1-ACETOXY-1-CYANOETHYLENE

Product Name: 1-ACETOXY-1-CYANOETHYLENE
CAS No.: 3061-65-2
Chemical Name: 1-ACETOXY-1-CYANOETHYLENE
Synonyms: 2-HYDROXYACRYLONITRILE;1-CYANOVINYL ACETATE;2-ACETOXYACRYLONITRILE;α-acetoxyacrylonitrile;1-cyanoethenyl acetate;alpha-cyanovinylacetate;alpha-Cyanovinyl acetate;1-cyanoethenyl ethanoate;1-ACETOXY-1-CYANOETHYLENE;ALPHA-ACETOXYACRYLONITRILE
CBNumber: CB8360889
Molecular Formula: C5H5NO2
Formula Weight: 111.1
MOL File: 3061-65-2.mol

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1-ACETOXY-1-CYANOETHYLENE Property

Boiling point:: 80-82 °C30 mm Hg(lit.)
Density: 1.061 g/mL at 20 °C(lit.)
vapor pressure: 30 mm Hg ( 80 °C)
refractive index: n20/D 1.426(lit.)
Flash point:: 147 °F
storage temp.: Sealed in dry,2-8°C
solubility: sol most organic solvents other than pure hydrocarbons.
form: clear liquid
color: Colorless to Light yellow
BRN: 1751158
CAS DataBase Reference: 3061-65-2(CAS DataBase Reference)

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Safety

Hazard Codes: T
Risk Statements: 23/24/25-41-37/38
Safety Statements: 36/37/39-45-26
RIDADR: UN 3276 6.1/PG 2
WGK Germany: 3
RTECS: AG4550000
HS Code: 2926.90.5050
HazardClass: 6.1(a)
PackingGroup: II
Toxicity: skn-rbt 10 mg/24H open MLD AIHAAP 23,95,62

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H227Combustible liquid

H301Toxic if swalloed

H310Fatal in contact with skin

H315Causes skin irritation

H318Causes serious eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P262Do not get in eyes, on skin, or on clothing.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P350IF ON SKIN: Gently wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: A1477
Product name: 1-Cyanovinyl Acetate (stabilized with TBC)
Purity: >97.0%(GC)
Packaging: 5g
Price: $307
Updated: 2024/03/01

TCI Chemical

Product number: A1477
Product name: 1-Cyanovinyl Acetate (stabilized with TBC)
Purity: >97.0%(GC)
Packaging: 25g
Price: $1035
Updated: 2023/06/20

TRC

Product number: C993058
Product name: 1-Cyanovinyl Acetate (stabilized with TBC)
Packaging: 2.5g
Price: $220
Updated: 2021/12/16

AK Scientific

Product number: 4737AL
Product name: 1-Acetoxy-1-cyanoethylene
Packaging: 5g
Price: $430
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0013468
Product name: ACETIC ACID 1-CYANOVINYL ESTER
Purity: 95.00%
Packaging: 1G
Price: $640.33
Updated: 2021/12/16

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1-ACETOXY-1-CYANOETHYLENE Chemical Properties,Usage,Production

Reactivity Profile

1-cyanovinyl acetate is a ketene equivalent for use in the Diels-Alder reaction; undergoes other cycloaddition reactions; reacts with nucleophiles and radicals[1].

Safety Profile

Poison by inhalation, ingestion, andskin contact. A skin irritant. Whenheated to decomposition it emits toxic fumes of NOx andCN-.

storage

Handling, Storage, and Precautions: highly toxic; use only in a fume hood. Reagent can be absorbed through the skin. Always wear gloves when handling this reagent.

References

1. Ranganathan, S.; Ranganathan, D.; Mehrotra, A. K. S 1977, 289.
2. Brown, D. S.; Paquette, L. A. JOC 1992, 57, 4512.
3. Nowak, R. M. JOC 1963, 28, 1182.

1-ACETOXY-1-CYANOETHYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-ACETOXY-1-CYANOETHYLENE Suppliers

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3061-65-2, 1-ACETOXY-1-CYANOETHYLENERelated Search:

Butyl acetate 2-Methoxypropene CYANOMETHYL FORMATE 2-Ethoxypropene VINYL FORMATE Vinyl acetate Glycolonitrile Methoxyacetonitrile 1-ACETOXY-1-CYANOETHYLENE Methoxyethene Ethyl vinyl ether Isopropenyl acetate Ammonium acetate Acrylonitrile

1-Cyanovinyl ester of acetic acid

1-Kyanvinylester kyseliny octove

1-kyanvinylesterkyselinyoctove

2-(acetyloxy)-2-propenenitril

2-(acetyloxy)-2-propenenitrile

2-hydroxy-acrylonitrilacetate

2-hydroxy-acrylonitrilacetate(ester)

2-Hydroxyacrylonitrile acetate

2-Acetoxyacrylonitrile 1-Acetoxy-1-cyanoethylene Acetic Acid 1-Cyanovinyl Ester

2-HYDROXYACRYLONITRILE

2-ACETOXYACRYLONITRILE

1-CYANOVINYL ACETATE

1-ACETOXY-1-CYANOETHYLENE

alpha-Acetoxyacrylonitrilepurum

α-acetoxyacrylonitrile

1-Cyanovinyl Acetate (stabilized with TBC)

α-Acetoxyacrylonitrile, 1-Acetoxy-1-cyanoethylene, 2-Hydroxyacrylonitrile acetate

2-hydroxyacrylonitrileacetate(ester)

2-Propenenitrile, 2-(acetyloxy)-

Acrylonitrile, 2-hydroxy-, acetate

alpha-Cyanovinyl acetate

alpha-cyanovinylacetate

1-cyanoethenyl acetate

1-cyanoethenyl ethanoate

1-Acetoxy-1-cyanoethylene, 1-Cyanovinyl acetate, 2-Hydroxyacrylonitrile acetate

Acetic acid 1-cyanoethenyl ester

ALPHA-ACETOXYACRYLONITRILE

ACETIC ACID 1-CYANOVINYL ESTER

1-CyanovinylAcetate(stabilizedwithTBC)&gt

3061-65-2

CH2COCOCH3CN

Building Blocks

C1 to C5

Nitrogen Compounds

Organic Building Blocks

Cyanides/Nitriles

Nitrogen Compounds

Organic Building Blocks

Building Blocks

C1 to C5

Chemical Synthesis

Cyanides/Nitriles