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Stannic oxide

Description References
Product Name
Stannic oxide
CAS No.
18282-10-5
Chemical Name
Stannic oxide
Synonyms
TIN OXIDE;TIN DIOXIDE;TIN(IV) OXIDE;tin(iv);stannicdioxide[qr];STANNICOXIDE,POWDER,REAGENT;Tin ash;dioxotin;c.i.77861;t10(oxide)
CBNumber
CB8130822
Molecular Formula
O2Sn
Formula Weight
150.71
MOL File
18282-10-5.mol
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Stannic oxide Property

Melting point:
1127 °C
Boiling point:
1800-900°C
Density 
6.95 g/mL at 25 °C(lit.)
bulk density
500-600kg/m3
refractive index 
1.9968
Flash point:
1800-1900°C
storage temp. 
Store at +5°C to +30°C.
solubility 
Soluble in hot concentrated alkalis, and concentrated acids. Insoluble in alcohol.
form 
nanopowder
color 
White to slightly gray
Specific Gravity
7
PH
4-5 (50g/l, H2O, 20℃)(slurry)
Water Solubility 
INSOLUBLE
Hydrolytic Sensitivity
6: forms irreversible hydrate
Crystal Structure
Rutile type
crystal system
square
Sublimation 
1800-1900 ºC
Merck 
14,8778
Space group
P42/mnm
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.47370.47370.31859090900.0715
Exposure limits
ACGIH: TWA 2 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3
Stability:
Stable.
CAS DataBase Reference
18282-10-5(CAS DataBase Reference)
EPA Substance Registry System
Tin dioxide (18282-10-5)
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Safety

OEB
B
OEL
TWA: 2 mg/m3
RTECS 
XQ4000000
HS Code 
2825908590
Hazardous Substances Data
18282-10-5(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: > 20000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
GF03090136
Product name
Tin oxide
Purity
powder, max. particle size 150 micron, weight 200?g
Packaging
1EA
Price
$498
Updated
2025/07/31
Sigma-Aldrich
Product number
920169
Product name
Tin (IV) oxide nanosheets
Packaging
10 mL
Price
$267.9
Updated
2025/07/31
Sigma-Aldrich
Product number
204714
Product name
Tin(IV) oxide
Purity
≥99.99% trace metals basis
Packaging
5g
Price
$153
Updated
2025/07/31
Sigma-Aldrich
Product number
204714
Product name
Tin(IV) oxide
Purity
≥99.99% trace metals basis
Packaging
25g
Price
$544
Updated
2025/07/31
Sigma-Aldrich
Product number
1.07818
Product name
Tin(IV) oxide
Purity
EMPLURA?
Packaging
250g
Price
$122
Updated
2025/07/31
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Stannic oxide Chemical Properties,Usage,Production

Description

Stannic oxide, also known as tin oxide, is an inorganic compound consisted of tin and oxygen, which is widely applied in various fields. The dominant usage of stannic oxide is to serve as a precursor in the production of other, especially trivalent, tin compounds or salts. It is also commonly employed as an opacifier in glazes. The addition of larger amounts of stannic oxide enhances the refractoriness of glazes and turns it from transparent to an opaque white. Stannic oxide is also used in the production of customized glass by giving transparent glass an opaque, porcelain-like, opaque appearance. It has proved to be a highly effective polishing material for glass and quarried rock, such as marble, granite and quartz. Besides, stannous oxide can be used for llumination with UV light in combination with cerium oxide in ceramic form. It also has a broad range of applications in other areas, such as semiconductors, photovoltaic materials, solar cells, lithium ion batteries, photocatalysts, and as gas-sensing agents in solid-state detectors.

References

http://sciencing.com/tin-oxide-uses-8125683.html
https://www.alfa.com/zh-cn/catalog/012283/
http://www.azom.com/article.aspx?ArticleID=2358
https://en.wikipedia.org/wiki/Tin(II)_oxide

Chemical Properties

white or off-white powder

Physical properties

White or grayish powder; tetragonal crystals; density 6.85 g/cm3; refractive index 2.006; Mohs hardness 6.5; melts at 1,630°C; insoluble in water; soluble in hot concentrated alkalies.

