ChemicalBook > CAS DataBase List > BENZYL GLYCOLATE

BENZYL GLYCOLATE

Product Name: BENZYL GLYCOLATE
CAS No.: 30379-58-9
Chemical Name: BENZYL GLYCOLATE
Synonyms: Benzyl 2-hydroxyacetate;BENZYL GLYCOLATE;Benzyl glycolate 97%;Phenylmethyl glycolate;Ethanol,6-(propylamino)-;BENZYL 2-HYDROXYACETATE 98%;Phenylmethyl 2-hydroxyacetate;Acetic acid, hydroxy-, phenylMethyl ester;Acetic acid, 2-hydroxy-, phenylmethyl ester
CBNumber: CB8437646
Molecular Formula: C9H10O3
Formula Weight: 166.17
MOL File: 30379-58-9.mol

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BENZYL GLYCOLATE Property

Boiling point:: 136 °C/14 mmHg (lit.)
Density: 1.171 g/mL at 25 °C (lit.)
refractive index: n20/D 1.527(lit.)
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Sparingly), Methanol (Slightly)
form: Oil
pka: 12.96±0.10(Predicted)
color: Colourless
InChI: InChI=1S/C9H10O3/c10-6-9(11)12-7-8-4-2-1-3-5-8/h1-5,10H,6-7H2
InChIKey: VPYJBEIOKFRWQZ-UHFFFAOYSA-N
SMILES: C(OCC1=CC=CC=C1)(=O)CO

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Safety

WGK Germany: 3
HS Code: 2918199890

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 410926
Product name: Benzyl glycolate
Purity: 97%
Packaging: 5ml
Price: $90.06
Updated: 2025/07/31

Sigma-Aldrich

Product number: 410926
Product name: Benzyl glycolate
Purity: 97%
Packaging: 25ml
Price: $332.5
Updated: 2025/07/31

TCI Chemical

Product number: P2927
Product name: Benzyl Glycolate
Purity: min. 98.0 %
Packaging: 5G
Price: $53
Updated: 2025/07/31

TCI Chemical

Product number: P2927
Product name: Benzyl Glycolate
Purity: min. 98.0 %
Packaging: 25G
Price: $161
Updated: 2025/07/31

TRC

Product number: B277050
Product name: Benzyl glycolate
Packaging: 25g
Price: $220
Updated: 2021/12/16

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BENZYL GLYCOLATE Chemical Properties,Usage,Production

Uses

Benzyl Glycolate was utilized as a potential moiety for the preparation of phosphonate dipeptides as potential inhibitors of VanX.

Uses

Benzyl glycolate may be used for the synthesis of the methyl [2-(2′-benzyloxy-2′-oxoethyl)-5-acetamido-4,7,8,9- tetra-O-acetyl-3,5-dideoxy-α- and -β-D-glycero-D-galacto-2-nonulopyranosid]onate. It may be used for the preparation of monosaccharide building blocks. It may also be used for the synthesis of the following new polymeric phosphazenes having pendent esters of glycolic or lactic acid as side units:

poly[bis(ethyl glycolato)phosphazene]
poly[bis(ethyl lactato)phosphazene]
poly[bis(benzyl glycolato)phosphazene]
poly[bis(benzyl lactato)phosphazene]

General Description

Benzyl glycolate is a benzyl ester of glycolic acid.

Synthesis

79-14-1

100-39-0

30379-58-9

The general procedure for the synthesis of phenylmethyl ethanoate from ethanoic acid and benzyl bromide was as follows: first, a suspension formed by 2-hydroxyacetic acid (70% aqueous solution, 889 mg, 12.0 mmol) and Cs2CO3 (1955 mg, 6.00 mmol) in a solvent mixture of methanol (22 mL) and water (4 mL) was stirred for 30 min at room temperature. Subsequently, the solvent was removed and the residue was dissolved in DMF (18 mL) pre-cooled to 0 °C. After 10 min, benzyl bromide (2155 mg, 12.6 mmol) was added and the reaction mixture was continued to be stirred for 24 h at room temperature. Upon completion of the reaction, the reaction was quenched with brine (20 mL) and the organic layer was extracted with ethyl acetate (3 x 25 mL). The extract was washed sequentially with water (25 mL) and brine (20 mL), dried over MgSO4 and concentrated in vacuum to afford 1877 mg (97% yield) of benzyl 2-hydroxyacetate as a colorless liquid.HPLC analysis showed a retention time of 2.68 min (70%).

References

[1] Bioorganic and Medicinal Chemistry, 2011, vol. 19, # 16, p. 4903 - 4909
[2] Journal of Organic Chemistry, 2000, vol. 65, # 22, p. 7667 - 7675
[3] Patent: US2016/340365, 2016, A1. Location in patent: Paragraph 0126; 0127
[4] Patent: US2016/297784, 2016, A1. Location in patent: Paragraph 0150; 0151
[5] Journal of the American Chemical Society, 2010, vol. 132, # 31, p. 10920 - 10934

BENZYL GLYCOLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from BENZYL GLYCOLATE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: BENZYL GLYCOLATE 30379-58-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2024-07-25

R&D Scientific Inc.

Product: benzyl 2-hydroxyacetate 30379-58-9
Price: US $990.00/Kg
Min. Order: 1Kg
Purity: 98
Supply Ability: 500 Kg
Release date: 2024-07-11

Career Henan Chemical Co

Product: BENZYL GLYCOLATE 30379-58-9
Price: US $8.80/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 100kg
Release date: 2019-07-04

30379-58-9, BENZYL GLYCOLATERelated Search:

Dimethyl oxalate Sodium glycolate Methyl glycolate Ethylene carbonate Ethyl glycolate HYDROGEN IONOPHORE IV Fluorescein isothiocyanate isomer I

BENZYL GLYCOLATE

Benzyl 2-hydroxyacetate

Acetic acid, hydroxy-, phenylMethyl ester

Benzyl glycolate 97%

Acetic acid, 2-hydroxy-, phenylmethyl ester

Ethanol,6-(propylamino)-

Phenylmethyl 2-hydroxyacetate

Phenylmethyl glycolate

BENZYL 2-HYDROXYACETATE 98%

30379-58-9

HOCH2CO2CH2C6H5

C8 to C9

Carbonyl Compounds

Building Blocks

Esters

Organic Building Blocks

Esters

C8 to C9

Carbonyl Compounds