1,2-NAPHTHOQUINONE

ChemicalBook > CAS DataBase List > 1,2-NAPHTHOQUINONE

1,2-NAPHTHOQUINONE

Product Name: 1,2-NAPHTHOQUINONE
CAS No.: 524-42-5
Chemical Name: 1,2-NAPHTHOQUINONE
Synonyms: 1,2-Naphthaquinone;NSC 9831;SID 8139964;1,2-Naftochinon;o-Naphthoquinone;1,2-NAPHTHOQUINONE;BETA-NAPHTHOQUINONE;1,2-NAPHTHALENEDIONE;NAPHTHOQUINONE, 1,2-;ORTHO-NAPHTHOQUINONE
CBNumber: CB8244488
Molecular Formula: C10H6O2
Formula Weight: 158.15
MOL File: 524-42-5.mol

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1,2-NAPHTHOQUINONE Property

Melting point:: 139-142 °C (dec.) (lit.)
Boiling point:: 243.22°C (rough estimate)
Density: 1.450 g/cm3 (25℃)
refractive index: 1.5300 (estimate)
storage temp.: 2-8°C
solubility: Chloroform (Slightly), DMSO (Slightly)
form: Crystalline Mass or Waxy Solid
color: Colorless or white to pale yellow
Merck: 14,6394
BRN: 606546
Stability:: Light Sensitive
CAS DataBase Reference: 524-42-5(CAS DataBase Reference)
EPA Substance Registry System: 1,2-Naphthoquinone (524-42-5)

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Safety

Hazard Codes: Xn,Xi,C,F
Risk Statements: 22-36/37/38-34-11-25
Safety Statements: 26-36-45-36/37/39-16-37/39-28A
RIDADR: 2811
WGK Germany: 3
RTECS: QL7000000
Hazard Note: Irritant
HS Code: 29146990
Hazardous Substances Data: 524-42-5(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: N0041
Product name: 1,2-Naphthoquinone
Purity: >95.0%(HPLC)(W)
Packaging: 1g
Price: $45
Updated: 2024/03/01

TCI Chemical

Product number: N0041
Product name: 1,2-Naphthoquinone
Purity: >95.0%(HPLC)(W)
Packaging: 5g
Price: $120
Updated: 2024/03/01

TRC

Product number: N368485
Product name: 1,2-Naphthoquinone(90%)
Packaging: 10g
Price: $410
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 97658
Product name: 1,2-Naphthquinone
Packaging: 5G
Price: $590
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0017187
Product name: 1,2-NAPHTHOQUINONE
Purity: 95.00%
Packaging: 1G
Price: $644.46
Updated: 2021/12/16

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1,2-NAPHTHOQUINONE Chemical Properties,Usage,Production

Chemical Properties

brown powder

Uses

Chemical reagent and intermediate.

Uses

1,2-Naphthquinone is a highly reactive quinone species which aids in modulating cellular homeostasis and electrophilic signal transduction pathways.

Uses

1,2-Naphthoquinone was employed as mediator during electrochemical mapping of redox activity in normal human breast (MCF-10A) cells by scanning electrochemical microscopy (SECM).

Definition

ChEBI: 1,2-naphthoquinone is the parent structure of the family of 1,2-naphthoquinones, in which the oxo groups of the quinone moiety are at positions 1 and 2 of the naphthalene ring. It is a metabolite of naphthalene and is found in diesel exhaust particles. It has a role as a carcinogenic agent and an aryl hydrocarbon receptor agonist. It derives from a hydride of a naphthalene.

Synthesis Reference(s)

Tetrahedron Letters, 25, p. 603, 1984 DOI: 10.1016/S0040-4039(00)99949-0
The Journal of Organic Chemistry, 51, p. 5390, 1986 DOI: 10.1021/jo00376a061

General Description

Golden yellow needles or brown powder. Decomposes to a bluish-black color on standing.

Air & Water Reactions

The neat chemical may be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

Ketones, such as 1,2-NAPHTHOQUINONE, are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.

Hazard

Irritant

Health Hazard

ACUTE/CHRONIC HAZARDS: 1,2-NAPHTHOQUINONE is an irritant. When heated to decomposition it emits acrid smoke and fumes.

