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Styralyl acetate

Product Name
Styralyl acetate
CAS No.
93-92-5
Chemical Name
Styralyl acetate
Synonyms
STYRALLYL ACETATE;Gardenol;1-PHENYLETHYL ACETATE;1-Phenylethylacetat;α-Methylbenzyl acetate;ALPHA-METHYLBENZYL ACETATE;METHYL PHENYL CARBINYL ACETATE;FEMA 2684;gardeniolii;Gardeniol ii
CBNumber
CB8335113
Molecular Formula
C10H12O2
Formula Weight
164.2
MOL File
93-92-5.mol
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Styralyl acetate Property

Melting point:
-60°C
Boiling point:
94-95 °C12 mm Hg(lit.)
Density 
1.028 g/mL at 25 °C(lit.)
vapor pressure 
5.5Pa at 20℃
FEMA 
2684 | ALPHA-METHYLBENZYL ACETATE
refractive index 
n20/D 1.494(lit.)
Flash point:
196 °F
storage temp. 
Sealed in dry,Room Temperature
Odor
at 10.00 % in dipropylene glycol. green leafy gardenia rhubarb musty
Odor Type
green
Water Solubility 
1.27g/L at 20℃
JECFA Number
801
LogP
2.5
CAS DataBase Reference
93-92-5(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanol, «alpha»-methyl-, acetate(93-92-5)
EPA Substance Registry System
Benzenemethanol, .alpha.-methyl-, acetate (93-92-5)
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Safety

Safety Statements 
24/25
RIDADR 
NA 1993 / PGIII
WGK Germany 
1
RTECS 
DO9410000
Autoignition Temperature
450 °C
HS Code 
2915 39 00
Toxicity
LD50 orally in Rabbit: > 5000 mg/kg LD50 dermal Rabbit > 5000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W268402
Product name
Methyl phenylcarbinyl acetate
Purity
≥98%, FCC, FG
Packaging
sample-k
Price
$56.2
Updated
2024/03/01
Sigma-Aldrich
Product number
W268402
Product name
Methyl phenylcarbinyl acetate
Purity
≥98%, FCC, FG
Packaging
1kg
Price
$80.9
Updated
2024/03/01
Sigma-Aldrich
Product number
W268402
Product name
Methyl phenylcarbinyl acetate
Purity
≥98%, FCC, FG
Packaging
5kg
Price
$220
Updated
2024/03/01
Sigma-Aldrich
Product number
W268402
Product name
Methyl phenylcarbinyl acetate
Purity
≥98%, FCC, FG
Packaging
25kg
Price
$812
Updated
2024/03/01
Sigma-Aldrich
Product number
8.43785
Product name
1-Phenylethyl acetate
Purity
for synthesis
Packaging
100mL
Price
$86.1
Updated
2024/03/01
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Styralyl acetate Chemical Properties,Usage,Production

Description

α-Methylbenzyl acetate has an intensive green odor suggestive of gardenia with a bitter, acrid taste, interesting on dilution. May be prepared by acetylation of methyl phenyl carbinol; from benzaldehyde by reacting with magnesium methyl bromide and subsequent acetylation; from 1-bromoethylbenzene and silver acetate in acetic acid.

Chemical Properties

α-Methylbenzyl acetate has an intensive green odor suggestive of gardenia and a bitter, acrid taste, interesting on dilution.

Chemical Properties

CLEAR COLOURLESS TO PALE YELLOWISH LIQUID

Occurrence

Reported found in gardenia flower oil and avocado.

Uses

Perfumery, flavoring.

Uses

Styralyl Acetate is a freshening compound with Alkoxylated Phenols.

Definition

ChEBI: 1-Phenylethyl acetate is a carboxylic ester. It is functionally related to a benzyl alcohol.

Preparation

By acetylation of methyl phenyl carbinol; from benzaldehyde by reacting with magnesium methyl bromide and subse quent acetylation; from 1-bromoethylbenzene and silver acetate in acetic acid.

Taste threshold values

Taste characteristics at 12.0 ppm: fruity, berry, green, seedy and slightly nutty.

Synthesis Reference(s)

Journal of the American Chemical Society, 88, p. 1833, 1966 DOI: 10.1021/ja00960a057
Synthetic Communications, 8, p. 33, 1978 DOI: 10.1080/00397917808062180

Flammability and Explosibility

Non flammable

Metabolism

Although no published data exist on the metabolism of methylphenylcarbinyl acetate, it is likely that hydrolysis to the carbinol and acetic acid is the initial step. Williams (1959) reports studies in which 50% of a dose of (±)-methylphenylcarbinol given to rabbits was excreted as the glucuronide in the urine within 24 hr. There was some evidence of oxidation and demethylation, as mandelic and hippuric acids were found in the urine. Previously, El Masry, Smith

Styralyl acetate Preparation Products And Raw materials

Raw materials

Preparation Products

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Styralyl acetate Suppliers

Tianjin Zhongxin Chemtech Co., Ltd.
Tel
022-66880623
Fax
86(0)22-66880086
Email
sales@tjzxchem.com
Country
China
ProdList
614
Advantage
60
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
jiliang chemicals
Tel
21-62165282 15801962796;
Fax
021 61153784
Email
bidingchem@163.com
Country
China
ProdList
1165
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60
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12990
Advantage
57
Henan Wei Yuan Biotechnology Co., Ltd.
Tel
0371-27990887 13703782753
Fax
0371-27536887
Email
xuanqunlong@126.com
Country
China
ProdList
66
Advantage
62
Spectrum Chemical Manufacturing Corp.
Tel
021-021-021-67601398-809-809-809 15221380277
Fax
021-57711696
Email
marketing_china@spectrumchemical.com
Country
China
ProdList
9664
Advantage
60
BOC Sciences
Tel
1-631-485-4226; 16314854226
Email
info@bocsci.com
Country
United States
ProdList
14059
Advantage
65
Qingdao Free Trade Zone United International Co.,Ltd.
Tel
0532-83893697 18561902820
Fax
83893695
Email
sissili@unitedint.com
Country
China
ProdList
352
Advantage
58
Shanghai Yolne Chemical Co., Ltd.
Tel
021-62960152
Fax
021-52212593
Email
934678158@qq.com
Country
China
ProdList
9906
Advantage
55
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View Lastest Price from Styralyl acetate manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
STYRALLYL ACETATE 93-92-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
100tons
Release date
2023-09-27
Hebei Kingfiner Technology Development Co. , Ltd.
Product
Styralyl acetate 93-92-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
50000kg
Release date
2023-10-24
Hebei Mojin Biotechnology Co., Ltd
Product
Styralyl acetate 93-92-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-04

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