Itaconic anhydride

Product Name: Itaconic anhydride
CAS No.: 2170-03-8
Chemical Name: Itaconic anhydride
Synonyms: 2,5-Furandione, dihydro-3-methylene-;ITACONIC ANHYDIDE;ITACONIC AHYDRIDE;ITACONIC ANHYDRIDE;ItaconicAnhydride>Itaconic anhydride,98%;Itaconic anhydride 95%;Itaconic acid anhydride;ITACONIC ANHYDRIDE 95+%;Itaconic anhydride 98.5%
CBNumber: CB8209597
Molecular Formula: C5H4O3
Formula Weight: 112.08
MOL File: 2170-03-8.mol

More

Less

Itaconic anhydride Property

Melting point:: 66-68 °C (lit.)
Boiling point:: 114-115 °C/12 mmHg (lit.)
Density: 1.2600
refractive index: 1.5130 (estimate)
Flash point:: 114-115°C/12mm
storage temp.: Store below +30°C.
form: Crystalline Powder
color: White to cream
Water Solubility: Hydrolyzes in water.
Sensitive: Moisture Sensitive
BRN: 2212
CAS DataBase Reference: 2170-03-8(CAS DataBase Reference)
NIST Chemistry Reference: 2,5-Furandione, dihydro-3-methylene-(2170-03-8)
EPA Substance Registry System: 2,5-Furandione, dihydro-3-methylene- (2170-03-8)

More

Less

Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38-22
Safety Statements: 26-36-24/25
WGK Germany: 3
F: 3-10-21
TSCA: Yes
HS Code: 2917 19 80

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 259926
Product name: Itaconic anhydride
Purity: 95%
Packaging: 25g
Price: $50
Updated: 2024/03/01

Sigma-Aldrich

Product number: 259926
Product name: Itaconic anhydride
Purity: 95%
Packaging: 100g
Price: $176
Updated: 2024/03/01

TCI Chemical

Product number: I0203
Product name: Itaconic Anhydride
Purity: >95.0%(T)
Packaging: 25g
Price: $31
Updated: 2024/03/01

TCI Chemical

Product number: I0203
Product name: Itaconic Anhydride
Purity: >95.0%(T)
Packaging: 100g
Price: $107
Updated: 2024/03/01

Alfa Aesar

Product number: B25216
Product name: Itaconic anhydride, 97%
Packaging: 25g
Price: $32.65
Updated: 2024/03/01

More

Less

Itaconic anhydride Chemical Properties,Usage,Production

Chemical Properties

WHITE TO CREAM CRYSTALLINE POWDER

Uses

Itaconic anhydride is used in immobilization of β-glucosidase. It undergoes estrification to obtain suitable monomers for emulsion polymerization itaconates.

Preparation

To a flask equipped with a 12 mm diameter ground glass adaptor tube bent for downward distillation and joined to a 100 cm condenser is added 200 gm (0.95 mole) of citric acid monohydrate. An ice-cooled flask and a cold trap are connected to the condenser. The flask containing the citric acid is heated rapidly with a wide flame of the Meker burner so that in 12-15 min the distillation at 175-190°C is complete. The distillation is stopped earlier if the vapors in the reaction flask become yellow. Superheating of the citric acid will cause rearrangement to citraconic anhydride. The water is quickly separated from the distillate and the itaconic anhydride layer dried to afford 40-50 gm (37-47%), m.p. 67-68°C. Long time contact of the water with the anhydride causes it to hydrolyze to itaconic acid, m.p. 162-165°C.

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 6027, 1984 DOI: 10.1016/S0040-4039(01)81751-2

General Description

Itaconic anhydride (ITA) is a biobased material that is obtained from renewable resources. It is produced from the pyrolysis of citric acid or by fermenting carbohydrates which forms itanoic acid. Itanoic acid can be dehydrated to form an anhydride. It is relatively more reactive that maleic anhydride and can be used as an alternating monomer that facilitates the introduction of polar functionalities in polymers.

