ChemicalBook > CAS DataBase List > 4-METHYL-3-NITROBENZOTRIFLUORIDE

4-METHYL-3-NITROBENZOTRIFLUORIDE

Product Name
4-METHYL-3-NITROBENZOTRIFLUORIDE
CAS No.
65754-26-9
Chemical Name
4-METHYL-3-NITROBENZOTRIFLUORIDE
Synonyms
1-METHYL-2-NITRO-4-(TRIFLUOROMETHYL)BENZENE;4-METHYL-3-NITROBENZOTRIFLUORIDE;2-NITRO-4-(TRIFLUOROMETHYL)TOLUENE;Benzene, 1-methyl-2-nitro-4-(trifluoromethyl)-;4-METHYL-3-NITROBENZOTRIFLUORIDE ISO 9001：2015 REACH;1-methyl-2-nitro-4-(trifluoromethyl)benzene - [M87178]
CBNumber
CB8270090
Molecular Formula
C8H6F3NO2
Formula Weight
205.13
MOL File
65754-26-9.mol
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4-METHYL-3-NITROBENZOTRIFLUORIDE Property

Boiling point:
206.6±35.0℃ (760 Torr)
Density 
1.357±0.06 g/cm3 (20 ºC 760 Torr)
Flash point:
78.8±25.9℃
storage temp. 
Sealed in dry,Room Temperature
form 
liquid
color 
Clear
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Safety

Hazard Note 
Harmful
HS Code 
2921420090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
M338965
Product name
1-Methyl-2-nitro-4-(trifluoromethyl)benzene
Packaging
500mg
Price
$65
Updated
2021/12/16
SynQuest Laboratories
Product number
4854-3-13
Product name
4-Methyl-3-nitrobenzotrifluoride
Purity
98%
Packaging
5G
Price
$68
Updated
2021/12/16
AK Scientific
Product number
W7702
Product name
2-Nitro-4-(trifluoromethyl)toluene
Packaging
5g
Price
$77
Updated
2021/12/16
Apolloscientific
Product number
PC9163
Product name
4-Methyl-3-nitrobenzotrifluoride
Purity
97%
Packaging
25g
Price
$92
Updated
2021/12/16
SynQuest Laboratories
Product number
4854-3-13
Product name
4-Methyl-3-nitrobenzotrifluoride
Purity
98%
Packaging
1g
Price
$21
Updated
2021/12/16
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4-METHYL-3-NITROBENZOTRIFLUORIDE Chemical Properties,Usage,Production

Synthesis

6140-17-6

65754-26-9

General procedure for the synthesis of 1-methyl-2-nitro-4-(trifluoromethyl)benzene from 4-methyltrifluorotoluene: Referring to Example 10, 4-methyltrifluorotoluene (18.6 g, 116 mmol) was dissolved in concentrated sulfuric acid (120 ml), and a concentrated sulfuric acid solution (60 ml) of potassium nitrate (12.9 g, 128 mmol) was added slowly by dropwise addition, and the dropping process was controlled to be completed in 15 The titration process was controlled to be completed within 15 minutes and room temperature was maintained. After the dropwise addition, the reaction mixture was stirred at the same temperature for 2 hours. After completion of the reaction, the mixture was slowly poured into ice water and extracted with ethyl acetate, the organic phase was dried with anhydrous sodium sulfate and the solvent was subsequently removed by distillation. The crude product obtained was purified by silica gel column chromatography with an eluent ratio of hexane:ethyl acetate=8:1, resulting in 22.8 g of the target product 1-methyl-2-nitro-4-(trifluoromethyl)benzene as a pale yellow liquid in 96% yield. The structure of the product was confirmed by 1H-NMR (CDCl3, δ): 2.69 (3H, s), 7.52 (1H, d, J=8.3 Hz), 7.76 (1H, d, J=8.3 Hz), 8.25 (1H, s).

References

[1] Patent: US6562839, 2003, B1

4-METHYL-3-NITROBENZOTRIFLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-METHYL-3-NITROBENZOTRIFLUORIDE Suppliers

China 77 India 1 United Kingdom 2 United States 10 Global 90
Alchem Pharmtech,Inc.
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8485655694
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Combi-Blocks Inc.
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Matrix Scientific
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View Lastest Price from 4-METHYL-3-NITROBENZOTRIFLUORIDE manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-Nitro-4-(trifluoromethyl)toluene 65754-26-9
Price
US $5.00-0.50/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-01-13

65754-26-9, 4-METHYL-3-NITROBENZOTRIFLUORIDERelated Search:

4-METHYL-3-NITROBENZOTRIFLUORIDE 2,4-DIMETHYL-5-NITROBENZOTRIFLUORIDE 2,5-Bis(trifluoromethyl)nitrobenzene 2-NITRO-4-(TRIFLUOROMETHYL)PHENYLACETIC ACID 2-NITRO-4-(TRIFLUOROMETHYL)PHENYLACETONITRILE 2-NITRO-4-(TRIFLUOROMETHYL)BENZONITRILE 2-Nitro-4-trifluoromethylbenzoic acid 3-METHYL-2-NITROBENZOTRIFLUORIDE 4-CHLORO-2-METHYL-3-NITROBENZOTRIFLUORIDE,4-Chloro-2-methyl-5-nitrobenzotrifluoride 98%,4-Chloro-2-methyl-5-nitrobenzotrifluoride98% 2-Methyl-3-nitrobenzotrifluoride 5-METHYL-2-NITROBENZOTRIFLUORIDE 3-METHYL-4-NITROBENZOTRIFLUORIDE 2-METHOXY-4-METHYL-5-NITROBENZOTRIFLUORIDE 2-METHYL-5-NITROBENZOTRIFLUORIDE ETHYL ALPHA-CYANO-2-NITRO-4-(TRIFLUOROMETHYL)PHENYLACETATE 2-(2-nitro-4-trifluoromethylbenzoyl)-1,3-cyclohexanedione 2-NITRO-4-(TRIFLUOROMETHYL)BENZYL CHLORIDE 2-BROMO-6-NITRO-4-TRIFLUOROMETHYLTOLUENE

  • 4-METHYL-3-NITROBENZOTRIFLUORIDE
  • 1-METHYL-2-NITRO-4-(TRIFLUOROMETHYL)BENZENE
  • 2-NITRO-4-(TRIFLUOROMETHYL)TOLUENE
  • Benzene, 1-methyl-2-nitro-4-(trifluoromethyl)-
  • 4-METHYL-3-NITROBENZOTRIFLUORIDE ISO 9001：2015 REACH
  • 1-methyl-2-nitro-4-(trifluoromethyl)benzene - [M87178]
  • 65754-26-9