Bis(triphenylphosphine)nickel(II)chloride

ChemicalBook > CAS DataBase List > Bis(triphenylphosphine)nickel(II)chloride

Bis(triphenylphosphine)nickel(II)chloride

Reaction

Product Name: Bis(triphenylphosphine)nickel(II)chloride
CAS No.: 14264-16-5
Chemical Name: Bis(triphenylphosphine)nickel(II)chloride
Synonyms: NiCl2(PPh3)2;Bis(triphenylphosphine)nickel dichloride;BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE;DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II);BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE;NSC 137147;(II) dichL;(PPh3)2NiCl2;phosphine)nickeL;Bis(triphenylphosphine)nick
CBNumber: CB8433158
Molecular Formula: C36H30Cl2NiP2
Formula Weight: 654.17
MOL File: 14264-16-5.mol

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Bis(triphenylphosphine)nickel(II)chloride Property

Melting point:: 250 °C (dec.)(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: DMSO (Slightly), Methanol (Slightly)
form: Crystals or Powder
color: Dark green to dark gray
Water Solubility: insoluble
Sensitive: Hygroscopic
Exposure limits: NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference: 14264-16-5(CAS DataBase Reference)
NIST Chemistry Reference: dichlorobis(triphenylphosphine)nickel(14264-16-5)
EPA Substance Registry System: Nickel, dichlorobis(triphenylphosphine)- (14264-16-5)

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Safety

Hazard Codes: T
Risk Statements: 45-43-52/53-34-20/21/22
Safety Statements: 53-36/37-45-60-36/37/39-26
RIDADR: 3260
WGK Germany: 3
RTECS: QR6170000
F: 21
TSCA: Yes
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29310095

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H317May cause an allergic skin reaction

H350May cause cancer

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 237116
Product name: Bis(triphenylphosphine)nickel(II) dichloride
Purity: synthesis grade
Packaging: 10g
Price: $56.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 237116
Product name: Bis(triphenylphosphine)nickel(II) dichloride
Purity: synthesis grade
Packaging: 50g
Price: $106.8
Updated: 2024/03/01

TCI Chemical

Product number: B1571
Product name: Bis(triphenylphosphine)nickel(II) Dichloride
Purity: >96.0%(T)
Packaging: 10g
Price: $43
Updated: 2024/03/01

TCI Chemical

Product number: B1571
Product name: Bis(triphenylphosphine)nickel(II) Dichloride
Purity: >96.0%(T)
Packaging: 100g
Price: $200
Updated: 2024/03/01

Alfa Aesar

Product number: 013930
Product name: Dichlorobis(triphenylphosphine)nickel(II), 98%
Packaging: 10g
Price: $43.65
Updated: 2024/03/01

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Bis(triphenylphosphine)nickel(II)chloride Chemical Properties,Usage,Production

Reaction

Catalyst for hydrosilylation of styrene with diphenysilane
Catalyst for carboxylation of various aryl chlorides and other derivatives
Catalyst for C–P cross-coupling reactions of diphenylphosphine oxide with aryl chloride
Catalyst for N?Heterocyclic carbene-assisted cross-coupling reactions of diarylborinic acids with aryl chlorides,tosylates, and sulfamates.
Catalyst for Negishi biaryl ketone synthesis by cross-coupling of amides with aryl zinc halides via carbon-nitrogen bond cleavage.

Chemical Properties

dark green to dark grey crystals or powder

Uses

Coordination compund.

Uses

suzuki reaction

Uses

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

reaction suitability

core: nickel
reagent type: catalyst

Purification Methods

Wash it with glacial AcOH and dry it in a vacuum over H2SO4 and KOH until AcOH is removed. [Venanzi J Chem Soc 719 1958, Kocienski et al. J Org Chem 54 1215 1989, Beilstein 16 IV 953.]