Uses

It is used to detect carbon monoxide. Used in ceramic glazes and colors, putty, perfume preparations, textiles, polishing powder for steel, and the manufacture of special glasses. Stannic oxide is also used in making white patinas.

Uses

Polishing glass and metals; manufacture of milk-colored, ruby and alabaster glass, enamels, pottery, putty; mordant in printing and dyeing fabrics; in fingernail polishes.

Uses

Stannic oxide (SnO2) is a whitish powder used as a ceramic glaze and polishing agent.

Definition

ChEBI: Tin dioxide is a tin oxide compound consisting of tin(IV) covalently bound to two oxygen atoms.

Preparation

Tin(II) oxide is prepared by heating tin(II) hydroxide. The latter is obtained as a white precipitate by reacting Sn2+ ions with hydroxide ions: Sn2+(aq) + 2OHˉ(aq) → Sn(OH)2 (s) Sn(OH)2 ?→ ?? SnO(s) + H2O(g).

General Description

White or off-white crystalline solid or powder. Mp 1127°C, Sublimes: 1800-1900°C, density: 6.95 g cm-3. Insoluble in water. Soluble in concentrated sulfuric acid, hydrochloric acid. Occurs in nature as the mineral cassiterite. Used as a catalyst, in putty, as a polishing powder for steel and glass, in ceramic glazes and colors. Flowers of tin refers to the material collected as the result of condensation after sublimation.

Reactivity Profile

TIN(IV) OXIDE is non-flammable and non-combustible. Reacts vigorously with strong reducing agents. Incompatible with chlorine trifluoride.

Battery Materials

In perovskite solar cells (PSCs),  Stannic oxide (SnO2) is often employed as an electron transport layer (ETL) due to its excellent electron mobility and high transparency. Its function is to facilitate the efficient transport of photogenerated electrons from the perovskite layer to the external circuit, while also blocking holes, thereby improving the overall efficiency and stability of the solar cell. Using an aqueous solution of SnO2 can provide advantages such as ease of deposition, reduced toxicity, and environmental compatibility. This is particularly significant for scaling up the manufacturing process and aligns well with the sustainability goals often associated with renewable energy technologies like perovskite solar cells.

Purification Methods

Reflux it repeatedly with fresh HCl until the acid shows no tinge of yellow. The oxide is then dried at 110o.

Advantages

Stannic oxide, as the material of the electron transport layer, has good electronic conductivity and can effectively promote the rapid transmission of photogenerated electrons to the electrode.

Stannic oxide Preparation Products And Raw materials

Raw materials

Preparation Products

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Stannic oxide Suppliers

Shanghai Guanghua Technology Co., Ltd
Tel
Fax
010-62373998
Email
chemol@126.com
Country
China
ProdList
306
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58
BROFOS NANOTECHNOLOGY(NINGBO)CO ,LTD.
Tel
0574-62615397 17757424292
Email
brofosnano@foxmail.com
Country
China
ProdList
163
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58
Wuhan Xingzhongcheng Technology Co., Ltd.
Tel
027-83389957 18627766980
Fax
027-83389957
Email
914018854@qq.com
Country
China
ProdList
282
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58
Shanghai Yunfu Nano Technology Co., LTD
Tel
021-15796584478 15796584478
Email
3246531796@qq.com
Country
China
ProdList
490
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58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
Beijing HwrkChemical Technology Co., Ltd
Tel
18515581800 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
9400
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
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View Lastest Price from Stannic oxide manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
Stannic oxide 18282-10-5
Price
US $2.00-5.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-20
Hebei Chuanghai Biotechnology Co., Ltd
Product
Stannic oxide 18282-10-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-12-03
Hebei Zhuanglai Chemical Trading Co Ltd
Product
Stannic oxide 18282-10-5
Price
US $55.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-11-15

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