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3-Aminobenzylamine

Application
Product Name
3-Aminobenzylamine
CAS No.
4403-70-7
Chemical Name
3-Aminobenzylamine
Synonyms
3-(AMINOMETHYL)ANILINE;3-AminobenzyL;m-Aminobenzylamine;3-AMINOBENZYLAMINE;RARECHEM AL BW 0272;m-Aminomethylaniline;Meta aminobenzylamine;3-Aminobenzylamine,97%;3-Aminobenzylamine 99%;3-Aminobenzylamine >
CBNumber
CB8263063
Molecular Formula
C7H10N2
Formula Weight
122.17
MOL File
4403-70-7.mol
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3-Aminobenzylamine Property

Melting point:
41-45 °C
Boiling point:
134°C/4mmHg(lit.)
Density 
1.093±0.06 g/cm3(Predicted)
Flash point:
>110℃
storage temp. 
2-8°C, protect from light
solubility 
soluble in Methanol
form 
Low Melting Solid
pka
9.22±0.10(Predicted)
color 
Pale brown
CAS DataBase Reference
4403-70-7(CAS DataBase Reference)
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Safety

Hazard Codes 
N,C
Risk Statements 
34-51/53-22
Safety Statements 
26-36/37/39-61-45-22
RIDADR 
3259
WGK Germany 
3
HazardClass 
8
PackingGroup 
III
HS Code 
29215900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
721492
Product name
3-Aminobenzylamine
Purity
99%
Packaging
5g
Price
$98.8
Updated
2023/06/20
Sigma-Aldrich
Product number
721492
Product name
3-Aminobenzylamine
Purity
99%
Packaging
25g
Price
$126
Updated
2022/05/15
TCI Chemical
Product number
A1431
Product name
3-Aminobenzylamine
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$44
Updated
2025/07/31
TCI Chemical
Product number
A1431
Product name
3-Aminobenzylamine
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$121
Updated
2025/07/31
TRC
Product number
A601838
Product name
3-Aminobenzylamine
Packaging
100mg
Price
$60
Updated
2021/12/16
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3-Aminobenzylamine Chemical Properties,Usage,Production

Application

m-Aminobenzylamine is an important organic dye and pharmaceutical intermediate. It can also be used as a curing agent for epoxy resins and in the polymerization of olefin compounds to prepare insulated cables. Synthetic methods for benzylamine compounds include the reaction of benzaldehyde with hydroxylamine hydrochloride, direct amination of halobenzyl with aminoamine, amination with hexamethylenetetramine, and amination with phthalimide. Alfred prepared m-aminobenzylamine using m-nitrobenzoic acid as a raw material; other methods involve introducing a CN group onto the benzene ring followed by catalytic hydrogenation.

Chemical Properties

Pale brown low melting solid

Synthesis Reference(s)

Synthetic Communications, 25, p. 863, 1995 DOI: 10.1080/00397919508013422

Synthesis

3717-30-4

4403-70-7

The general procedure for the synthesis of 3-aminobenzylamine from the compound (CAS:3717-30-4) is as follows: Example 18: 16.6 g (0.1 mol) of m-nitrobenzaldehyde oxime made in Example 15, 9.5 g (0.05 mol) of p-toluenesulfonic acid, 0.5 g of 5% Pt-C catalyst and 75 mL of dioxane were added to a sealed glass vessel. Vigorous stirring was carried out under hydrogen-filled conditions. The reaction was continued at 30°C to 40°C for 8 hours. Upon completion of the reaction, the mixture was filtered to remove the catalyst, followed by the addition of 35 g (0.3 mol) of 35% aqueous sodium hydroxide. After stirring, the mixture was allowed to stand until layered. The lower layer was separated and discarded and the upper layer was distilled. Finally 8.9 g of m-aminobenzylamine was obtained in 72.9% yield and 99.3% purity by gas chromatography.

References

[1] Patent: US4751328, 1988, A
[2] Patent: US4751328, 1988, A

3-Aminobenzylamine Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Aminobenzylamine Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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81
Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
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Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Country
China
ProdList
18207
Advantage
66
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
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Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11035
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64
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
15883
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64
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768836
Email
1791901229@qq.com
Country
China
ProdList
6950
Advantage
52
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View Lastest Price from 3-Aminobenzylamine manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
3-Aminobenzylamine 4403-70-7
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-31
Henan Aochuang Chemical Co.,Ltd.
Product
3-Aminobenzylamine 4403-70-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-20
Career Henan Chemical Co
Product
3-Aminobenzylamine 4403-70-7
Price
US $1.00/kg
Min. Order
1kg
Purity
98%min
Supply Ability
as request
Release date
2018-12-23

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