ChemicalBook > CAS DataBase List > 2-AMINO-5-BROMOBENZOPHENONE

2-AMINO-5-BROMOBENZOPHENONE

Product Name
2-AMINO-5-BROMOBENZOPHENONE
CAS No.
39859-36-4
Chemical Name
2-AMINO-5-BROMOBENZOPHENONE
Synonyms
IFLAB-BB F1386-0357;2-BENZOYL-4-BROMOANILINE;2-AMINO-5-BROMOBENZOPHENONE;5-BROMO-2-AMINOBENZOPHENONE;2-Benzoyl-4-bromobenzenamine;2-Amino-5-bromobenzophenone, >=97%;(2-AMINO-5-BROMO-PHENYL)-PHENYL-METHANONE;Methanone, (2-amino-5-bromophenyl)phenyl-;2-Benzoyl-4-bromoaniline 5-Bromo-2-aminobenzophenone
CBNumber
CB8170910
Molecular Formula
C13H10BrNO
Formula Weight
276.13
MOL File
39859-36-4.mol
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2-AMINO-5-BROMOBENZOPHENONE Property

Melting point:
109-113℃
Boiling point:
424.6±35.0 °C(Predicted)
Density 
1.484±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
DMF: 30 mg/ml; DMSO: 30 mg/ml; Ethanol: 30 mg/ml
pka
-0.01±0.10(Predicted)
form 
Powder
color 
Yellow
InChI
InChI=1S/C13H10BrNO/c14-10-6-7-12(15)11(8-10)13(16)9-4-2-1-3-5-9/h1-8H,15H2
InChIKey
LXJVUGANBDAASB-UHFFFAOYSA-N
SMILES
C(C1=CC(Br)=CC=C1N)(C1=CC=CC=C1)=O
CAS DataBase Reference
39859-36-4(CAS DataBase Reference)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
HS Code 
2922.39.4500
HazardClass 
6.1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
A3311
Product name
2-Amino-5-bromobenzophenone
Packaging
1G
Price
$93
Updated
2025/07/31
TCI Chemical
Product number
A3311
Product name
2-Amino-5-bromobenzophenone
Packaging
5G
Price
$279
Updated
2025/07/31
TRC
Product number
A601960
Product name
(2-Amino-5-bromophenyl)phenyl-methanone
Packaging
5g
Price
$140
Updated
2021/12/16
Matrix Scientific
Product number
119112
Product name
2-Benzoyl-4-bromoaniline
Purity
95+%
Packaging
1g
Price
$118
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA140254
Product name
(2-Amino-5-bromophenyl)(phenyl)methanone
Packaging
2g
Price
$104
Updated
2021/12/16
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2-AMINO-5-BROMOBENZOPHENONE Chemical Properties,Usage,Production

Chemical Properties

Pale Yellow Solid

Uses

2-Amino-5-bromobenzophenone is a benzophenone (B204980) derivative that is widely used in the synthesis of pharmaceutical compounds.

Synthesis

2835-77-0

39859-36-4

The general procedure for the synthesis of 2-benzoyl-4-bromoaniline from 2-aminobenzophenone is as follows: reference is made to the synthesis of Example A16 (2-amino-5-bromophenyl)-phenyl-methanone, which can be accessed from US 20040127536 A1 and is based on the work of D. Roche, K. Prasad, O. Repic, TJ Blacklock in Tetrahedron Lett. 41, 2083-2085 (2000). This was done as follows: 2-aminobenzophenone (30 g, 152 mmol) was suspended in acetic acid (300 mL). Potassium bromide (19.9 g, 167 mmol), sodium perborate tetrahydrate (28 g, 183 mmol) and ammonium molybdate tetrahydrate (1.5 g) were subsequently added and the mixture was stirred continuously for 3 h at 0 °C. The dense yellow precipitate formed during the reaction was washed with ice water (300 mL) and subsequently separated by filtration, washed again with ice water and dried. Finally, 40.3 g (96% yield) of yellow solid product was obtained. Mass spectrometry analysis showed: m/z = 276 (M).

References

[1] Tetrahedron, 2007, vol. 63, # 13, p. 2811 - 2823
[2] Patent: US2006/94754, 2006, A1. Location in patent: Page/Page column 11
[3] Organic Letters, 2010, vol. 12, # 12, p. 2841 - 2843
[4] Chemical Communications, 2010, vol. 46, # 29, p. 5244 - 5246
[5] European Journal of Organic Chemistry, 2017, vol. 2017, # 31, p. 4600 - 4608

2-AMINO-5-BROMOBENZOPHENONE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-5-BROMOBENZOPHENONE Suppliers

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View Lastest Price from 2-AMINO-5-BROMOBENZOPHENONE manufacturers

RongNa Biotechnology Co.,Ltd
Product
2-AMINO-5-BROMOBENZOPHENONE 39859-36-4
Price
US $10.00/ASSAYS
Min. Order
1ASSAYS
Purity
99%
Supply Ability
1 ton
Release date
2025-08-05
Hebei Chuanghai Biotechnology Co., Ltd
Product
2-AMINO-5-BROMOBENZOPHENONE 39859-36-4
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-26
Jinan Million Pharmaceutical Co., Ltd
Product
2-AMINO-5-BROMOBENZOPHENONE 39859-36-4
Price
US $1.00/kg
Min. Order
2kg
Purity
2-AMINO-5-BROMOBENZOPHENONE
Supply Ability
100
Release date
2024-10-25

39859-36-4, 2-AMINO-5-BROMOBENZOPHENONERelated Search:


  • 2-Amino-5-bromobenzophenone, >=97%
  • 5-BROMO-2-AMINOBENZOPHENONE
  • 2-AMINO-5-BROMOBENZOPHENONE
  • (2-AMINO-5-BROMO-PHENYL)-PHENYL-METHANONE
  • 2-BENZOYL-4-BROMOANILINE
  • IFLAB-BB F1386-0357
  • Methanone, (2-amino-5-bromophenyl)phenyl-
  • 2-Benzoyl-4-bromoaniline 5-Bromo-2-aminobenzophenone
  • 2-Benzoyl-4-bromobenzenamine
  • 39859-36-4
  • Aromatic Benzophenones & Derivatives (substituted)
  • API intermediates