Bis(triphenylphosphine)nickel(II)chloride Preparation Products And Raw materials

Raw materials

Nickel(II) chloride hexahydrate Ethanol Dichloromethane Triphenylphosphine

Preparation Products

6,6'-Dimethyl-2,2'-dipyridyl 3-PHENYLPIPERIDINE

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View Lastest Price from Bis(triphenylphosphine)nickel(II)chloride manufacturers

Hebei Mujin Biotechnology Co.,Ltd

Product: Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-23

Hebei Weibang Biotechnology Co., Ltd

Product: Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-12-04

Shanghai Yunao International Trade Co., Ltd

Product: Bis(triphenylphosphine)nickel(II)chloride 14264-16-5
Price: US $200.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500t
Release date: 2021-09-29

14264-16-5, Bis(triphenylphosphine)nickel(II)chlorideRelated Search:

Potassium chloride Nickel(II) chloride hexahydrate Ammonium chloride Calcium chloride Triphenylphosphine Bis(triphenylphosphine)palladium(II) chloride Polyvinyl chloride Nickel oxide Tris(triphenylphosphine)rhodiu Choline chloride Nickel chloride Sodium chloride Thionyl chloride (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) BIS(TRIPHENYLPHOSPHINE)DICARBONYLNICKEL Bis-(triphenylphosphino)-cuprous borohydride BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE Bis(tricyclohexylphosphine)nickel(II) chloride, 99%

Dichlorobis(triphenyIphosphine)-nickel

tributyl-phosphin compd. with nickelchloride

Nickel(II) chloride bis(triphenylphosphine)

Bis(triphenylphosphine)nick

Dichlorobis(triphenylphosphine)nickel(II), Nickel(II)bis(triphenylphosphine) dichloride

Phosphine, tributyl-, compound with nickel chloride (2:1)

Dichlorobis(triphenylphosphine)nickel(Ⅱ)

Dichlorobis(triphenylphosphine)nickel(II), 98+%

Dichlorobis(triphehylphosphine)nickel(II) ,98%

Bis(triphenylphosphine)nickel(II)chloride, 98% 10GR

Bis(triphenylphosphine)nickel(II) chloride,98% (PPh3)2NiCl2

NSC 137147

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORI

Bis (triphenylphosphine) nickel chloride

NiCl2(PPh3)2

Bis(triphenylphosphine)nickel(II) dichloride 99.99% trace metals basis

Bis(triphenylphosphine)nickel(II) dichloride synthesis grade

Bis(triphenylphosphine)nickel(II)chloride,(PPh3)2NiCl2

NICKEL(II)-BIS(TRIPHENYLPHOSPHINE) DICHLORIDE

NICKEL BIS(TRIPHENYLPHOSPHINE)DICHLORIDE

DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL

DICHLOROBIS(TRIPHENYLPHOSPHINE)NICKEL(II)

BIS(TRIPHENYLPHOSPHINO)NICKEL(II) CHLORIDE

BIS(TRIPHENYLPHOSPHINE)NICKEL(2) DICHLORIDE

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) CHLORIDE

BIS(TRIPHENYLPHOSPHINE)NICKEL(II) DICHLORIDE

Bis(tri-N-butylphosphine)dichloronickel

bis(triphenylphosphine)dichloro-nicke

Bis(triphenylphosphine)dichloronickel

Bis(triphenylphosphine)nickel dichloride

Dichlorobis(triphenyIphosphine)-nickel(II)

dichlorobis(triphenylphosphine)-nicke

Nickel, bis(triphenylphosphine)dichloro-

Nickel, dichlorobis(triphenylphosphine)-

Phosphine, tributyl-, compd. with nickelchloride (2:1)

bis(triphenylphosphine)nickle(II)

Bis-(triphenylphosphino)-nickel chloride

tributyl-phosphincompd.withnickelchloride(2:1)

Bis(triphenylphosphine)nickel(II) chloride for synthesis

TRIPHENYLPHOSPHINE NICKEL (II) CHLORIDE

Bis(triphenylphosphine)nickel(II) chloride, 98+%

Bis(triphenylphosphine)dichloronickel(II)~Dichlorobis(triphenylphosphine)nickel(II)

Bis(triphenylphosphine)nickel(II)chloride,99%

Dichloro bis (Triphenyl phosphine) Nickel catalyst

Bis(triphenylphosphine)nickel(II)chloride,NiCl2(PPh3)2

Dichlorobis(triphenylphosphine)nickel(II), 98%, for synthesis

Bis(triphenylphosphine)nickel(II) Dichloride &gt

(II) dichL

phosphine)nickeL

Bis(triphenylphosphine)nickel(II)chloride ISO 9001：2015 REACH

Bis(triphenylphosphin)nickel(II)chlorid

dichloronickel triphenylphosphane

is(triphenylphosphine)nickel(II)chloride

(PPh3)2NiCl2

NICKEL(2+) ION BIS(TRIPHENYLPHOSPHINE) DICHLORIDE

Bis(Triphenylphosphoranyl)nickel(iv) chloride

14264-16-5

14262-16-5