Reaction
ChemicalBook > CAS DataBase List > (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE

Reaction
Product Name
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
CAS No.
130004-33-0
Chemical Name
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
Synonyms
(S)-RuCl[(p-cymene(BINAP)Cl;S-(-)-BINAP-CHLORO(P-CYM;[RuCl(p-cymene)((S)-binap)]Cl;[RuCl(p-cymene)((S)-binap)]Cl >S-(-)-BINAP-CHLORO(P-CYMENE)RUTHENIUM CHLORIDE;[bis(diphenylphosphino)binaphthyl]chloro(p-cumene)RuCl;(S)-RuCl[(p-cyMene(BINAP)]Cl, 11% Ru, Product of UMicore;Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](...;-binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-binap)]Cl;(R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
CBNumber
CB8228824
Molecular Formula
C54H44Cl2P2Ru
Formula Weight
926.86
MOL File
130004-33-0.mol
More
Less

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Property

Melting point:
>100°C
storage temp. 
2-8°C
solubility 
Chloroform (Sparingly)
form 
Powder
color 
orange
Sensitive 
Air Sensitive
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
28439000
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692972
Product name
(S)-RuCl[(p-cymene(BINAP)]Cl
Packaging
500mg
Price
$53.2
Updated
2024/03/01
Sigma-Aldrich
Product number
692972
Product name
(S)-RuCl[(p-cymene(BINAP)]Cl
Packaging
100mg
Price
$36.1
Updated
2023/06/20
TCI Chemical
Product number
R0147
Product name
[RuCl(p-cymene)((S)-binap)]Cl
Purity
>90.0%(HPLC)
Packaging
200mg
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
R0147
Product name
[RuCl(p-cymene)((S)-binap)]Cl
Purity
>90.0%(HPLC)
Packaging
1g
Price
$168
Updated
2024/03/01
Strem Chemicals
Product number
44-0086
Product name
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl
Packaging
250mg
Price
$53
Updated
2024/03/01
More
Less

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Chemical Properties,Usage,Production

Reaction

This catalyst has shown to effect the highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.

Chemical Properties

Brown crystalline powder

Uses

Takasago Ligands and Complexes for Asymmetric Reactions

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE Suppliers

Alfa Chemistry
Tel
1-516-6625404
Fax
1-516-927-0118
Email
support@alfa-chemistry.com
Country
United States
ProdList
9171
Advantage
60
Protheragen-ING
Tel
+16313385890
Email
info@protheragen-ing.com
Country
United States
ProdList
3868
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
MilliporeSigma (Sigma-Aldrich Corp.)
Tel
--
Fax
--
Email
@sial.com
Country
United States
ProdList
5414
Advantage
58
Alichem Inc.
Tel
--
Fax
--
Email
sales@alichem.com
Country
United States
ProdList
6167
Advantage
58
Ivy Fine Chemicals
Tel
--
Fax
--
Email
sales@ivychem.com
Country
United States
ProdList
6493
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
More
Less

View Lastest Price from (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE 130004-33-0
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-04-21
Wuhan LPBchem Technology Co.,Ltd
Product
Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride/ (S)-RuCl[(p-cymene(BINAP)]Cl 130004-33-0
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50kg
Release date
2020-09-28
Career Henan Chemical Co
Product
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE 130004-33-0
Price
US $1.00/g
Min. Order
100g
Purity
98%min
Supply Ability
G/KG/T
Release date
2019-12-20

130004-33-0, (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDERelated Search:


  • [(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
  • (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
  • S-(-)-BINAP-CHLORO(P-CYMENE)RUTHENIUM CHLORIDE
  • (S)-(-)-2,2''-BIS(DIPHENYLPHOSPHINO)-1,1''-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
  • [bis(diphenylphosphino)binaphthyl]chloro(p-cumene)RuCl
  • (S)-RuCl[(p-cymene(BINAP)Cl
  • (R)-(+)-2,2'-[BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]CHLORO(P-CYMENE)RUTHENIUM
  • [(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
  • S-(-)-BINAP-CHLORO(P-CYM
  • [(1S)-(1,1'-Binaphthalene)-2,2'-diylbis-(diphenylphosphine)]-chloro-[(1,2,3,4,5,6)-1-methyl-4-(1-methylethyl)-benzene]-ruthenium chloride
  • (S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLO
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride, ca 5% MeOH of cryst.
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride,9
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cymene)ruthenium chloride, ca 5% MeOH of cryst., 97+%
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-binap)]Cl
  • (RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-
  • (RutheniuM(1+),[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-kP]]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]-,chloride (1:1) )
  • (S)-RuCl[(p-cyMene(BINAP)]Cl, 11% Ru, Product of UMicore
  • [RuCl(p-cymene)((S)-binap)]Cl
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride [RuCl(p-
  • [2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene]chloro(p-cymene)ruthenium Chloride
  • -binaphthyl](p-cymene)ruthenium(II) chloride,[RuCl(p-cymene)((S)-binap)]Cl
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cyMene)rutheniuM chloride, 97+%, ca 5% MeOH of cryst.
  • CHLORO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM (II) CHLORIDE
  • CHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL](P-CYMENE)RUTHENIUM (II) CHLORIDE
  • (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
  • [RuCl(p-cymene)((S)-binap)]Cl &gt
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) chloride/ (S)-RuCl[(p-cymene(BINAP)]Cl
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](...
  • (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
  • (S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]-CHLORO-(P-CYMENE)-RUTHENIUMCHLORIDE
  • Chloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II) Chloride
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalenechloro(p-cyMene)rutheniuM chloride
  • Ruthenium(1+), [1,1′-(1S)-[1,1′-binaphthalene]-2,2′-diylbis[1,1-diphenylphosphine-κP]]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-, chloride (1:1) (ACI)
  • 130004-33-0
  • C54H46ClP2RuCl
  • C54H46Cl2P2Ru
  • Ru