Reaction
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Bis(acetonitrile)dichloropalladium(II)

Reaction
Product Name
Bis(acetonitrile)dichloropalladium(II)
CAS No.
14592-56-4
Chemical Name
Bis(acetonitrile)dichloropalladium(II)
Synonyms
BIS(ACETONITRILE)PALLADIUM(II) DICHLORIDE;(MeCN)2PdCl2;bis(acetonitrile)dichloropalladium;Palladium, bis(acetonitrile)dichloro-;TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;DICHLOROBIS(ACETONITRILE)PALLADIUM(II);BIS(ACETONITRILE)PALLADIUM(II) CHLORIDE;e)dichL;Bis(acetonitriL;Bis(Acetonitrile)Pd(II)
CBNumber
CB8245652
Molecular Formula
C4H6Cl2N2Pd
Formula Weight
259.43
MOL File
14592-56-4.mol
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Bis(acetonitrile)dichloropalladium(II) Property

Melting point:
300 °C
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Soluble in acetonitrile, acetone, chloroform
form 
Fine Crystalline Powder
color 
Orange to rust-brown
Water Solubility 
insoluble
CAS DataBase Reference
14592-56-4(CAS DataBase Reference)
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Safety

Hazard Codes 
T,Xn
Risk Statements 
23/24/25-36/37/38-20/21/22
Safety Statements 
16-27-36/37-45-36-26
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
TSCA 
No
HazardClass 
6.1
PackingGroup 
III
HS Code 
28439090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
225657
Product name
Bis(acetonitrile)dichloropalladium(II)
Purity
99%
Packaging
500mg
Price
$77
Updated
2024/03/01
Sigma-Aldrich
Product number
225657
Product name
Bis(acetonitrile)dichloropalladium(II)
Purity
99%
Packaging
5g
Price
$502
Updated
2024/03/01
TCI Chemical
Product number
B1676
Product name
Bis(acetonitrile)palladium(II) Dichloride
Purity
>98.0%(T)
Packaging
1g
Price
$279
Updated
2024/03/01
TCI Chemical
Product number
B1676
Product name
Bis(acetonitrile)palladium(II) Dichloride
Purity
>98.0%(T)
Packaging
5g
Price
$1046
Updated
2024/03/01
Alfa Aesar
Product number
010002
Product name
Bis(acetonitrile)dichloropalladium(II), Pd 40.5%
Packaging
1g
Price
$123
Updated
2023/06/20
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Bis(acetonitrile)dichloropalladium(II) Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.
  8. Catalyst used for the direct C-H arylation of isoxazoles at the 5 position.

Chemical Properties

Light yellow to Brown powder to crystaline.

Physical properties

Bis(acetonitrile)dichloropalladium(II) is a yellow-brown solid that is soluble in organic solvents. It is a reagent and a catalyst for reactions that require soluble Pd(II).The compound is similar to bis(benzonitrile)palladium dichloride. 

Uses

suzuki reaction

Uses

It is used as a catalyst in an ether-directed aza-Claisen rearrangement. Also used in cyclization and cross-coupling reactions. It is applied for olefin isomerization, preparation of acetals and hemiacetal esters.

Uses

Catalyst used in an ether-directed aza-Claisen rearrangement.

Application

Synthesis of Oxindoles

To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), Bis(acetonitrile)dichloropalladium(II) (3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to room temperature, the reaction is diluted with EtOAc and filtered with a glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.

Preparation

Bis(acetonitrile)palladium dichloride is prepared by reacting two acetonitrile ligands and palladium(II) chloride.

General Description

This product has been enhanced for catalytic efficiency.

Bis(acetonitrile)dichloropalladium(II) Preparation Products And Raw materials

Raw materials

Acetonitrile Palladium chloride Dichloromethane

Preparation Products

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Bis(acetonitrile)dichloropalladium(II) Suppliers

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View Lastest Price from Bis(acetonitrile)dichloropalladium(II) manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Bis(acetonitrile)dichloropalladium(II) 14592-56-4
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5tons
Release date
2024-12-03
Hebei Mojin Biotechnology Co., Ltd
Product
Bis(acetonitrile)dichloropalladium(II) 14592-56-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-08-15
henan kanbei chemical co.,ltd
Product
Bis(acetonitrile)dichloropalladium(II) 14592-56-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23

14592-56-4, Bis(acetonitrile)dichloropalladium(II)Related Search:

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  • PALLADIUM(II) CHLORIDE-DIACETONITRILE COMPLEX
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  • (II)Bis(acetonitrile)dichloropalladium(II)
  • TRANS-BIS(ACETONITRILE)PALLADIUM(II) CHL
  • Bis(acetonitrile)palladiuM(II) chloridel
  • Bis(acetonitrile)-palladium(II) chloride (41% Pd) for synthesis
  • DICHLOROBIS(ACETONITRILE)PALLADIUM(II)
  • DICHLOROBIS(ACETONITRILE)PALLADIUM(III)
  • BIS(ACETONITRILE)DICHLOROPALLADATE (II)
  • BIS(ACETONITRILE)DICHLOROPALLADIUM(II)
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  • bis (acetontrile) dichloropalladium (II)
  • BIS(ACETONITRILE)DICHLOROPALLADIUM(II), 99.99%
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  • Bis(Acetonitrile)Pd(II)
  • palladium(2+) bis(acetonitrile) dichloride
  • Bis(Acetonitrile)Dichloropalladium (II) extrapure, 99%, ~41% Pd
  • DICHLOROBIS (ACETONITRILE) PALLADIUM (II) For Synthesis
  • Di-(acetonitrile) palladium chloride
  • chloranuidylpalladiobis(ylium)]chloranuide
  • Acetonitrile-dichloropalladium
  • 14592-56-4
  • C4H6Cl2N2Pd
  • C4Cl4N2Pd
  • C4H6N2PdCl2
  • Catalysis and Inorganic Chemistry
  • Homogeneous Pd Catalysts
  • Transition Metal Compounds