Titanium tetraisopropanolate

Reactions

Product Name: Titanium tetraisopropanolate
CAS No.: 546-68-9
Chemical Name: Titanium tetraisopropanolate
Synonyms: TITANIUM ISOPROPOXIDE;TITANIUM(IV) ISOPROPOXIDE;TITANIUM TETRAISOPROPOXIDE;TTIP;tetraisopropoxytitanium;TETRAISOPROPYL TITANATE;ISOPROPYL TITANATE;Titanium(Ⅳ) isopropoxide;TETRAISOPROPYL ORTHOTITANATE;TITANIUM(IV) TETRAISOPROPOXIDE
CBNumber: CB3363214
Molecular Formula: C12H28O4Ti
Formula Weight: 284.22
MOL File: 546-68-9.mol

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Titanium tetraisopropanolate Property

Melting point:: 14-17 °C(lit.)
Boiling point:: 232 °C(lit.)
Density: 0.96 g/mL at 20 °C(lit.)
vapor pressure: 60.2hPa at 25℃
refractive index: n20/D 1.464(lit.)
Flash point:: 72 °F
storage temp.: Flammables area
solubility: Soluble in anhydrous ethanol, ether, benzene and chloroform.
form: Liquid
Specific Gravity: 0.955
color: Colorless to pale yellow
Water Solubility: HYDROLYSIS
FreezingPoint: 14.8℃
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Merck: 14,9480
BRN: 3679474
Stability:: Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.
InChIKey: VXUYXOFXAQZZMF-UHFFFAOYSA-N
LogP: 0.05
CAS DataBase Reference: 546-68-9(CAS DataBase Reference)
EPA Substance Registry System: 2-Propanol, titanium(4+) salt (546-68-9)

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Safety

Hazard Codes: Xi,F
Risk Statements: 10-36-36/37/38-11-67
Safety Statements: 16-26-36/37/39-7/9
RIDADR: UN 2413 3/PG 3
WGK Germany: 2
RTECS: NT8060000
F: 21
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29051900
Hazardous Substances Data: 546-68-9(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H319Causes serious eye irritation

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 205273
Product name: Titanium(IV) isopropoxide
Purity: 97%
Packaging: 1l
Price: $145
Updated: 2024/03/01

Sigma-Aldrich

Product number: 205273
Product name: Titanium(IV) isopropoxide
Purity: 97%
Packaging: 2l
Price: $263
Updated: 2024/03/01

TCI Chemical

Product number: T0133
Product name: Tetraisopropyl Orthotitanate
Packaging: 25g
Price: $17
Updated: 2024/03/01

TCI Chemical

Product number: T0133
Product name: Tetraisopropyl Orthotitanate
Packaging: 500g
Price: $49
Updated: 2024/03/01

Alfa Aesar

Product number: 077115
Product name: Titanium(IV) isopropoxide, 97+%
Packaging: 10g
Price: $31.65
Updated: 2024/03/01

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Titanium tetraisopropanolate Chemical Properties,Usage,Production

Reactions

Catalyst for the synthesis of acyclic epoxy alcohols and allylic epoxy alcohols.
Useful for diastereoselective reduction of alpha-fluoroketones.
Catalyzes the asymmetric allylation of ketones.
Reagent for the synthesis of cyclopropylamines from aryl and alkenyl nitriles.
Useful for racemic and/or enantioselective addition of nucleophiles to aldehydes, ketones and imines.
Catalytic intramolecular formal [3+2] cycloaddition.
Catalyst for the synthesis of cyclopropanols from esters and organomagnesium reagents

Chemical Properties

colourless to light yellow liquid

Uses

Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.

Uses

Titanium(IV) isopropoxide is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films. It is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes. It is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides. In Kulinkovich reaction, it is involved as a catalyst in the preparation of cyclopropanes.

Definition

ChEBI: Titanium(IV) isopropoxide is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.

General Description

Tetraisopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.

