023-12-27

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AKOS BRN-0675

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4-Isopropoxyphenylboronic Acid (contains varying aMounts of Anhydride)

1-Borono-4-isopropoxybenzene

[4-(propan-2-yloxy)phenyl]boronic acid

4-Isopropoxyphenylboronic Acid&nbsp

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4-ISOPROPOXYPHENOL BORONIC ACID

Boronic acid, B-[4-(1-methylethoxy)phenyl]-

4-Isopropoxylphenylboronicaci

4-Isopropoxyphenylboronic acid - [I3909]

153624-46-5

C6H4OCHCH32BOH2

BORONIC ACID

Potassium Trifluoroborate

Boronate Ester

Aryl Boronic Acids

Boronic Acids and Derivatives

Chemical Synthesis

Monosubstituted Aryl Boronic Acids

Organometallic Reagents

Boronic Acid series

blocks

BoronicAcids

Boronic acid

Boronic Acids

Boronic Acids and Derivatives

Alkoxy

Aryl

Organoborons

Boronic acids