Methyl 3-methoxysalicylate

Product Name: Methyl 3-methoxysalicylate
CAS No.: 6342-70-7
Chemical Name: Methyl 3-methoxysalicylate
Synonyms: AKOS 214-56;RARECHEM AL BF 0033;METHYL 3-METHOXYSALICYLATE;Methyl 2-Hydroxy-m-anisate;Methyl3-Methoxysalicylate>METHYL 2-HYDROXY-3-METHOXY-BENZOATE;2-Hydroxy-m-anisic Acid Methyl Ester;3-Methoxysalicylic Acid Methyl Ester;2-HYDROXY-3-METHOXYBENZOIC ACID METHYL ESTER;Benzoic acid, 2-hydroxy-3-methoxy-, methyl ester
CBNumber: CB8314842
Molecular Formula: C9H10O4
Formula Weight: 182.17
MOL File: 6342-70-7.mol

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Methyl 3-methoxysalicylate Property

Melting point:: 65-68 °C (lit.)
Boiling point:: 105 °C(Press: 2 Torr)
Density: 1.216±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: soluble in Methanol
form: powder to crystal
pka: 9.76±0.10(Predicted)
color: White to Gray to Red
λmax: 320nm(Dioxane)(lit.)
InChI: InChI=1S/C9H10O4/c1-12-7-5-3-4-6(8(7)10)9(11)13-2/h3-5,10H,1-2H3
InChIKey: BWRCJLJJIXYLNV-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=CC(OC)=C1O
CAS DataBase Reference: 6342-70-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 29189900
Storage Class: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 449490
Product name: Methyl 3-methoxysalicylate
Purity: 98%
Packaging: 10g
Price: $686
Updated: 2023/01/07

TCI Chemical

Product number: M2167
Product name: Methyl 3-Methoxysalicylate
Purity: >98.0%(GC)
Packaging: 5g
Price: $85
Updated: 2025/07/31

TCI Chemical

Product number: M2167
Product name: Methyl 3-Methoxysalicylate
Purity: >98.0%(GC)
Packaging: 25g
Price: $254
Updated: 2025/07/31

TRC

Product number: M323653
Product name: Methyl2-Hydroxy-3-methoxybenzoate
Packaging: 500mg
Price: $45
Updated: 2021/12/16

TRC

Product number: M323653
Product name: Methyl2-Hydroxy-3-methoxybenzoate
Packaging: 1g
Price: $60
Updated: 2021/12/16

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Methyl 3-methoxysalicylate Chemical Properties,Usage,Production

Synthesis

67-56-1

877-22-5

6342-70-7

General procedure for the synthesis of methyl 2-hydroxy-3-methoxybenzoate from methanol and 3-methoxysalicylic acid: 25.5 g (0.152 mol) of 3-methoxysalicylic acid was added to 250 ml of methanol containing 1 ml of concentrated sulfuric acid. The reaction mixture was heated to reflux for 4 days. After completion of the reaction, the mixture was concentrated to dryness. The concentrate was extracted with ethyl acetate. The organic layer was washed sequentially with water, 10% sodium carbonate solution, water and saturated sodium chloride solution. After the above treatment, 25.2 g of the target product methyl 2-hydroxy-3-methoxybenzoate was obtained in 91.2% yield. The melting point was 68-69°C.

References

[1] Bioorganic and Medicinal Chemistry, 1998, vol. 6, # 9, p. 1447 - 1456
[2] Patent: KR2018/56603, 2018, A. Location in patent: Paragraph 0441; 0453-0455
[3] Australian Journal of Chemistry, 2003, vol. 56, # 11, p. 1099 - 1106
[4] Synthetic Communications, 1995, vol. 25, # 6, p. 915 - 920
[5] Journal of Medicinal Chemistry, 1991, vol. 34, # 5, p. 1612 - 1624

Methyl 3-methoxysalicylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 3-methoxysalicylate Suppliers

Americas 1 China 116 Europe 3 Germany 3 India 4 Japan 1 Switzerland 1 Ukraine 1 United Kingdom 6 United States 18 Global 154

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View Lastest Price from Methyl 3-methoxysalicylate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: Methyl 3-methoxysalicylate 6342-70-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-28

Hebei Yanxi Chemical Co., Ltd.

Product: Methyl 3-methoxysalicylate 6342-70-7
Price: US $10.00-1.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-09-18

Career Henan Chemical Co

Product: Methyl 3-methoxysalicylate 6342-70-7
Price: US $3.00/KG
Min. Order: 1IU
Purity: 98%
Supply Ability: 200KG
Release date: 2020-01-07

6342-70-7, Methyl 3-methoxysalicylateRelated Search:

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METHYL 3-METHOXYSALICYLATE

METHYL 2-HYDROXY-3-METHOXY-BENZOATE

2-HYDROXY-3-METHOXYBENZOIC ACID METHYL ESTER

AKOS 214-56

RARECHEM AL BF 0033

Methyl 3-methoxysalicylate,Methyl 2-hydroxy-3-methoxybenzoate

3-Methoxysalicylic Acid Methyl Ester Methyl 2-Hydroxy-3-methoxybenzoate 2-Hydroxy-3-methoxybenzoic Acid Methyl Ester Methyl 2-Hydroxy-m-anisate 2-Hydroxy-m-anisic Acid Methyl Ester

Methyl3-Methoxysalicylate&gt

Benzoic acid, 2-hydroxy-3-methoxy-, methyl ester

3-Methoxysalicylic Acid Methyl Ester

2-Hydroxy-m-anisic Acid Methyl Ester

Methyl 2-Hydroxy-m-anisate

6342-70-7

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