Tetrabutyl titanate

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Tetrabutyl titanate

Product Name: Tetrabutyl titanate
CAS No.: 5593-70-4
Chemical Name: Tetrabutyl titanate
Synonyms: TITANIUM BUTOXIDE;TNBT;TETRA-N-BUTYL TITANATE;tetrabutoxytitanium;BUTYL TITANATE;TITANIUM(IV) BUTOXIDE;TITANIUM TETRABUTOXIDE;TETRABUTYL ORTHOTITANATE;Tyzor TBT;titaniuM salt
CBNumber: CB6222404
Molecular Formula: C16H36O4Ti
Formula Weight: 340.32
MOL File: 5593-70-4.mol

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Tetrabutyl titanate Property

Melting point:: -55°C
Boiling point:: 206 °C/10 mmHg (lit.)
Density: 1.00 g/mL at 20 °C (lit.)
vapor pressure: 5.6 hPa (20 °C)
refractive index: n20/D 1.491(lit.)
Flash point:: 55 °F
storage temp.: Store at +2°C to +8°C.
solubility: Miscible with aliphatic, aromatic, chlorinated and oxygenated solvents.
form: Liquid
Specific Gravity: 0.998
color: Pale yellow
explosive limit: 2.0-12.0%(V)
Water Solubility: RAPIDLY HYDROLIZED
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
BRN: 4148236
Stability:: Stable, but moisture sensitive. Flammable. Incompatible with water, moisture, strong oxidizing agents, strong acids.
InChIKey: YHWCPXVTRSHPNY-UHFFFAOYSA-N
LogP: 0.84 at 25℃
CAS DataBase Reference: 5593-70-4(CAS DataBase Reference)
NIST Chemistry Reference: Tetrabutoxytitanium(5593-70-4)
EPA Substance Registry System: Tetrabutyl titanate (5593-70-4)

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Safety

Hazard Codes: Xi,T
Risk Statements: 10-36/37/38-67-41-37/38-45
Safety Statements: 16-26-39-24/25-53
RIDADR: UN 1993 3/PG 3
WGK Germany: 1
RTECS: XR1585000
F: 21
TSCA: Yes
HazardClass: 8
PackingGroup: III
HS Code: 29051900
Hazardous Substances Data: 5593-70-4(Hazardous Substances Data)
Toxicity: LD50 orally in Rabbit: 3122 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.21084
Product name: Tetra-n-butyl orthotitanate
Purity: forsynthesis
Packaging: 100mL
Price: $40.9
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.21084
Product name: Tetra-n-butyl orthotitanate
Purity: forsynthesis
Packaging: 500mL
Price: $136
Updated: 2024/03/01

Sigma-Aldrich

Product number: 244112
Product name: Titanium(IV) butoxide
Purity: reagent grade, 97%
Packaging: 5g
Price: $42.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.21084
Product name: Tetra-n-butyl orthotitanate
Purity: forsynthesis
Packaging: 10Kg
Price: $640
Updated: 2024/03/01

Sigma-Aldrich

Product number: 244112
Product name: Titanium(IV) butoxide
Purity: reagent grade, 97%
Packaging: 2kg
Price: $282
Updated: 2024/03/01

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Tetrabutyl titanate Chemical Properties,Usage,Production

Chemical Properties

colourless to light yellow viscous liquid

Uses

Ester exchange reactions; heat-resistant paints (up to 500C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross-linking agent; condensation catalyst.

Uses

Titanium(IV) n-butoxide is used in the preparation of nanosized titania powders in the anatase form and ferroelectric bismuth titanate thin films. It is also used as intermediates, paint additives, coating additives, processing aids and as process regulators. It is involved in the preparation of nanocrystalline titanium dioxide powders at room temperature.

Uses

Titanium(IV) butoxide is a sourcing material for the preparation of titanium oxide (TiO₂) which can further be used in a variety of applications such as dye sensitized solar cells (DSSCs), photo-catalytic and self-cleaning based coatings.

