ChemicalBook > CAS DataBase List > 4-METHOXY-3-METHYLACETOPHENONE

4-METHOXY-3-METHYLACETOPHENONE

Product Name
4-METHOXY-3-METHYLACETOPHENONE
CAS No.
10024-90-5
Chemical Name
4-METHOXY-3-METHYLACETOPHENONE
Synonyms
4-METHOXY-3-METHYLACETOPHENONE;3'-Methyl-4'-methoxyacetophenone;4'-Methoxy-3'-methylacetophenone;Ethanone, 1-(4-methoxy-3-methylphenyl)-;1-(4-Methoxy-3-methylphenyl)ethan-1-one
CBNumber
CB81406160
Molecular Formula
C10H12O2
Formula Weight
164.2
MOL File
10024-90-5.mol
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4-METHOXY-3-METHYLACETOPHENONE Property

Melting point:
26-26.5 °C
Boiling point:
251.67°C (rough estimate)
Density 
1.0326 (rough estimate)
refractive index 
1.5460 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Oil
color 
Dark Yellow
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Safety

HS Code 
2914500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC
Product number
M269560
Product name
1-(4-Methoxy-3-methylphenyl)ethanone
Packaging
500mg
Price
$120
Updated
2021/12/16
Rieke Metals
Product number
AC0322
Product name
1-(4-Methoxy-3-methylphenyl)ethanone
Packaging
1g
Price
$200
Updated
2021/12/16
Apolloscientific
Product number
OR944970
Product name
1-(4-Methoxy-3-methylphenyl)ethanone
Packaging
1g
Price
$270
Updated
2021/12/16
AK Scientific
Product number
J96845
Product name
3'-Methyl-4'-methoxyacetophenone
Packaging
5g
Price
$292
Updated
2021/12/16
Rieke Metals
Product number
AC0322
Product name
1-(4-Methoxy-3-methylphenyl)ethanone
Packaging
5g
Price
$494
Updated
2021/12/16
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4-METHOXY-3-METHYLACETOPHENONE Chemical Properties,Usage,Production

Preparation

Preparation by reaction of acetic anhydride with 2-methylanisole in the presence of lithium perchlorate at 60° for 1.5 h (99%).

Synthesis

876-02-8

77-78-1

10024-90-5

1. Dimethyl sulfate (17.50 mL, 183 mmol) was slowly added to a stirred suspension of 1-(4-hydroxy-3-methylphenyl)ethanone (25 g, 166 mmol) and potassium carbonate (28.8 g, 208 mmol) in acetone (277 mL). The reaction was carried out at room temperature. 2. The reaction mixture was heated to reflux and stirred continuously overnight. 3. Upon completion of the reaction, it was cooled to room temperature, the solids were separated by filtration, and the solids were washed with acetone. 4. The filtrate was concentrated under vacuum to remove the solvent. 5. The concentrated organic residue was dissolved in ethyl acetate (EtOAc) and the organic layer was washed with water. 6. The organic layer was separated, dried with anhydrous magnesium sulfate (MgSO?), filtered, and the solvent was evaporated under vacuum to give 1-(4-methoxy-3-methylphenyl)ethanone (28.7 g) as a yellow oil. The product did not require further purification and could be used directly in the next reaction.

References

[1] Patent: WO2015/12708, 2015, A1. Location in patent: Page/Page column 14; 15
[2] Patent: CN107337596, 2017, A. Location in patent: Paragraph 0039; 0040; 0044; 0045

4-METHOXY-3-METHYLACETOPHENONE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-METHOXY-3-METHYLACETOPHENONE Suppliers

China 49 India 1 United States 4 Global 54
Carbott PharmTech Inc.
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Adamas Reagent, Ltd.
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021-64823266
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chenyj@titansci.com
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Beijing Eternalchem Co,. Ltd.
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010-59484199 18611897322
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sales@eternalchem.com
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SynAsst Chemical.
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Shanghai JONLN Reagent Co., Ltd.
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Xinyanhe Pharmatech Co.,Ltd
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Amadis Chemical Company Limited
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Yantai ShengKailun Chemical Technology Co., Ltd.
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Shanghai CR Corporation Limited
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fred.wen@crcorporation.cn
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China
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Wuxi AppTec
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China
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10024-90-5, 4-METHOXY-3-METHYLACETOPHENONERelated Search:

Rotenone 1-[3-(CHLOROMETHYL)-4-METHOXYPHENYL]ETHAN-1-ONE 4'-BENZYLOXY-2'-METHOXY-3'-METHYLACETOPHENONE 4'-BENZYLOXY-2'-HYDROXY-3'-METHYLACETOPHENONE 5-ACETYL-2,3-DIHYDROBENZO(B)FURAN STERIGMATOCYSTIN 5-HYDROXY-7,4'-DIMETHOXY-6,8-DIMETHYLFLAVONE 4'-Methoxyacetophenone OSAJIN 2-HYDROXY-4,6-DIMETHOXY-3-METHYLACETOPHENONE 2-BENZYL-5-ACETYL METHYL SALICYLATE ISO-OSAJIN 7-[3-(4-ACETYL-3-HYDROXY-2-PROPYLPHENOXY)-2-HYDROXYPROPOXY]-4-OXO-8-PROPYL-4H-1-BENZOPYRAN-2-CARBOXYLIC ACID SODIUM SALT ethyl 5-acetyl-2-benzyloxybenzoate 1-(2,4-dimethoxy-3-methyl-phenyl)ethanone ISOPOMIFERIN POMIFERIN ISO-OSAJIN-4'-METHYL ETHER

  • 4-METHOXY-3-METHYLACETOPHENONE
  • 3'-Methyl-4'-methoxyacetophenone
  • 1-(4-Methoxy-3-methylphenyl)ethan-1-one
  • Ethanone, 1-(4-methoxy-3-methylphenyl)-
  • 4'-Methoxy-3'-methylacetophenone
  • 10024-90-5