ChemicalBook > CAS DataBase List > 2-Nitro-4-trifluoromethylbenzoic acid

2-Nitro-4-trifluoromethylbenzoic acid

Product Name
2-Nitro-4-trifluoromethylbenzoic acid
CAS No.
320-94-5
Chemical Name
2-Nitro-4-trifluoromethylbenzoic acid
Synonyms
2NTF-BOA;2-Nitro-4-(trifL;BUTTPARK 24\10-94;RARECHEM AL BO 0289;2-Nitro-4-trifluorom;Nitrotrifluoromethylbenzoicacid;Nitro-4-(trifluoroMethyl)benzoi;2-nitro-α,α,α-trifluor-p-toluic acid;α,α,α-Trifluoro-2-nitro-p-toluic Acid;2-NITRO-4-(TRIFLUOROMETHYL)BENZOIC ACID
CBNumber
CB7215186
Molecular Formula
C8H4F3NO4
Formula Weight
235.12
MOL File
320-94-5.mol
More
Less

2-Nitro-4-trifluoromethylbenzoic acid Property

Melting point:
134-138 °C(lit.)
Boiling point:
306.6±42.0 °C(Predicted)
Density 
1.596±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO, Methanol
pka
1.70±0.25(Predicted)
form 
Crystalline Powder
color 
Pale yellow
BRN 
1985588
CAS DataBase Reference
320-94-5(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29163990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
328901
Product name
2-Nitro-4-(trifluoromethyl)benzoic acid
Purity
98%
Packaging
1g
Price
$24.5
Updated
2025/07/31
TCI Chemical
Product number
N0720
Product name
2-Nitro-4-(trifluoromethyl)benzoic Acid
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$40
Updated
2025/07/31
TCI Chemical
Product number
N0720
Product name
2-Nitro-4-(trifluoromethyl)benzoic Acid
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$157
Updated
2025/07/31
TRC
Product number
N596800
Product name
2-Nitro-4-(trifluoromethyl)benzoic Acid
Packaging
10g
Price
$145
Updated
2021/12/16
TRC
Product number
N596800
Product name
2-Nitro-4-(trifluoromethyl)benzoic Acid
Packaging
50g
Price
$495
Updated
2021/12/16
More
Less

2-Nitro-4-trifluoromethylbenzoic acid Chemical Properties,Usage,Production

Chemical Properties

Off-White to Pale Yellow Solid

Uses

2-Nitro-4-(trifluoromethyl)benzoic Acid (cas# 320-94-5) is a compound useful in organic synthesis.

Synthesis

455-24-3

320-94-5

Example 2 a) Synthesis of 2-nitro-4-trifluoromethylbenzoic acid: 11.97 g (63 mmol) of 4-trifluoromethylbenzoic acid was slowly added in batches to 48 mL of concentrated nitric acid (100%) at room temperature. Subsequently, the reaction mixture was heated to reflux for 1 h. After completion of the reaction, it was cooled to room temperature and slowly poured into about 600 g of ice. After stirring the mixture for 1 hour, the precipitate was collected by filtration and washed with 1 L of water. The filtrate was extracted with 300 mL of dichloromethane (CH2Cl2), the organic phase was combined with the precipitate and dried over anhydrous sodium sulfate (Na2SO4). The solvent was removed by distillation under reduced pressure and the residue was recrystallized by dissolving in 1 L of diisopropyl ether (DIP) and adding 2 L of heptane (HEP) at 68 °C, followed by slow cooling of the solution to room temperature. The crystalline product was washed with 1 L of heptane and dried under reduced pressure to give 7.1 g (48% yield) of 2-nitro-4-trifluoromethylbenzoic acid with a melting point of 136 °C - 138 °C.

References

[1] Patent: US2005/124681, 2005, A1. Location in patent: Page/Page column 16

2-Nitro-4-trifluoromethylbenzoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

2-Nitro-4-trifluoromethylbenzoic acid Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Ark Pharm, Inc.
Tel
847-367-3680
Fax
847-367-3681
Email
sales@arkpharminc.com
Country
United States
ProdList
1670
Advantage
56
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Shijiazhuang Sdyano Fine Chemical Co., Ltd.
Tel
0311-89250318 031166536426
Fax
4000311741
Email
master@sjzsdyn.com
Country
China
ProdList
2809
Advantage
65
Wuhan Chemwish Technology Co., Ltd
Tel
86-027-67849912
Fax
86-027-87531808
Email
sales@chemwish.com
Country
China
ProdList
35896
Advantage
56
More
Less

View Lastest Price from 2-Nitro-4-trifluoromethylbenzoic acid manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
2-Nitro-4-trifluoromethylbenzoic acid 320-94-5
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-11-18
Shaanxi Dideu Medichem Co. Ltd
Product
2-Nitro-4-(trifluoromethyl)benzoic acid 320-94-5
Price
US $1500.00/KG
Min. Order
1KG
Purity
99.0% min
Supply Ability
100 tons min
Release date
2025-04-14
Wuhan Boye Science And Technology Development Co., Ltd.
Product
2-Nitro-4-trifluoromethylbenzoic acid 320-94-5
Price
US $0.00/KG
Min. Order
1Kg/Bag
Purity
99%
Supply Ability
100KG
Release date
2021-04-14

320-94-5, 2-Nitro-4-trifluoromethylbenzoic acidRelated Search:


  • RARECHEM AL BO 0289
  • 2NTF-BOA
  • 2-NITRO-4-(TRIFLUOROMETHYL)BENZOIC ACID
  • 2-NITRO-4-(TRIFLUOROMETHYL)BENZOIC ACID METHYL ESTER
  • 2-NITRO-ALPHA,ALPHA,ALPHA-TRIFLUORO-P-TOLUIC ACID
  • 2-NITRO-ALPHA,ALPHA,ALPHA-TRIFLUOR-P-TOLUIC ACID
  • 2-nitro-α,α,α-trifluor-p-toluic acid
  • 2-Nitro-4-(trifluoromethyl)benzoic acid 97%
  • Methyl 2-nitro-4-(trifluoromethyl)benzoate 99+%
  • 2-Nitro-4-(trifluoromethyl)benzoicacid97%
  • METHYL 2-NITRO-4-(TRIFLUOROMETHYL)BENZOATE
  • BUTTPARK 24\10-94
  • 4-(Trifluoromethyl)-2-nitrobenzoic acid
  • 2-Nitro-4-(trifluoromethyl)benzoic acid ,98%
  • 2-Nitro-4-trifluorom
  • Nitrotrifluoromethylbenzoicacid
  • α,α,α-Trifluoro-2-nitro-p-toluic Acid
  • Nitro-4-(trifluoroMethyl)benzoi
  • 2-Nirto-alpha,alpha,alpha-trifluoro-p-toluylic acid
  • The 2-nitro -4- threefluorine Methyl benzoic acid
  • 2-Nitro-4-(trifluoromethyl)benzoicAcid&gt
  • 2-Nitro-4-(trifL
  • Benzoic acid, 2-nitro-4-(trifluoromethyl)-
  • 320-94-5
  • C8H4NO4F3
  • C9H6NO4F3
  • O2NC6H3CF3CO2H
  • Carboxylic Acids
  • Carbonyl Compounds
  • C8
  • Organic Building Blocks
  • Building Blocks
  • Fluorine series
  • Aromatics
  • Miscellaneous Reagents
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
  • Benzoic acid