2,2,2-Trichloro-1-phenylethyl acetate

Product Name: 2,2,2-Trichloro-1-phenylethyl acetate
CAS No.: 90-17-5
Chemical Name: 2,2,2-Trichloro-1-phenylethyl acetate
Synonyms: ROSALIN;ROSE CRYSTALS;Rosacetol;Rosephenone;rose acetate;Rosaliu;ROSATOL;α-(TrichL;Rose Ester;Crystal rose
CBNumber: CB8215486
Molecular Formula: C10H9Cl3O2
Formula Weight: 267.53
MOL File: 90-17-5.mol

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2,2,2-Trichloro-1-phenylethyl acetate Property

Melting point:: 86-89 °C(lit.)
Boiling point:: 282°C(lit.)
Density: 1.3807 (estimate)
vapor pressure: 0.13Pa at 25℃
solubility: 28.72g/L in organic solvents at 20 ℃
form: powder to crystal
pka: 0.003[at 20 ℃]
color: White to Almost white
Odor: at 10.00 % in dipropylene glycol. heavy deep rose floral powdery balsamic soapy
Odor Type: floral
Water Solubility: 16.56mg/L at 25℃
Stability:: Stable. Incompatible with strong oxidizing agents.
LogP: 3.535 at 25℃
CAS DataBase Reference: 90-17-5(CAS DataBase Reference)
NIST Chemistry Reference: Benzenemethanol, «alpha»-(trichloromethyl)-, acetate(90-17-5)
EPA Substance Registry System: Benzenemethanol, .alpha.-(trichloromethyl)-, acetate (90-17-5)

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Safety

WGK Germany: 2
RTECS: AJ8375000
HS Code: 2915.39.2000
Toxicity: LD50 orl-rat: 6800 mg/kg FCTXAV 13,681,75

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P233Keep container tightly closed.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304IF INHALED:

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P340Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P362Take off contaminated clothing and wash before reuse.

P403Store in a well-ventilated place.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: T3122
Product name: α-(Trichloromethyl)benzyl Acetate
Purity: >98.0%(GC)
Packaging: 25g
Price: $33
Updated: 2024/03/01

TCI Chemical

Product number: T3122
Product name: α-(Trichloromethyl)benzyl Acetate
Purity: >98.0%(GC)
Packaging: 250g
Price: $81
Updated: 2024/03/01

AK Scientific

Product number: Z3616
Product name: alpha-(Trichloromethyl)benzylacetate
Packaging: 25g
Price: $161
Updated: 2021/12/16

AK Scientific

Product number: J56717
Product name: alpha-(Trichloromethyl)benzylacetate
Packaging: 1g
Price: $20
Updated: 2021/12/16

Crysdot

Product number: CD12010783
Product name: 2,2,2-Trichloro-1-phenylethylacetate
Purity: 95+%
Packaging: 100g
Price: $50
Updated: 2021/12/16

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2,2,2-Trichloro-1-phenylethyl acetate Chemical Properties,Usage,Production

Chemical Properties

white powder

Chemical Properties

2,2,2-Trichloro-1-phenylethyl acetate forms white crystals (mp 88 °C) and has a weak, very natural, lasting rose odor.
The ester is prepared from ??-trichloromethylbenzyl alcohol, for example, by reaction with acetic anhydride. The alcohol can be prepared by one of the following methods:
1) Addition of trichloroacetaldehyde (chloral) to benzene in the presence of aluminum chloride.
2) Reaction of benzaldehyde with chloroform in the presence of potassium hydroxide.
??-Trichloromethylbenzyl acetate is a stable rose fragrancewith excellent fixative properties. It is preferentially used in soaps, powders, and bath salts.

Occurrence

Has apparently not been reported to occur in nature.

Uses

Perfumes, fixative for essential oils and perfumes.

Preparation

By the reaction of benzene and chloral, in the presence of a catalyst, followed by acetylation.

Definition

ChEBI: Alpha-Trichloromethylbenzyl acetate is a carboxylic ester. It is functionally related to a benzyl alcohol.

Flammability and Explosibility

Non flammable

Trade name

Rosalin (Yinghai)

Safety Profile

Mildly toxic by ingestion. A skinirritant. When heated to decomposition it emits toxicfumes of Clí.

Solubility in organics

Insoluble in water, somewhat soluble in alcohol, soluble in most perfume oils. The volubility in cold alcohol is sufficient for perfume composition purposes, but not to have a concentrated solution of the material on hand.