Reactivity Profile

Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Flammability and Explosibility

Flammable

Purification Methods

Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]

Titanium tetraisopropanolate Preparation Products And Raw materials

Raw materials

(S)-tert-Butyl 6-amino-2-((tert-butoxycarbonyl)amino)hexanoate hydrochloride Toluene Titanium tetrachloride Isopropyl alcohol

Preparation Products

3-PHENOXYBENZALDEHYDE CYANOHYDRIN 2,3-DIHYDROXYPROPYL METHACRYLATE 6-FLUORO-1H-PYRAZOLO[3,4-B]PYRIDINE-3-CARBONITRILE 6-FLUORO-1H-PYRAZOLO[3,4-B]PYRIDINE-3-CARBOXYLIC ACID Ti(BINOL)complex (+)-DISPARLURE

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Titanium tetraisopropanolate Suppliers

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View Lastest Price from Titanium tetraisopropanolate manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: Titanium tetraisopropanolate 546-68-9
Price: US $50.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10000
Release date: 2023-11-01

Hebei Weibang Biotechnology Co., Ltd

Product: Titanium tetraisopropanolate 546-68-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-24

Hebei Chuanghai Biotechnology Co,.LTD

Product: Tetra Isopropyl Titanate 546-68-9
Price: US $19.00/KG
Min. Order: 1KG
Purity: 99.%
Supply Ability: 10 ton
Release date: 2024-08-15

546-68-9, Titanium tetraisopropanolateRelated Search:

TITANIUM ISOBUTOXIDE Rutile Chloromethyl isopropyl carbonate TITANIUM Isopropyl palmitate Isopropyl salicylate Isopropyl isocyanate Diisopropyl azodicarboxylate Isopropyl myristate Isopropyl acetate Tetrabutyl titanate (R)-Glycidyl butyrate Titanium ethoxide Tazobactam Diphenylmethyl Ester Titanium propoxide Titanium ethylhexoxide Titanium tetrachloride Diethyl carbonate

ISOPROPYL TITANATE

ISOPROPYL TITANATE(IV)

TITANIUM ISOPROPOXIDE

TITANIUM ISO-PROPYLATE

TITANIUM (IV) I-PROPOXIDE

TITANIUM(IV) ISOPROPOXIDE

TITANIUM (IV) TETRA-I-PROPOXIDE

TITANIUM(IV) TETRAISOPROPOXIDE

Titanium tetraisopropanolate

TITANIUM TETRAISOPROPOXIDE

TITANIUM TETRAISOPROPYLATE

TITANIUM(+4)ISOPROPOXIDE

TITANIC ACID TETRAISOPROPYL ESTER

TETRAISOPROPYL TITANATE

TETRAISOPROPYL ORTHOTITANATE

ORTHOTITANIC ACID TETRAISOPROPYL ESTER

VERTEC(TM) TIPT

TYZOR(R) ORGANIC TITANATE

Titanium(4+) tetrapropan-2-olate

tetraisopropoxidetitanium

tetraisopropoxytitanium

tetraisopropyltitanate(flammableliquids,n.o.s.)

tetrakis(1-methylethoxy)-titaniu

tetrakis(isopropoxy)titanium

tiisopropylate

titanic(iv)acid,tetraisopropylester

Titanium(IV) isopropoxide, 99.999% metals basis

TITANIUM(IV) ISOPROPOXIDE, FOR CAMBRIDG&

Tetra-#niso-propyl orthotitanate

Titanium(IV)isopropoxide,95%

Titanium(IV)isopropoxide,99.995%(metalsbasis)

Titanium(IV) isopropoxide, 98+%

Titanium(IV)i-propoxide,min.98%

titanium(iv) isopropoxide, vertec

TETRA-ISO-PROPYL-O-TITANATE

Titantetraisopropanolat

2-Propanol, titanium salt

Titanium(IV) isopropoxide, VERTEC(R) TIPT, 97+%

Isopropyl titanate(IV): (Titanium(IV) isopropoxide)

Titanium (IV) isopropoxide, 97% min

Titanium(IV) isopropoxide, VERTEC TIPT, 97+%

Iso-propy titanate

Tetraisopropoxytitanium(IV)

Titanium(IV) i-propoxide, min. 98%

Titanium(IV) isopropoxide, 99.995% trace metals basis

Tetraisopropyl Titanate(monomer) 〔Titanium(Ⅳ) Isopropoxide〕

Titanium(IV) isopropoxide (Tetra isopropyl titanate)

Titanium(IV) i-propoxide, min. 98%, 93-2216, contained in 50 ml Swagelok(R) cylinder (96-1070) for CVD/ALD

TTIP: Ti[OCH(CH3)2]4

A-1(TPT)

TYZOR TP

Titanium(IV) i-propoxide, min. 98%, 93-2216, contained in 50 ml Swagelok cylinder (96-1070) for CVD/ALD

TITANIUM ISOPROPOXIDETITANIUM ISOPROPOXIDETITANIUM ISOPROPOXIDE

Titanium(IV) isopropoxide, 97+%

titanicacidisopropylester

titanium(4+)salt

titaniumisopropoxide(ti(oc3h7)4)

Titaniumispropoxide