Purification Methods

Crystallise the anhydride from CHCl3/pet ether. It can be distilled under reduced pressure. Distillation at atmospheric pressure, or prolonged distillation causes rearrangement to citraconic anhydride (2-methylmaleic anhydride). If the material (as seen in the IR spectrum) contains much free acid, then heat with acetyl chloride or SOCl2, evaporate and distil at as high a vacuum as possible. The crude anhydride deposits crystals of itaconic acid on standing probably due to hydrolysis by H2O — store it in sealed ampoules under dry N2. [Skinner et al. Org Synth Coll Vol II 368 1943, IR: Nagai Bull Chem Soc Jpn 37 369 1964, Kelly & Segura J Am Chem Soc 56 2497 1934, Beilstein 17/11 V 66.]

Itaconic anhydride Preparation Products And Raw materials

Raw materials

Itaconic acid Citric acid

Preparation Products

More

Less

Itaconic anhydride Suppliers

Americas 1 Belgium 1 China 218 Europe 1 Germany 3 India 4 Japan 4 Slovakia 1 Switzerland 1 United Kingdom 7 United States 32 Global 273

BOC Sciences

Tel: 1-631-485-4226; 16314854226
Email: info@bocsci.com
Country: United States
ProdList: 14055
Advantage: 65

Alfa Chemistry

Tel: 1-516-6625404
Fax: 1-516-927-0118
Email: support@alfa-chemistry.com
Country: United States
ProdList: 9171
Advantage: 60

Alfa Chemistry

Tel
Fax: 1-516-927-0118
Email: Info@alfa-chemistry.com
Country: United States
ProdList: 24072
Advantage: 58

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

TargetMol Chemicals Inc.

Tel
Email: support@targetmol.com
Country: United States
ProdList: 38632
Advantage: 58

AlliChem, LLC

Tel: --
Fax: --
Email: sales@allichemllc.com
Country: United States
ProdList: 6516
Advantage: 60

Monomer Polymer & Dajac Labs

Tel: --
Fax: --
Email: info@monomerpolymer.com
Country: United States
ProdList: 1609
Advantage: 58

United States Biological

Tel: --
Fax: --
Email: chemicals@usbio.net
Country: United States
ProdList: 6214
Advantage: 80

Beijing Lys Chemicals Co, LTD.

Tel: --
Fax: --
Email: jiayanyong@lyschem.com
Country: United States
ProdList: 710
Advantage: 58

Combi-Blocks Inc.

Tel: --
Fax: --
Email: sales@combi-blocks.com
Country: United States
ProdList: 6618
Advantage: 69

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

TCI America

Tel: --
Fax: --
Email: sales@tciamerica.com
Country: United States
ProdList: 6909
Advantage: 75

Frontier Scientific, Inc.

Tel: --
Fax: --
Email: sales@frontiersci.com
Country: United States
ProdList: 6222
Advantage: 86

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

Chemstock Inc.

Tel: --
Fax: --
Email: mail@chemstock.com
Country: United States
ProdList: 575
Advantage: 34

Advance Scientific & Chemical

Tel: --
Fax: --
Email: sales@advance-scientific.com
Country: United States
ProdList: 6419
Advantage: 71

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

HONEST JOY HOLDINGS LIMITED

Tel: --
Fax: --
Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

Acros Organics USA

Tel: --
Fax: --
Email: eveleth@fisherchem.com
Country: United States
ProdList: 3846
Advantage: 81

City Chemical LLC

Tel: --
Fax: --
Email: sales@citychemical.com
Country: United States
ProdList: 6708
Advantage: 72

Chembargains

Tel: --
Fax: --
Email: info@chembargains.com
Country: United States
ProdList: 178
Advantage: 69

ChemService Inc.

Tel: --
Fax: --
Country: United States
ProdList: 6379
Advantage: 68

INDOFINE Chemical Company, Inc.

Tel: --
Fax: --
Email: chemical@indofinechemical.com
Country: United States
ProdList: 6176
Advantage: 69

Spectrum Chemicals & Laboratory Products

Tel: --
Fax: --
Email: sales@spectrumchemical.com
Country: United States
ProdList: 6699
Advantage: 77

MP Biomedicals, Inc.