General Description

A water-white to pale-yellow liquid with an alcohol-like odor. About the same density as water. Flash point 170°F. Contact may irritate or cause burns.

Air & Water Reactions

Soluble in water. Reacts with water to form butanol and titanium dioxide, the reaction is not generally thought to be hazardous.

Reactivity Profile

Organometallics are strongly reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Generally highly toxic. Often react on contact with tissues to give toxic products.

Health Hazard

LIQUID: Irritating to skin and eyes. If swallowed will cause nausea and vomiting.

Fire Hazard

Combustible. Containers may explode in fire. May give off dense white smoke. Containers may explode.

Flammability and Explosibility

Flammable

Safety Profile

Suspected carcinogen. A poison by intravenous route. Moderately toxic by ingestion. See n-BUTYL ALCOHOL and TITANIUM COMPOUNDS. Flammable when exposed to heat or flame. To fight fire, use water, spray, foam, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.

Purification Methods

Dissolve it in *C6H6, filter if solid is present, evaporate and vacuum fractionate through a Widmer 24inch column (p 11). The ester hydrolyses when exposed to air to give hydrated ortho-titanic acid. The titanium content can be determined thus: weigh a sample (ca 0.25g) into a weighed crucible and cover it with 10mL of H2O and a few drops of conc HNO3. Heat (hot plate) carefully till most of the H2O has evaporated. Cool and add more H2O (10mL) and conc HNO3 (2mL), and evaporate carefully (no spillage) to dryness and ignite the residue at 600-650o/1hour. Weigh the residual TiO2. [Bradley et al. J Chem Soc 2773 1952, Speer J Org Chem 14 655 1949, Beilstein 1 II 398, 1 III 1515, 1 IV 1415.]

Tetrabutyl titanate Preparation Products And Raw materials

Raw materials

(S)-tert-Butyl 6-amino-2-((tert-butoxycarbonyl)amino)hexanoate hydrochloride 4-Chlorobenzaldehyde Toluene Titanium tetrachloride 1-Butanol

Preparation Products

1,2,5,6,9,10-Hexabromocyclododecane Diphenyl isophthalate

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View Lastest Price from Tetrabutyl titanate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: tetrabutyl titanate 5593-70-4
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-06

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Tetrabutyl titanate 5593-70-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-16

Baoji Guokang Bio-Technology Co., Ltd.

Product: Tetrabutyl titanate 5593-70-4
Price: US $1451.00/L
Min. Order: 200L
Purity: 80-98%
Supply Ability: 2000T
Release date: 2021-06-03

5593-70-4, Tetrabutyl titanateRelated Search:

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titanium(iv) n-butoxide, vertec

TiTanium n-buThoxide

Tetra-n-butyl orthotitanate for synthesis

Titantetrabutanolat

1-butanol, titanium salt

butyl alcohol, titanium salt

Tetra-N-butyl Titanate (TNBT)

TNBT

Titanium(IV) n-butoxide, VERTEC(R) TNBT, 98+%

Tetra-n-butyl Titanate(monomer)

b1(titanate)

Butyl alcohol, titanium(4+) salt

Butyl orthotitanate

Butyl titanate(IV) ((BuO)4Ti)

butylalcohol,titanium(4+)salt

butylorthotitanate

butyltitanate(iv)((buo)4ti)

butyltitanatemonomer

nsc220232

orgaticsta25

tetrabutoxy-titane

tetrabutoxy-titaniu

tetrabutoxytitanium

tetrabutyltitanate(czech)

Titanium butoxide (Ti(OBu)4)

titanium(4+)butoxide

Titanium, tetrabutoxy-

titaniumbutoxide(ti(obu)4)

titaniumbutylate

TitaniumButyrate

titaniumtetrakis(butoxide)

Tyzor BP

Tyzor TBT

tyzortbt

Tetrabutyl titanate: (Butyl titanate)

Titanium (IV) n-butoxide, 99+%