Titanium tetraisopropanolate
Reactions- Product Name
- Titanium tetraisopropanolate
- CAS No.
- 546-68-9
- Chemical Name
- Titanium tetraisopropanolate
- Synonyms
- TITANIUM ISOPROPOXIDE;TITANIUM(IV) ISOPROPOXIDE;TITANIUM TETRAISOPROPOXIDE;TTIP;tetraisopropoxytitanium;TETRAISOPROPYL TITANATE;ISOPROPYL TITANATE;Titanium(Ⅳ) isopropoxide;TETRAISOPROPYL ORTHOTITANATE;TITANIUM(IV) TETRAISOPROPOXIDE
- CBNumber
- CB3363214
- Molecular Formula
- C12H28O4Ti
- Formula Weight
- 284.22
- MOL File
- 546-68-9.mol
Titanium tetraisopropanolate Property
- Melting point:
- 14-17 °C(lit.)
- Boiling point:
- 232 °C(lit.)
- Density
- 0.96 g/mL at 20 °C(lit.)
- vapor pressure
- 60.2hPa at 25℃
- refractive index
- n20/D 1.464(lit.)
- Flash point:
- 72 °F
- storage temp.
- Flammables area
- solubility
- Soluble in anhydrous ethanol, ether, benzene and chloroform.
- form
- Liquid
- color
- Colorless to pale yellow
- Specific Gravity
- 0.955
- Water Solubility
- HYDROLYSIS
- FreezingPoint
- 14.8℃
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Merck
- 14,9480
- BRN
- 3679474
- Stability:
- Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.
- InChIKey
- VXUYXOFXAQZZMF-UHFFFAOYSA-N
- LogP
- 0.05
- CAS DataBase Reference
- 546-68-9(CAS DataBase Reference)
- EPA Substance Registry System
- 2-Propanol, titanium(4+) salt (546-68-9)
Safety
- Hazard Codes
- Xi,F
- Risk Statements
- 10-36-36/37/38-11-67
- Safety Statements
- 16-26-36/37/39-7/9
- RIDADR
- UN 2413 3/PG 3
- WGK Germany
- 2
- RTECS
- NT8060000
- F
- 21
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- III
- HS Code
- 29051900
- Hazardous Substances Data
- 546-68-9(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H319Causes serious eye irritation
H336May cause drowsiness or dizziness
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P241Use explosion-proof electrical/ventilating/lighting/…/equipment.
P242Use only non-sparking tools.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 205273
- Product name
- Titanium(IV) isopropoxide
- Purity
- 97%
- Packaging
- 1l
- Price
- $145
- Updated
- 2024/03/01
- Product number
- 205273
- Product name
- Titanium(IV) isopropoxide
- Purity
- 97%
- Packaging
- 2l
- Price
- $263
- Updated
- 2024/03/01
- Product number
- T0133
- Product name
- Tetraisopropyl Orthotitanate
- Packaging
- 25g
- Price
- $17
- Updated
- 2024/03/01
- Product number
- T0133
- Product name
- Tetraisopropyl Orthotitanate
- Packaging
- 500g
- Price
- $49
- Updated
- 2024/03/01
- Product number
- 077115
- Product name
- Titanium(IV) isopropoxide, 97+%
- Packaging
- 10g
- Price
- $31.65
- Updated
- 2024/03/01
Titanium tetraisopropanolate Chemical Properties,Usage,Production
Reactions
- Catalyst for the synthesis of acyclic epoxy alcohols and allylic epoxy alcohols.
- Useful for diastereoselective reduction of alpha-fluoroketones.
- Catalyzes the asymmetric allylation of ketones.
- Reagent for the synthesis of cyclopropylamines from aryl and alkenyl nitriles.
- Useful for racemic and/or enantioselective addition of nucleophiles to aldehydes, ketones and imines.
- Catalytic intramolecular formal [3+2] cycloaddition.
- Catalyst for the synthesis of cyclopropanols from esters and organomagnesium reagents
Chemical Properties
colourless to light yellow liquid
Uses
Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.
Uses
Titanium(IV) isopropoxide is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films. It is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes. It is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides. In Kulinkovich reaction, it is involved as a catalyst in the preparation of cyclopropanes.
Definition
ChEBI: Titanium(IV) isopropoxide is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.
General Description
Tetraisopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water. Vapors heavier than air.
Air & Water Reactions
Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.
Reactivity Profile
Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.
Health Hazard
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Flammability and Explosibility
Flammable
Purification Methods
Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]
Titanium tetraisopropanolate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Titanium tetraisopropanolate manufacturers
- Product
- Titanium(IV) isopropoxide 546-68-9
- Price
- US $3200.00/T
- Min. Order
- 1T
- Purity
- 99%
- Supply Ability
- 600T
- Release date
- 2020-11-09
- Product
- Titanium tetraisopropanolate 546-68-9
- Price
- US $50.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-22
- Product
- Titanium tetraisopropanolate 546-68-9
- Price
- US $50.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10000
- Release date
- 2023-11-01