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(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE

Product Name
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
CAS No.
38465-86-0
Chemical Name
(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
Synonyms
methyl(diphenyl)phosphane;(bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i);1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%;1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate;1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM;(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate;(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
CBNumber
CB8242424
Molecular Formula
C34H38F6IrP3
Formula Weight
845.79
MOL File
38465-86-0.mol
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(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Property

Melting point:
224 °C (dec.) (lit.)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Crystalline Powder
color 
Red
Water Solubility 
Soluble in acetone. Insoluble in water.
Sensitive 
Air & Moisture Sensitive
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
337455
Product name
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Purity
97%
Packaging
50mg
Price
$30.3
Updated
2024/03/01
Sigma-Aldrich
Product number
337455
Product name
(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Purity
97%
Packaging
500mg
Price
$176
Updated
2024/03/01
Alfa Aesar
Product number
018809
Product name
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging
0.5g
Price
$150
Updated
2023/06/20
Alfa Aesar
Product number
018809
Product name
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging
2g
Price
$457
Updated
2023/06/20
TRC
Product number
C984583
Product name
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate
Packaging
25mg
Price
$45
Updated
2021/12/16
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(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Chemical Properties,Usage,Production

Chemical Properties

red crystalline powder

Uses

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh2Me)2]PF6, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH2(solv)2(PPh2Me)2]PF6 which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.

(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE Suppliers

Belgium 1 China 48 Germany 1 India 1 Japan 1 Switzerland 1 United Kingdom 3 United States 6 Global 62
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United Kingdom
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MOLEKULA Ltd.
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kevinbanks@molekula.com
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VWR International
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solutions@vwr.com
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38465-86-0, (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATERelated Search:

METHYLDIPHENYLPHOSPHINE 1,3-CYCLOOCTADIENE (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE 1,5-Cyclooctadiene

  • (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE
  • 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate
  • (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYL-P HOSPHINE)IRIDIUM(I) PF6, 97%
  • Iridium(1+), (1,2,5,6-.eta.)-1,5-cyclooctadienebis(methyldiphenylphosphine)-, hexafluorophosphate(1-)
  • methyl(diphenyl)phosphane
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(i)
  • (bis(methyldiphenylphosphine))(cyclooctadiene)iridium PF6
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate,97%
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(Ⅰ) hexafluorophosphate
  • 1,5-CYCLOOCTADIENE BIS(METHYLDIPHENYLPHOSPHANE) HEXAFLUOROPHOSPHATE IRIDIUM
  • (1,5-CYCLOOCTADIENE)BIS(METHYLDIPHENYLPHOSPHINE)IRIDIUM(I) HEXAFLUOROPHOSPHATE ISO 9001：2015 REACH
  • 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium hexafl...
  • (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate, [Ir(COD)(PPh2Me)2]PF6
  • 38465-86-0
  • C34H38F6lrP3
  • C34H38F6IrP3
  • C34H38IrP2F6P
  • C42H50F6IrP3
  • C36H46F6IrP3
  • Iridium
  • Catalysis and Inorganic Chemistry
  • Ir
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Iridium