ChemicalBook > CAS DataBase List > 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

Product Name
2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine
CAS No.
174500-20-0
Chemical Name
2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine
Synonyms
SF150030;94.0%(LC);(S,S)-Ph-Pybox;2,6-Bis[(4S)-4-phenyL;2,6-Bis[(S)-4-phenyloxazolin-2-yl]pyridine;2,6-Bis[(S)-4-phenyl-2-oxazolinyl]pyridine;2,6-bis[(4s)-4-phenyl-2-oxazolinyl]pyridine;2,6-BIS[(4S)-PHENYL-2-(OXAZOLIN-2-YL)]PYRIDINE;(S,S)-2,6-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PYRIDINE;2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine 98%
CBNumber
CB8386236
Molecular Formula
C23H19N3O2
Formula Weight
369.42
MOL File
174500-20-0.mol
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2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine Property

Melting point:
171-175 °C(lit.)
alpha 
-224 º (c=1, chloroform)
Boiling point:
600.4±55.0 °C(Predicted)
Density 
1.28±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
pka
3.07±0.70(Predicted)
color 
white
optical activity
[α]20/D 224°, c = 1 in chloroform
Water Solubility 
Insoluble
CAS DataBase Reference
174500-20-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-37/39
WGK Germany 
3
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
496073
Product name
2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine
Purity
98%
Packaging
500mg
Price
$70.8
Updated
2024/03/01
Sigma-Aldrich
Product number
496073
Product name
2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine
Purity
98%
Packaging
2g
Price
$503
Updated
2024/03/01
TCI Chemical
Product number
B2220
Product name
(S,S)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine
Purity
>95.0%(HPLC)
Packaging
1g
Price
$399
Updated
2024/03/01
TCI Chemical
Product number
B2220
Product name
(S,S)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine
Purity
>95.0%(HPLC)
Packaging
250mg
Price
$137
Updated
2024/03/01
Strem Chemicals
Product number
07-0304
Product name
(-)-2,6-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]pyridine, 98+% (S,S)-Ph-pybox
Packaging
500mg
Price
$167
Updated
2024/03/01
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2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine Chemical Properties,Usage,Production

Chemical Properties

White solid

Reactions

1. Ligand for Copper catalyzed syn-selective Mukaiyama aldol reaction.
2. Ligand for Tin catalyzed anti-selective aldol reaction.
3. Ligand for Ytterbuim catalyzed desymmetrization of meso epoxides.
4. Ligand for Copper catalyzed enantioselective addition of terminal alkynes to imines.
5. Ligand for Scandium catalyzed enantioselective syn-selective ene reactions.
6. Ligand for Copper catalysed asymmetric alkynylation of cyclic azomethine Imines.
7. Ligand for Europium catalyzed asymmetric alpha amination.
8. Ligand for Indium catalyzed enantioselective construction of spiro-fused 2-oxindole/α-methylene-γ-butyrolactones.
9. Ligand for Copper catalyzed asymmetric azide-alkyne cycloaddition to quaternary oxindoles.
10. Ligand for Iron catalyzed enantioselective nitrene transfer to sulfides.
11. Ligand for Copper catalyzed enantioselective intramolecular propargylic amination.
12. Ligand for Copper catalyzed asymmetric hydroxylation.
13. Ligand for Scandium catalyzed dearomatization of 2-naphthols by electrophilic amination.
14. Ligand for Copper catalyzed asymmetric alkynylation of oxocarbenium ions to set diaryl tetrasubstituted stereoceters.


2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine Preparation Products And Raw materials

Raw materials

Preparation Products

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2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine Suppliers

Americas 1 Belgium 1 China 113 Europe 1 Germany 3 India 2 Japan 2 South Korea 1 Switzerland 1 The Netherlands 1 United Kingdom 3 United States 16 Global 145
SIGMA-RBI
Tel
--
Fax
--
Country
Switzerland
ProdList
6896
Advantage
91
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View Lastest Price from 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine 174500-20-0
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
99%
Supply Ability
2000tons
Release date
2019-12-31

174500-20-0, 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridineRelated Search:

Sulfamethoxazole Pyridine Diphenyl ether PHENYL VALERATE Famoxadone Fenoxaprop-P (S,S)-2,2-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PROPANE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE PHENYL RESIN Phenylacetic acid 2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine METHYL PICOLINIMIDATE PYRIDINE-2-CARBOXIMIDIC ACID ETHYL ESTER (-)-2,6-BIS[2-[3AS-(2(3'AR*,8'AS*),3A,8A)-3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE]]PYRIDINE 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine

  • (S,S)-2,6-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PYRIDINE
  • (S,S)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-PHENYL-2-OXAZOLINE)
  • (4S)-4-phenyl-2-[6-[(4S)-4-phenyl-4,5-dihydrooxazol-2-yl]-2-pyridinyl]-4,5-dihydrooxazole
  • 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine, 98%, (99% ee)
  • SF150030
  • [S-(R*,R*)]-2,6-BIS(4,5-DIHYDRO-4-PHENYL-2-OXAZOLYL)PYRIDINE
  • 2,6-BIS[(4S)-PHENYL-2-(OXAZOLIN-2-YL)]PYRIDINE
  • (-)-2,6-BIS[(4S)-4-PHENYL-2-OXAZOLIN-2-YL]PYRIDINE
  • 2,6-BIS-[(S)-4-PHENYL-4,5-DIHYDRO-OXAZOL-2-YL]-PYRIDINE
  • (-)-2,6-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]pyridine,98+%
  • (s,s)-2,6-bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine
  • 2,6-bis[(4s)-4-phenyl-2-oxazolinyl]pyridine
  • (S,S)-2,6-Bis(4-phenyl-2-oxazolinyl)pyridine, (S,S)-2,6-Bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine
  • 2,6-Bis[(S)-4-phenyloxazolin-2-yl]pyridine
  • (S-(R*,R*))-2,6-bis(4,5-dihydro-4-phenyl-2-oxazol
  • Pyridine, 2,6-bis[(4S)-4,5-dihydro-4-phenyl-2-oxazolyl]
  • 2,6-Bis[(4S)-4-phenyl-2-oxazolinyl]pyridine 98%
  • 2,6-Bis[(4S)-phenyl-2-oxazolin-2-yl]pyridine,99%e.e.
  • (-)-2,6-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]pyridine, 98+% (S,S)-Ph-pybox
  • (S,S)-2,6-Bis(4-phenyl-2-oxazolin-2-yl)pyridine &gt
  • 94.0%(LC)
  • 2,6-Bis[(4S)-4-phenyL
  • (-)-2,6-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]pyridine,98%,99%ee
  • (-)-2,6-bis-[(4S)-4-Phenyl-2-oxazolin-2-yl]pyridine
  • (S,S)-Ph-Pybox
  • 2,6-Bis[(S)-4-phenyl-2-oxazolinyl]pyridine
  • (-)-2,6-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]pyridine,98% (S,S)-Ph-pybox
  • (-)-2,6-Bis[(4S)-4-phenyl-2-oxazolin-2-yl]pyridine,98%
  • 174500-20-0
  • Chiral Catalysts, Ligands, and Reagents
  • PyBOX
  • Privileged Ligands
  • Asymmetric Synthesis
  • Furans ,Coumarins
  • BOX series
  • Chiral Nitrogen
  • Heterocycle-Pyridine series
  • organic amine
  • Asymmetric Synthesis
  • Synthetic Organic Chemistry