2,2,2-Trichloro-1-phenylethyl acetate Preparation Products And Raw materials

Raw materials

Chloral Potassium hydroxide Acetyl chloride Aluminum chloride Benzene

Preparation Products

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2,2,2-Trichloro-1-phenylethyl acetate Suppliers

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View Lastest Price from 2,2,2-Trichloro-1-phenylethyl acetate manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: 2,2,2-Trichloro-1-phenylethyl acetate 90-17-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-06-29

Jinan Finer Chemical Co., Ltd

Product: 2,2,2-Trichloro-1-phenylethyl acetate 90-17-5
Price: US $0.00/Kg/Drum
Min. Order: 1KG
Purity: 99%
Supply Ability: 200mt/year
Release date: 2021-06-18

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 2,2,2-Trichloro-1-phenylethyl acetate 90-17-5
Price: US $45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-11-29

90-17-5, 2,2,2-Trichloro-1-phenylethyl acetateRelated Search:

Butyl acetate Methyl 2,2-dimethylphenylacetate Ethyl acetate Benzoyl peroxide Benzyl acetate Methyl 4-methylbenzoate Trichloroacetic acid Benzyl benzoate Benzyl chloromethyl ether Benzyl chloride Cellulose acetate Ammonium acetate 4-Methylphenylacetic acid Methyl 4-(bromomethyl)benzoate 2-Methylphenylacetic acid SODIUM TRICHLOROACETATE Isopropyl acetate Vinyl acetate

-(Trichloromethyl)benzylacetate

ROSE CRYSTALS

ROSALIN

TRICHLOROMETHYL PHENYL CARBINYL ACETATE

ALPHA-(TRICHLOROMETHYL)BENZYL ACETATE

rose acetate

Acetic acid, alpha-(trichloromethyl)benzyl ester

aceticacid,alpha-(trichloromethyl)benzylester

alpha-(Trichloromethyl)-, acetate

alpha-(trichloromethyl)-benzenemethanoacetate

alpha-(trichloromethyl)benzenemethanolacetate

alpha-(trichloromethyl)-benzylalcohoacetate

alpha-(trichloromethyl)benzylalcoholacetate

Benzyl alcohol, alpha-(trichloromethyl)-, acetate

Benzylalcohol,.alpha.-(trichloromethyl)-,acetate

Rosacetol

Rosaliu

Rose Ester

Rosephenone trichloro methyl phenyl-carbinyl acetate

Trichlor phenyl methyl carbinyl acetate

A,A,A-TRICHLOROMETHYLPHENYLCARBINYL ACETATE

2,2,2-TRICHLORO-1-PHENYLETHYLACETATE

ROSALIN (ROSE ACETATE)

ROSE CRYSTALS 97+%

ALPHA-(TRICHLOROMETHYL)BENZYL ACETATE, 9 9%

2-Trichloro-1-phenylethyl acetate

Rosephenone

Trichloromethyl-benzyl

Benzenemethanol, .alpha.-(trichloromethyl)-, acetate

ALPHA-(TRICHLOOMETHYL)BENZYLACETATE

TRICHLORMETHYLPHENYLCARBINYLACETATE

2,2,2-Trichlor-1-phenylethylacetat

ROSATOL

A-(TRICHLOROMETHYL)BENZYL ACETATE

Benzenemethanol, α-(trichloromethyl)-, acetate

alpha-(Trichloromethyl)benzyl acetate 99%

BenzeneMethanol, a-(trichloroMethyl)-, 1-acetate

1,1,1-Trichloro-2-acetoxy-2-phenylethane

Acetic acid α-(trichloromethyl)benzyl ester

Acetic acid α-trichloromethylbenzyl ester

(2,2,2-trichloro-1-phenyl-ethyl) ethanoate

acetic acid (2,2,2-trichloro-1-phenyl-ethyl) ester

α-(Trichloromethyl)benzyl acetate, Rose Crystals

6-methoxy-1H-1,3,5-triazin-2-one

Benzenemethanol, .alpha.-(trichloromethyl)-, 1-acetate

alpha-(Trichloromethyl)benzyl Acetate/C10H9Cl3O2

Benzenemethanol, α-(trichloromethyl)-, 1-acetate

α-(Trichloromethyl)benzyl acetate

α-(TrichL

2,2,2-Trichloro-1-phenylethyl acetate USP/EP/BP

Factory supply high quality 2,2,2-Trichloro-1-phenylethyl acetate CAS 90-17-5

Rosacetolo (Rosalin)

Crystal rose

ROSE CRYSTAL EX. BENZALDEHYDE

90-17-5

CH3CO2CHCCl3C6H5

C11H9I3O2

C10 to C11