Fire Hazard

Flash point data for 1,2-NAPHTHOQUINONE are not available. 1,2-NAPHTHOQUINONE is probably combustible.

Purification Methods

Crystallise the quinone from ether (red needles) or *benzene (orange leaflets). [Beilstein 7 IV 2417.]

1,2-NAPHTHOQUINONE Preparation Products And Raw materials

Raw materials

Preparation Products

POTASSIUM 1,2-NAPHTHOQUINONE-4-SULFONIC ACID 2-Hydroxy-1,4-naphoquinone

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View Lastest Price from 1,2-NAPHTHOQUINONE manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd

Product: 1,2-NAPHTHOQUINONE 524-42-5
Price: US $50.00/kg
Min. Order: 1kg
Purity: 99.10%
Supply Ability: 50000kg
Release date: 2024-04-24

Hebei Guanlang Biotechnology Co., Ltd.

Product: 1,2-NAPHTHOQUINONE 524-42-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2022-09-23

Hebei Mojin Biotechnology Co., Ltd

Product: 1,2-NAPHTHOQUINONE 524-42-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000tons
Release date: 2023-07-31

524-42-5, 1,2-NAPHTHOQUINONERelated Search:

4-Chloro-1,2-naphthalenedione 1,2-Naphthoquinone-4-sulfoni POTASSIUM 1,2-NAPHTHOQUINONE-4-SULFONIC ACID DIHYDROTANSHINONE 1,2-NAPHTHOQUINONE Cryptotanshinone 1,4-Naphthoquinone, 2,3-dichloro-,2,3-Dichloro-1,4-naphthoquinone (dichlone),2,3-dichloro-4-naphthoquinon 1,4-dihydroxynaphthalene,1:1mixturewith1,4-naphthoquinon Menadione 1,4-Naphthoquinone, 2-hydroxy-,2-hydroxy-4-naphthoquinon 1,2-NAPHTHOQUINONE-2-DIAZIDO-4-SULFONYL CHLORIDE 1,4-Naphthoquinone, 2-hydroxy-3-(3-methyl-2-butenyl)-,2-hydroxy-3-(3-methyl-2-butenyl)-4-naphthoquinon 5,12-NAPHTHACENEQUINONE SODIUM 1,2-NAPHTHOQUINONE-2-DIAZIDO-5-SULFONATE 4,8-diamino-2-bromo-1,5-naphthoquinone Menlaquinone 9 2,3,4,4'-Tetrahydroxybenzophenone 1,2-naphthoquinonediazido-5-sulfonate 1 3-BIS(2 6-DIISOPROPYLPHENYL)IMIDAZOL-&

1,2-dihydro-1,2-diketo-naphthalene

1,2-Naftochinon

1,2-Naphthaquinone

Dapoxetine Impurity S

o-Naphthoquinone

NAPHTHOQUINONE, 1,2-

BETA-NAPHTHOQUINONE

1,2-NAPHTHALENEDIONE

1,2-NAPHTHOQUINONE

1,2-naphthoquinone (beta)

1,2-NAPHTHOQUINONE TECH 97%

1,2-Naphthoquinone, tech., 95%

NAPTHOQUINONE,1,2-(RG)

1,2-NAPHTHOQUINONE TECH 95+%

1,2-Naphthoquinone, 95%,tech

1,2-Dihydronaphthalene-1,2-dione

NAPHTHOQUINONE,1,2-(RG)

1,2-Naphthoquinone, tech., 95% 10GR

ORTHO-NAPHTHOQUINONE

1,2-Naphthoquinone 97%

NSC 9831

SID 8139964

1,2-Naphthoquinone, 94%, tech.

1,2-Naphthoquinone&gt

524-42-5

C10

Carbonyl Compounds

Building Blocks

Ketones

Organic Building Blocks

Anthraquinones, Hydroquinones and Quinones

Intermediates of Dyes and Pigments

Bioactive Small Molecules

Building Blocks

C10

Carbonyl Compounds

Cell Biology

Chemical Synthesis

Ketones

Organic Building Blocks