1,1,1-Tris(4-hydroxyphenyl)ethane

Product Name: 1,1,1-Tris(4-hydroxyphenyl)ethane
CAS No.: 27955-94-8
Chemical Name: 1,1,1-Tris(4-hydroxyphenyl)ethane
Synonyms: 1,1,1-TRIS(P-HYDROXYPHENYL)ETHANE;TIMTEC-BB SBB006476;LABOTEST-BB LT00159983;TRIS-HYDROXYPHENYLETHANE;Tri(4-hydroxyphenyl)ethane;TRIS(P-HYDROXYPHENYL)ETHANE;tris(4-hydroxyphenyl)ethane;4,4',4"-Ethylidynetriphenol;4,4’,4’’-ethylidynetri-pheno;4,4’,4’’-ethylidynetrisphenol
CBNumber: CB8390792
Molecular Formula: C20H18O3
Formula Weight: 306.36
MOL File: 27955-94-8.mol

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1,1,1-Tris(4-hydroxyphenyl)ethane Property

Melting point:: 246-248 °C (lit.)
Boiling point:: 531.8±45.0 °C(Predicted)
Density: 1.252±0.06 g/cm3(Predicted)
vapor pressure: 0Pa at 25℃
storage temp.: Sealed in dry,Room Temperature
solubility: 241 in mg/100g standard fat at 20 ℃
form: powder to crystal
pka: 10.02±0.10(Predicted)
color: White to Almost white
Water Solubility: 25.1mg/L at 20℃
InChI: InChI=1S/C20H18O3/c1-20(14-2-8-17(21)9-3-14,15-4-10-18(22)11-5-15)16-6-12-19(23)13-7-16/h2-13,21-23H,1H3
InChIKey: BRPSWMCDEYMRPE-UHFFFAOYSA-N
SMILES: C(C1=CC=C(O)C=C1)(C1=CC=C(O)C=C1)(C1=CC=C(O)C=C1)C
LogP: 3.88 at 20℃
CAS DataBase Reference: 27955-94-8(CAS DataBase Reference)
EPA Substance Registry System: Phenol, 4,4',4''-ethylidynetris- (27955-94-8)

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Safety

Hazard Codes: Xi,N
Risk Statements: 36/37/38-51/53
Safety Statements: 26-37/39-61
RIDADR: UN 3077 9/PG 3
WGK Germany: 2
RTECS: SL4375275
HazardClass: 9
PackingGroup: III
HS Code: 2907290030

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H411Toxic to aquatic life with long lasting effects
Precautionary statements: P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 326844
Product name: 1,1,1-Tris(4-hydroxyphenyl)ethane
Purity: 99%
Packaging: 100g
Price: $143.45
Updated: 2025/07/31

TCI Chemical

Product number: T1254
Product name: 1,1,1-Tris(4-hydroxyphenyl)ethane
Purity: >98.0%(GC)
Packaging: 25g
Price: $43
Updated: 2025/07/31

TCI Chemical

Product number: T1254
Product name: 1,1,1-Tris(4-hydroxyphenyl)ethane
Purity: >98.0%(GC)
Packaging: 100g
Price: $107
Updated: 2025/07/31

TCI Chemical

Product number: T1254
Product name: 1,1,1-Tris(4-hydroxyphenyl)ethane
Purity: >98.0%(GC)
Packaging: 500g
Price: $321
Updated: 2025/07/31

TRC

Product number: T884955
Product name: 1,1,1-Tris(4-hydroxyphenyl)ethane
Packaging: 250mg
Price: $45
Updated: 2021/12/16

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1,1,1-Tris(4-hydroxyphenyl)ethane Chemical Properties,Usage,Production

Application

In polycarbonate synthesis, 1,1,1-Tris(4-hydroxyphenyl)ethane functions as a highly effective branching agent that can be incorporated into reaction mixtures containing dihydroxyaromatic compounds such as bisphenol A and carbonate sources including phosgene or diphenyl carbonate. This application has proven particularly valuable in the production of high-performance engineering polymers where enhanced mechanical strength and thermal resistance are critical requirements.

Hazard

Low toxicity by ingestion and skin contact. A mild eye irritant.

Flammability and Explosibility

Non flammable

Synthesis

99-93-4

108-95-2

27955-94-8

Synthesis: Phenol (54.0 mol) and zinc chloride (100 g) were added to the reactor and stirred until well mixed. Subsequently, p-hydroxyacetophenone (6.5 mol) was slowly added over 40 minutes, warmed to 60°C and maintained at this temperature for 60 minutes. Concentrated hydrochloric acid (100 mL) was added and the reaction was continued with stirring for 8 hours. After completion of the reaction, the temperature was lowered to 20 °C, dichloroethane was added and filtered with thorough stirring. The filter cake was dried under vacuum at 55 °C for 6 h. The crude product 1,1,1-tris(4-hydroxyphenyl)ethane (THPE) was obtained as 1811 g. The purity of the crude product was 95.0% and the yield was 91.1%. Purification method: the crude product (1000 g) prepared above was added into methanol (2000 mL), heated until completely dissolved and then cooled, slowly added into water (1600 mL), stirred at room temperature for 50 minutes, a light yellow product was obtained. Filtered and dried. The dried product was dissolved in methanol (1200 mL), heated to complete dissolution and added activated carbon to decolorize, filtered and evaporated the solvent to obtain a solid. The obtained solid was dissolved in methanol (1000 mL), and a mixed solution of sodium borohydride (5 g) and sodium sulfite (35 g) was slowly added, and the light yellow powder gradually precipitated. The solid obtained was filtered and dried under vacuum at 25 °C for 10 h. The purified product was obtained as 913 g in 91.3% yield and 99.5% purity by HPLC analysis.

