ChemicalBook > CAS DataBase List > 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE

Product Name
2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE
CAS No.
472-66-2
Chemical Name
2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE
Synonyms
FEMA 3474;β-Homocyclocitra;B-HOMOCYCLOCITRAL;β-Homocyclocitral;beta-Homocyclocitral;homo cyclocitral, beta;Ethyl ring high citral;2 6 6-TRIMETHYL-1-CYCLOHEXENE-1-ACET- &;2,6,6-trimethyl-1-cyclohexene-1-acetaldehyd;2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-ACETALDEHYDE
CBNumber
CB8231545
Molecular Formula
C11H18O
Formula Weight
166.26
MOL File
472-66-2.mol
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2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Property

Boiling point:
58-59 °C/0.4 mmHg (lit.)
Density 
0.941 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.485(lit.)
FEMA 
3474 | 2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-ACETALDEHYDE
Flash point:
191 °F
storage temp. 
2-8°C
Odor
at 10.00 % in dipropylene glycol. camphoreous cooling woody medicinal oily berry orris soapy
Odor Type
camphoreous
JECFA Number
978
LogP
3.94
EPA Substance Registry System
1-Cyclohexene-1-acetaldehyde, 2,6,6-trimethyl- (472-66-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
264679
Product name
2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde
Purity
technical grade, 80%
Packaging
1g
Price
$27.04
Updated
2024/03/01
Sigma-Aldrich
Product number
264679
Product name
2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde
Purity
technical grade, 80%
Packaging
5g
Price
$196
Updated
2024/03/01
Sigma-Aldrich
Product number
W347418
Product name
2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde
Purity
≥75%
Packaging
sample
Price
$81.9
Updated
2024/03/01
Sigma-Aldrich
Product number
W347418
Product name
2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde
Purity
≥75%
Packaging
25g
Price
$305
Updated
2024/03/01
Sigma-Aldrich
Product number
W347418
Product name
2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde
Purity
≥75%
Packaging
100g
Price
$896
Updated
2024/03/01
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2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Chemical Properties,Usage,Production

Uses

2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde can be used as a starting material to prepare:

  • (±)-Aeginetolide by oxidation in the presence of meta-chloroperoxybenzoic acid (m-CPBA).
  • (±)-Dihydroactinidiolide (a C11-terpenic lactone) via dehydration of key intermediate aeginetolide.

It can also be used as a key intermediate to synthesize drimane-related sesquiterpenes and substituted retinoic acid analogs.

Definition

ChEBI: 2,6,6-Trimethyl-1-cyclohexen-1-acetaldehyde is an aldehyde.

Taste threshold values

Taste characteristics at 15 ppm: cooling, woody, oily, soapy, citrus with a berry, orris-like nuance.

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Suppliers

China 62 Germany 1 India 1 Switzerland 1 United Kingdom 1 United States 7 Global 73
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View Lastest Price from 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE manufacturers

Anhui Yisheng Technology Co., LTD
Product
beta-Homocyclocitral 472-66-2
Price
US $260.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 Ton
Release date
2023-01-09
Hebei Mojin Biotechnology Co., Ltd
Product
2-(2,6,6-trimethylcyclohexen-1-yl)acetaldehyde 472-66-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-11
Hubei Harvest Chemical CO.,Ltd
Product
2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE 472-66-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100000000000
Release date
2023-03-11

472-66-2, 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDERelated Search:

7-EPI-10-DEACETYL-TAXOL Deacetyltaxol 10-DEACETYLCEPHALOMANNINE Docetaxel Baccatine III 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE 10-Deacetylbaccatin III Cephalomannine Paclitaxel 7-EPI-TAXOL PACLITAXEL, [3H(G)] 2'-ACETYLTAXOL 2,6,6-trimethyl-2-cyclohexene-1-acetaldehyde XYLOSYLTAXOL PACLITAXEL-[BENZOATE RING-UL-14C] PACLITAXEL C 10-DEACETYLTAXOL C 10-DEACETYL-7-XYLOSYLTAXOL

  • (2,6,6-Trimethyl-1-cyclohexen-1-yl)acetaldehyde
  • 2,6,6-trimethyl-1-cyclohexene-1-acetaldehyd
  • B-HOMOCYCLOCITRAL
  • FEMA 3474
  • 2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-ACETALDEHYDE
  • 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE
  • 2-(2,6,6-triMethylcyclohex-1-en-1-yl)acetaldehyde
  • 2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde technical grade, 80%
  • 2-(2,6,6-trimethylcyclohexen-1-yl)acetaldehyde
  • 2 6 6-TRIMETHYL-1-CYCLOHEXENE-1-ACET- &
  • 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDE HYDE, TECH., 80%
  • beta-Homocyclocitral
  • 1-Cyclohexene-1-acetaldehyde, 2,6,6-trimethyl-
  • homo cyclocitral, beta
  • β-Homocyclocitral
  • 2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde,β-Homocyclocitral
  • Ethyl ring high citral
  • β-Homocyclocitra
  • 2,6,6- trimethyl -1- cyclohexenyl acetaldehyde
  • 2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde >=75%
  • 472-66-2
  • Organic Building Blocks
  • Building Blocks
  • Aldehydes
  • Carbonyl Compounds
  • C10 to C21
  • Aldehydes
  • Building Blocks
  • C10-C12
  • Carbonyl Compounds
  • Chemical Synthesis
  • Organic Building Blocks