ChemicalBook > CAS DataBase List > Bis(triphenylphosphine)nickel(II)chloride
Bis(triphenylphosphine)nickel(II)chloride
Reaction- Product Name
- Bis(triphenylphosphine)nickel(II)chloride
- CAS No.
- 14264-16-5
- Chemical Name
- Bis(triphenylphosphine)nickel(II)chloride
- Synonyms
- NiCl2(PPh3)2;Bis(triphenylphosphine)nickel dichloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL;(PPh3)2NiCl2;phosphine)nickeL;Bis(triphenylphosphine)nick
- CBNumber
- CB8433158
- Molecular Formula
- C36H30Cl2NiP2
- Formula Weight
- 654.17
- MOL File
- 14264-16-5.mol
More
Less
Bis(triphenylphosphine)nickel(II)chloride Property
- Melting point:
- 250 °C (dec.)(lit.)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- form
- Crystals or Powder
- color
- Dark green to dark gray
- Water Solubility
- insoluble
- Sensitive
- Hygroscopic
- Exposure limits
- NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
- CAS DataBase Reference
- 14264-16-5(CAS DataBase Reference)
- NIST Chemistry Reference
- dichlorobis(triphenylphosphine)nickel(14264-16-5)
- EPA Substance Registry System
- Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)
More
Less
Safety
- Hazard Codes
- T
- Risk Statements
- 45-43-52/53-34-20/21/22
- Safety Statements
- 53-36/37-45-60-36/37/39-26
- RIDADR
- 3260
- WGK Germany
- 3
- RTECS
- QR6170000
- F
- 21
- TSCA
- Yes
- HazardClass
- 6.1(b)
- PackingGroup
- III
- HS Code
- 29310095
More
Less
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H317May cause an allergic skin reaction
H350May cause cancer
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P308+P313IF exposed or concerned: Get medical advice/attention.
More
Less
N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 237116
- Product name
- Bis(triphenylphosphine)nickel(II) dichloride
- Purity
- synthesis grade
- Packaging
- 10g
- Price
- $56.8
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 237116
- Product name
- Bis(triphenylphosphine)nickel(II) dichloride
- Purity
- synthesis grade
- Packaging
- 50g
- Price
- $106.8
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1571
- Product name
- Bis(triphenylphosphine)nickel(II) Dichloride
- Purity
- >96.0%(T)
- Packaging
- 10g
- Price
- $43
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1571
- Product name
- Bis(triphenylphosphine)nickel(II) Dichloride
- Purity
- >96.0%(T)
- Packaging
- 100g
- Price
- $200
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 013930
- Product name
- Dichlorobis(triphenylphosphine)nickel(II), 98%
- Packaging
- 10g
- Price
- $43.65
- Updated
- 2024/03/01
More
Less
Bis(triphenylphosphine)nickel(II)chloride Chemical Properties,Usage,Production
Reaction
- Catalyst for hydrosilylation of styrene with diphenysilane
- Catalyst for carboxylation of various aryl chlorides and other derivatives
- Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
- Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
- Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.
Chemical Properties
dark green to dark grey crystals or powder
Uses
Coordination compund.
Uses
suzuki reaction
Uses
Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.
Purification Methods
Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]
Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials
Raw materials
Preparation Products
More
Less
Bis(triphenylphosphine)nickel(II)chloride Suppliers
- Tel
- --
- Fax
- --
- frankquy@gmail.com
- Country
- Australia
- ProdList
- 20
- Advantage
- 0
More
Less
View Lastest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers
Hebei Weibang Biotechnology Co., Ltd
- Product
- Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 5tons
- Release date
- 2021-10-15
Hebei Mojin Biotechnology Co., Ltd
- Product
- Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-08-23
Shanghai Yunao International Trade Co., Ltd
- Product
- Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
- Price
- US $200.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500t
- Release date
- 2021-09-29
14264-16-5, Bis(triphenylphosphine)nickel(II)chlorideRelated Search:
Potassium chloride
Nickel(II) chloride hexahydrate
Ammonium chloride
Calcium chloride
Triphenylphosphine
Bis(triphenylphosphine)palladium(II) chloride
Polyvinyl chloride
Nickel oxide
Tris(triphenylphosphine)rhodiu
Choline chloride
Nickel chloride
Sodium chloride
Thionyl chloride
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL
Bis-(triphenylphosphino)-cuprous borohydride
BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE
Bis(tricyclohexylphosphine)nickel(II) chloride, 99%