Tetrabutyl titanate
- Product Name
- Tetrabutyl titanate
- CAS No.
- 5593-70-4
- Chemical Name
- Tetrabutyl titanate
- Synonyms
- TITANIUM BUTOXIDE;TNBT;TETRA-N-BUTYL TITANATE;tetrabutoxytitanium;BUTYL TITANATE;TITANIUM(IV) BUTOXIDE;TITANIUM TETRABUTOXIDE;TETRABUTYL ORTHOTITANATE;Tyzor TBT;titaniuM salt
- CBNumber
- CB6222404
- Molecular Formula
- C16H36O4Ti
- Formula Weight
- 340.32
- MOL File
- 5593-70-4.mol
Tetrabutyl titanate Property
- Melting point:
- -55°C
- Boiling point:
- 206 °C/10 mmHg (lit.)
- Density
- 1.00 g/mL at 20 °C (lit.)
- vapor pressure
- 5.6 hPa (20 °C)
- refractive index
- n20/D 1.491(lit.)
- Flash point:
- 55 °F
- storage temp.
- Store at +2°C to +8°C.
- solubility
- Miscible with aliphatic, aromatic, chlorinated and oxygenated solvents.
- form
- Liquid
- Specific Gravity
- 0.998
- color
- Pale yellow
- explosive limit
- 2.0-12.0%(V)
- Water Solubility
- RAPIDLY HYDROLIZED
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- BRN
- 4148236
- Stability:
- Stable, but moisture sensitive. Flammable. Incompatible with water, moisture, strong oxidizing agents, strong acids.
- InChIKey
- YHWCPXVTRSHPNY-UHFFFAOYSA-N
- LogP
- 0.84 at 25℃
- CAS DataBase Reference
- 5593-70-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Tetrabutoxytitanium(5593-70-4)
- EPA Substance Registry System
- Tetrabutyl titanate (5593-70-4)
Safety
- Hazard Codes
- Xi,T
- Risk Statements
- 10-36/37/38-67-41-37/38-45
- Safety Statements
- 16-26-39-24/25-53
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 1
- RTECS
- XR1585000
- F
- 21
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29051900
- Hazardous Substances Data
- 5593-70-4(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: 3122 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
H336May cause drowsiness or dizziness
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 8.21084
- Product name
- Tetra-n-butyl orthotitanate
- Purity
- forsynthesis
- Packaging
- 100mL
- Price
- $40.9
- Updated
- 2024/03/01
- Product number
- 8.21084
- Product name
- Tetra-n-butyl orthotitanate
- Purity
- forsynthesis
- Packaging
- 500mL
- Price
- $136
- Updated
- 2024/03/01
- Product number
- 8.21084
- Product name
- Tetra-n-butyl orthotitanate
- Purity
- forsynthesis
- Packaging
- 10Kg
- Price
- $640
- Updated
- 2024/03/01
- Product number
- 244112
- Product name
- Titanium(IV) butoxide
- Purity
- reagent grade, 97%
- Packaging
- 5g
- Price
- $42.1
- Updated
- 2024/03/01
- Product number
- 244112
- Product name
- Titanium(IV) butoxide
- Purity
- reagent grade, 97%
- Packaging
- 2kg
- Price
- $282
- Updated
- 2024/03/01
Tetrabutyl titanate Chemical Properties,Usage,Production
Chemical Properties
colourless to light yellow viscous liquid
Uses
Ester exchange reactions; heat-resistant paints (up to 500C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross-linking agent; condensation catalyst.
Uses
Titanium(IV) n-butoxide is used in the preparation of nanosized titania powders in the anatase form and ferroelectric bismuth titanate thin films. It is also used as intermediates, paint additives, coating additives, processing aids and as process regulators. It is involved in the preparation of nanocrystalline titanium dioxide powders at room temperature.
Uses
Titanium(IV) butoxide is a sourcing material for the preparation of titanium oxide (TiO2) which can further be used in a variety of applications such as dye sensitized solar cells (DSSCs), photo-catalytic and self-cleaning based coatings.
General Description
A water-white to pale-yellow liquid with an alcohol-like odor. About the same density as water. Flash point 170°F. Contact may irritate or cause burns.
Air & Water Reactions
Soluble in water. Reacts with water to form butanol and titanium dioxide, the reaction is not generally thought to be hazardous.
Reactivity Profile
Organometallics are strongly reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Generally highly toxic. Often react on contact with tissues to give toxic products.
Health Hazard
LIQUID: Irritating to skin and eyes. If swallowed will cause nausea and vomiting.
Fire Hazard
Combustible. Containers may explode in fire. May give off dense white smoke. Containers may explode.
Flammability and Explosibility
Flammable
Safety Profile
Suspected carcinogen. A poison by intravenous route. Moderately toxic by ingestion. See n-BUTYL ALCOHOL and TITANIUM COMPOUNDS. Flammable when exposed to heat or flame. To fight fire, use water, spray, foam, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.
Purification Methods
Dissolve it in *C6H6, filter if solid is present, evaporate and vacuum fractionate through a Widmer 24inch column (p 11). The ester hydrolyses when exposed to air to give hydrated ortho-titanic acid. The titanium content can be determined thus: weigh a sample (ca 0.25g) into a weighed crucible and cover it with 10mL of H2O and a few drops of conc HNO3. Heat (hot plate) carefully till most of the H2O has evaporated. Cool and add more H2O (10mL) and conc HNO3 (2mL), and evaporate carefully (no spillage) to dryness and ignite the residue at 600-650o/1hour. Weigh the residual TiO2. [Bradley et al. J Chem Soc 2773 1952, Speer J Org Chem 14 655 1949, Beilstein 1 II 398, 1 III 1515, 1 IV 1415.]
Tetrabutyl titanate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Tetrabutyl titanate manufacturers
- Product
- tetrabutyl titanate 5593-70-4
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-05-06
- Product
- Tetrabutyl titanate 5593-70-4
- Price
- US $1451.00/L
- Min. Order
- 200L
- Purity
- 80-98%
- Supply Ability
- 2000T
- Release date
- 2021-06-03
- Product
- Tetrabutyl titanate 5593-70-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-16