Tel: --
Fax: --
Country: United States
ProdList: 6561
Advantage: 81

ASDI Incorporated

Tel: --
Fax: --
Email: customerservice@asdi.net
Country: United States
ProdList: 6922
Advantage: 67

BOSCHE SCIENTIFIC, LLC

Tel: --
Fax: --
Email: Sales@BoscheSci.com
Country: United States
ProdList: 6477
Advantage: 55

Alfa Aesar

Tel: --
Fax: --
Email: tech@alfa.com
Country: United States
ProdList: 6814
Advantage: 81

ChemPacific Corporation

Tel: --
Fax: --
Email: sales@chempacific.com
Country: United States
ProdList: 6891
Advantage: 51

City Chemicals Corporation

Tel: --
Fax: --
Country: United States
ProdList: 6460
Advantage: 72

Eastern Chemical Corp.

Tel: --
Fax: --
Email: eastern@u-g.com
Country: United States
ProdList: 2786
Advantage: 34

Monomer-Polymer & Dajac Laboratories, Inc.

Tel: --
Fax: --
Email: monomerpolymer@comcast.net
Country: United States
ProdList: 1989
Advantage: 60

More

Less

View Lastest Price from Itaconic anhydride manufacturers

Jinan Finer Chemical Co., Ltd

Product: Itaconic anhydride 2170-03-8
Price: US $2.00/KG
Min. Order: 1KG
Purity: ≥99.5%
Supply Ability: 1000mt/year
Release date: 2023-04-24

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Itaconic anhydride 2170-03-8
Price: US $25.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-11

Baoji Guokang Bio-Technology Co., Ltd.

Product: Itaconic anhydride 2170-03-8
Price: US $48.00/KG
Min. Order: 100KG
Purity: 98%
Supply Ability: 1-20mt
Release date: 2021-06-08

2170-03-8, Itaconic anhydrideRelated Search:

Glutaric anhydride Trimellitic Anhydride Phthalic anhydride Polysebacic acid anhydride Dodecenylsuccinic anhydride 1,4-DIAMINOBUTANE Trifluoromethanesulfonic anhydride Succinic acid Isatoic Anhydride 2,3-Butanedione Dimethyl succinate Di-tert-butyl dicarbonate Itaconic acid Dimethylglyoxime CIS-BUTENEDIOIC ANHYDRIDE Erythromycin Estolate Succinic anhydride Succinimide

2-Methylenebutanedioic anhydride

Methylenesuccinic acid anhydride

3,4-Dihydro-3-methylene-2,5-furandione Methylenesuccinic Anhydride

Itaconic anhydride(2-Methylenesuccinic anhydride)

Itaconic anhydride 95%

Itaconic anhydride,98%

ITACONIC ANHYDIDE

ITACONIC ANHYDRIDE

METHYLENESUCCINIC ANHYDRIDE

3,4-DIHYDRO-3-METHYLENE-2,5-FURANDIONE

2-METHYLENESUCCINIC ANHYDRIDE

3-Methylenedihydro-2,5-furandione

dihydro-3-methylene-2,5-furandione

dihydro-3-methylene-5-furandione

Itaconic acid anhydride

Succinic anhydride, methylene-

Propylene dicarboxylic anhydride

2,5-Furandione, dihydro-3-methylene-

Itaconic anhydride 98.5%

ITACONIC AHYDRIDE

3-Methylenedihydrofuran-2,5-dione

3-methylideneoxolane-2,5-dione

ITACONIC ANHYDRIDE 95+%

3-methyleneoxolane-2,5-dione

ItaconicAnhydride&gt

Itaconic anhydride 2170-03-8

Itaconic anhydride (6CI)

2170-03-8

98-68-4

2170-03-08

Organic Building Blocks

Building Blocks

Carbonyl Compounds

Carboxylic Acid Anhydrides

ANHYDRIDE