Fluroxypyr

ChemicalBook > CAS DataBase List > Fluroxypyr

Product Name: Fluroxypyr
CAS No.: 69377-81-7
Chemical Name: Fluroxypyr
Synonyms: ADVANCE;4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyaceticacid;((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-aceticaci;ff4014;ef-689;FLUROXYPYR;Advance(TM);Fluroxypyr(Starane);Fluroxypyr Solution;Fluroxypyr Standard
CBNumber: CB8389671
Molecular Formula: C7H5Cl2FN2O3
Formula Weight: 255.03
MOL File: 69377-81-7.mol

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Fluroxypyr Property

Melting point:: 57.5°C
Boiling point:: 399.4±37.0 °C(Predicted)
Density: 1.3
storage temp.: Sealed in dry,2-8°C
solubility: DMSO (Slightly), Methanol (Slightly)
pka: 2.22±0.10(Predicted)
color: White to Off-White
Merck: 13,4229
BRN: 7136185
LogP: 3.160 (est)
CAS DataBase Reference: 69377-81-7(CAS DataBase Reference)
NIST Chemistry Reference: Fluroxypyr(69377-81-7)
EPA Substance Registry System: Fluroxypyr (69377-81-7)

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Safety

Risk Statements: 52/53
Safety Statements: 61
RIDADR: UN3077(solid)
WGK Germany: 2
RTECS: AF2500000
Hazardous Substances Data: 69377-81-7(Hazardous Substances Data)
Toxicity: LD50 orally in rats: 2405 mg/kg; i.p. in male, female rats: 458, 519 mg/kg; percutaneous in rabbits >5000 mg/kg (Paul)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 45758
Product name: Fluroxypyr
Purity: PESTANAL?, analytical standard
Packaging: 100mg
Price: $79.8
Updated: 2024/03/01

TRC

Product number: F598780
Product name: Fluroxypyr
Packaging: 250mg
Price: $205
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: PST0000137
Product name: FLUROXYPYR
Purity: 95.00%
Packaging: 500MG
Price: $721.88
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: PST0000137
Product name: FLUROXYPYR
Purity: 95.00%
Packaging: 5G
Price: $1299.38
Updated: 2021/12/16

Atlantic Research Chemicals

Product number: CA002427
Product name: [(4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy]aceticacid(Fluroxypyr)
Purity: 95%
Packaging: 250mgs:
Price: $130.78
Updated: 2021/12/16

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Fluroxypyr Chemical Properties,Usage,Production

Chemical Properties

White crystalline solid.

Uses

Fluroxypyr is a systemic and selective herbicide. Fluroxypyr is used for the control of broad-leaved weeds in small grain cereals, maize, pastures, range land and turf. Fluroxypyr is a synthetic auxin.

Definition

ChEBI: An aminopyridine that is pyridin-4-amine substituted by chloro groups at positions 3 and 5, a fluoro group at position 6 and a carboxymethoxy group at position 2.

Trade name

methyl ester: AGROSTAR; BOFIX FFC®; CABADEX®; CASCADE®; DOWCO® 433 MHE; FOREFRONT®; GALAXY GL184®; PARADIGM®; PASTUREGARD®; STARANE®; TOMAHAWK®; VISTA®; WIDEMATCH®, (fluroxypyr + clopyralid); XRM-5084®

Potential Exposure

Those who manufacture, distribute or use this pyridinecarboxylic acid/pyridine herbicide.

Environmental Fate

The DT₅₀ in soil is relatively short, ranging from 5 to 9 days in experiments conducted in the laboratory. This rapid degradation is due to microbes.Because of its rapid soil degradation, little fluroxypyr is available for other dissipation processes, e.g., leaching.

