7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene

Product Name: 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene
CAS No.: 319906-45-1
Chemical Name: 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene
Synonyms: 2-Bromo-7-iodo-9,9-d;2-Bromo-7-iodo-9,9-dimethyl-fluoren;2-Bromo-7-iodo-9,9-dimethylfluorene;7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene;2-Bromo-7-iodo-9,9-dimethyl-9H-fluorene;9H-Fluorene, 2-bromo-7-iodo-9,9-dimethyl-
CBNumber: CB82128658
Molecular Formula: C15H12BrI
Formula Weight: 399.06
MOL File: 319906-45-1.mol

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7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene Property

Boiling point:: 424.2±38.0 °C(Predicted)
Density: 1.773
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Biosynth Carbosynth

Product number: FB149471
Product name: 2-Bromo-7-iodo-9,9-dimethyl-9H-fluorene
Packaging: 500mg
Price: $75
Updated: 2021/12/16

AK Scientific

Product number: 3519AB
Product name: 2-Bromo-7-iodo-9,9-dimethyl-9H-fluorene
Packaging: 5g
Price: $178
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB149471
Product name: 2-Bromo-7-iodo-9,9-dimethyl-9H-fluorene
Packaging: 2g
Price: $225
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB149471
Product name: 2-Bromo-7-iodo-9,9-dimethyl-9H-fluorene
Packaging: 1g
Price: $129
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB149471
Product name: 2-Bromo-7-iodo-9,9-dimethyl-9H-fluorene
Packaging: 5G
Price: $449
Updated: 2021/12/16

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7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene Chemical Properties,Usage,Production

Synthesis

28320-31-2

319906-45-1

Synthesis of Intermediate 1: 30.27 g (110.8 mmol) of 9,9-dimethyl-2-bromofluorene, 16.9 g (66.5 mmol) of iodine (I2) and 15.2 g (66.5 mmol) of periodate (H5IO6) were dissolved in acetic acid (AcOH). To this solution, dilute aqueous sulfuric acid (H2SO4) was slowly added dropwise and the reaction was stirred at 50°C for 5 hours. Upon completion of the reaction, deionized water was added to the reaction mixture and a solid precipitate was precipitated. The precipitate was collected by filtration to give 37.6 g of intermediate 1 in 85% yield. The resulting compound was structurally confirmed by high resolution mass spectrometry (HR-MS).

References

[1] Angewandte Chemie - International Edition, 2016, vol. 55, # 44, p. 13724 - 13728
[2] Angew. Chem., 2016, vol. 128, p. 13928 - 13932,5
[3] Patent: EP2292603, 2011, A1. Location in patent: Page/Page column 24
[4] Patent: EP2738166, 2014, A1. Location in patent: Paragraph 0153-0154
[5] Patent: EP2762478, 2014, A1. Location in patent: Paragraph 0179; 0180

7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene Preparation Products And Raw materials

Raw materials

Preparation Products

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7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene Suppliers

China 112 Germany 1 United Kingdom 1 United States 5 Global 119

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View Lastest Price from 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene 319906-45-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-04-07

Henan Fengda Chemical Co., Ltd

Product: 2-bromo-7-iodo-9,9-dimethyl-9H-fluorene 319906-45-1
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-01-02

Career Henan Chemical Co

Product: 7-Bromo-2-iodo-9,9-dimethyl-9H-fluorene 319906-45-1
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: Customized
Release date: 2018-12-19

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319906-45-1

C15H12BrI