References

[1] Patent: CN105541561, 2016, A. Location in patent: Paragraph 0021; 0022; 0023; 0024; 0025
[2] Asian Journal of Chemistry, 2014, vol. 26, # 22, p. 7846 - 7852
[3] Patent: US2006/4214, 2006, A1. Location in patent: Page/Page column 4-5

1,1,1-Tris(4-hydroxyphenyl)ethane Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1,1-Tris(4-hydroxyphenyl)ethane Suppliers

China 241 France 2 Germany 5 India 3 Japan 4 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 9 United States 31 Global 299

Wuhan Qiaofeng Chemical Technology Co., Ltd.

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CHANGZHOU TIANHUA PHARMACEUTICAL CO.，LTD.

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Shanghai Longsheng chemical Co.,Ltd.

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View Lastest Price from 1,1,1-Tris(4-hydroxyphenyl)ethane manufacturers

Watson Biotechnology Co.,Ltd

Product: Tris(p-hydroxyphenyl)ethane 27955-94-8
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20MT
Release date: 2025-07-04

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 4,4',4"-Ethylidynetriphenol 27955-94-8
Price: US $2.20-8.80/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 1000kg
Release date: 2025-06-13

Shaanxi Dideu New Materials Co. Ltd

Product: 1,1,1-Tris(4-hydroxyphenyl)ethane 27955-94-8
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 10000KGS
Release date: 2025-05-26

27955-94-8, 1,1,1-Tris(4-hydroxyphenyl)ethaneRelated Search:

ETHYLENE OXIDE Triphenylmethyl Chloride Ethanol Triphenyltin acetate Tricine Triphenylphosphine 1,2-Dichloroethane Lactulose BUFFER SOLUTION PH = 6,00 (20 °C) (POTASSIUM DIHYDROGEN PHOSPHATE/SODIUM HYDROXIDE) BIS-Tris Dichloroethane CHLOROETHANE 2,3,5-Triphenyltetrazolium chloride Tris(hydroxymethyl)aminomethane Propiophenone Phenylacetone 1,1,1-TRIS(4-TRIFLUOROVINYLOXYPHENYL)ETHANE 3A-AMINO-3A-DEOXY-(2AS,3AS)-BETA-CYCLODEXTRIN

4,4’,4’’-ethylidynetri-pheno

4,4’,4’’-ethylidynetris-pheno

4,4’,4’’-ethylidynetrisphenol

4-[1,1-bis(4-hydroxyphenyl)ethyl]phenol

3,5-dichloro-N-diethoxyphosphoryl-2-(trichloromethyl)-4-pyridinamine

tris(4-hydroxyphenyl)ethane

4,4',4''-(ETHYLIDENE)TRISPHENOL

1,1,1-TRIS(4-HYDROXYPHENYL)ETHANE

1,1,1-TRIS(P-HYDROXYPHENYL)ETHANE

TIMTEC-BB SBB006476

TRIS(P-HYDROXYPHENYL)ETHANE

TRIS-HYDROXYPHENYLETHANE

LABOTEST-BB LT00159983

4,4',4''-(ethan-1,1,1-triyl)triphenol

4,4μ,4μμ-Ethylidynetrisphenol, THPE

1,1,1 TRIS HYDROXY PHENYL ETHANE

4,4',4''-(1,1,1-Ethanetriyl)tris(phenol)

4,4',4''-(Ethane-1,1,1-triyl)tris(phenol)

Phenol, 4,4',4''-ethylidynetri- (8ci)

Phenol, 4,4',4''-ethylidynetris-

1,1,1-Tris(4-hydroxyphenyl)ethane 99%

4-tris(hydroxyphenyl)ethaMe,THPE

4,4',4''-(Ethane-1,1,1-triyl)triphenol

1,1,1-Tris(4-hydroxyphenyl)ethane (THPE)

1,1,1-This(4-hydroxyphenyl)ethane

1-Tris(4-hydroxyphenyl)ethane

1,1,1-Tris(4-hydroxyphenyl)ethane ISO 9001：2015 REACH

1,1, 1-tri (4-hydroxyphenyl) ethane

4,4',4"-Ethylidynetriphenol

Tri(4-hydroxyphenyl)ethane

1,1,1-Tris(4-hydroxyphenyl)ethane（Assumed）

1,1,1-TRIS(4-HYDROXYPHENYL)ETHANE >98.0%

27955-94-8

55-94-8

27995-94-8

C20H18O3

CH3CC6H4OH3

Color Former & Related Compounds

Developer

Color Former & Related Compounds

Developer

Functional Materials

Industrial/Fine Chemicals