Metabolism

Fluroxypyr is stable under acidic conditions and moderately stable in alkaline conditions; e.g., the DT₅₀ in water at pH 9 is 185 days. Degradation occurs at temperatures above its melting point. Fluroxypyr is stable in light.
Plant. The metabolism of fluroxypyr has not been fully described. Conjugates of fluroxypyr have been observed in tolerant plants.
Soil. Fluroxypyr is rapidly metabolized by soil microbes via the removal of the carboxyl group or acetic acid group, yielding 4-amino-3,5-dichloro-6-fluoro- 2-methoxypyridine, and 4-amino-3,5-dichloro-6-fluoro-2- pyridinol, respectively.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous haz ardous material, Technical Name Required.

Toxicity evaluation

Mammalian Toxicity. Fluroxypyr appears to be rapidly excreted, unmodified, in the urine of animals. The acute oral LD₅₀ for rat is 2405 mg/kg.
Weed Resistance/Modified Crop Tolerance. Fuerst et al. (48) reported fluroxypyr resistance in yellow starthistle (Centaurea solstitialis). No crops with modified tolerance toward fluroxypyr are currently in production.

Incompatibilities

May not be compatible with nitrates. Moisture may cause hydrolysis or other forms of decompo sition; forming a strong acid. Temperatures above 250℃ can cause decomposition. Methyl ester: Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is suffi ciently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solu tions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Waste Disposal

Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an after burner and scrubber. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesti cide containers.

Fluroxypyr Preparation Products And Raw materials

Raw materials

Ethyl glycolate Flupirtine

Preparation Products

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View Lastest Price from Fluroxypyr manufacturers

Hebei Weibang Biotechnology Co., Ltd

Product: Fluroxypyr 69377-81-7
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-12-02

qingdao trust agri chemical co.,ltd

Product: Fluroxypyr 69377-81-7
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 20tons
Release date: 2024-07-23

qingdao trust agri chemical co.,ltd

Product: Fluroxypyr 69377-81-7
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 20tons
Release date: 2024-07-23

69377-81-7, FluroxypyrRelated Search:

Glycine Sodium dichloroacetate Methyl chloroacetate Trifluoroacetic acid Ethyl chloroacetate Allyl phenoxyacetate Dichloroacetic acid Clopyralid Ethyl acetate Ethyl 2-(Chlorosulfonyl)acetate Ethyl bromodifluoroacetate Phenoxyacetic acid 3-Aminopyridine Trifluoroacetic anhydride Iminodiacetic acid 2-Aminopyridine ALTRENOGEST Triclopyr

((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)-aceticaci

4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyaceticacid

ff4014

[(4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy]acetic acid

2-[(4-AMino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic Acid

Fluroxypyr Solution, 1000ppm

2-((4-Amino-3,5-dichloro-6-fluoropyridin-2-yl)oxy)acetic acid

Aceticacid, 2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]-

2-[(4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy]acetic acid octan-2-yl ester

ADVANCE

((4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy)acetic acid

ef-689

FLUROXYPYR

4,5-amino-3,5-dichloro-6-fluoro-2-pyridinyloxyacetic acid

fluroxypyr 4-amino-3,5-dichloro-6-fluoro-2-pyridyloxyacetic acid

2-(4-Amino-3,5-dichloro-6-fluoropyrin-2-yl)oxyacetic acid

Fluroxypyr(Starane)

FLUROXYPYR PESTANAL (4-AMINO-3,5-DI CHLO

Acetic acid, (4-amino-3,5-dichloro-6-fluoro-2-pyridinyl)oxy-

fluroxypyr (bsi,iso)

Advance(TM)

Fluroxypyr Solution

Fluroxypyr Standard

Fluroxypyr @100 μg/mL in MeOH

Commercial Fluroxypyr 250g/L EC Selective Broadleaf Herbicide 69377-81-7

Fluroxypyr in Methanol

Fluroxypyr 10.0 μg/ml Acetonitrile

XA13849000ALFluroxypyr 100μg/mLin Acetonitril

Fluroxypyr in Acetonitrile

69377-81-7

C7H5CI2FN2O3

C7H5Cl2FN2O3

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FA - FLPesticides&Metabolites

Herbicides

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Pyridine