ChemicalBook > CAS DataBase List > O-BENZYL-L-SERINE

O-BENZYL-L-SERINE

Product Name
O-BENZYL-L-SERINE
CAS No.
4726-96-9
Chemical Name
O-BENZYL-L-SERINE
Synonyms
H-ser(Obzl)-OH;H-SER(BZL)-OH;BENZYL-L-SERINE;H-L-SER(BZL)-OH;L-Serine, O-(phenylmethyl)-;L-Ser(Bzl)-OH;SERINE(BZL)-OH;L-O-Benzylserine;O-BENZYL-L-SERINE;O-benzyl-L-aerine
CBNumber
CB8439589
Molecular Formula
C10H13NO3
Formula Weight
195.22
MOL File
4726-96-9.mol
More
Less

O-BENZYL-L-SERINE Property

Melting point:
~227 °C (dec.)
Boiling point:
359℃
Density 
1.217
refractive index 
7.3 ° (C=2, 1mol/L HCl)
Flash point:
171℃
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Aqueous Acid (Slightly), DMSO (Slightly), Methanol (Slightly), Water (Slightly)
form 
Powder
pka
2.10±0.10(Predicted)
color 
White to off-white
optical activity
[α]20/D +21±2°, c = 2% in acetic acid: water (4:1) (+ 1 Eq HCl)
BRN 
2114846
CAS DataBase Reference
4726-96-9(CAS DataBase Reference)
EPA Substance Registry System
L-Serine, O-(phenylmethyl)- (4726-96-9)
More
Less

Safety

Safety Statements 
24/25
WGK Germany 
3
TSCA 
Yes
HS Code 
29225090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
13900
Product name
O-Benzyl-L-serine
Purity
≥99.0% (NT)
Packaging
5G
Price
$103
Updated
2022/05/15
TCI Chemical
Product number
B0861
Product name
O-Benzyl-L-serine
Purity
>99.0%(T)
Packaging
1g
Price
$31
Updated
2025/07/31
TCI Chemical
Product number
B0861
Product name
O-Benzyl-L-serine
Purity
>99.0%(T)
Packaging
5g
Price
$86
Updated
2025/07/31
TRC
Product number
B316180
Product name
O-Benzyl-L-Serine
Packaging
5g
Price
$70
Updated
2021/12/16
Usbiological
Product number
241019
Product name
O-Benzyl-L-serine 99+%
Packaging
1g
Price
$154
Updated
2021/12/16
More
Less

O-BENZYL-L-SERINE Chemical Properties,Usage,Production

Chemical Properties

Crystalline

Uses

O-Benzyl-L-Serine is used in the preparation of serine analogs as specific agonists for NMDA receptor glycine binding sites. It also functions as an eluent for ligand exchange chromatography for the separation of constrained glutamate receptor ligands.

Definition

ChEBI: O-BENZYL-l-SERINE is a L-alpha-amino acid.

reaction suitability

reaction type: solution phase peptide synthesis

Synthesis

23680-31-1

4726-96-9

The general procedure for the synthesis of (S)-2-amino-3-(benzyloxy)propionic acid from N-BOC-O-benzyl-L-serine was as follows: the compound obtained in the previous step was dissolved in an appropriate amount of dry dichloromethane (DCM), 1.0 mL of trifluoroacetic acid (TFA) and 0.1 mL of triethylsilane were added, and the reaction was stirred for 2 hr at room temperature, and the reaction was monitored by thin-layer chromatography (TLC) The reaction was monitored until complete. Upon completion of the reaction, the pH of the reaction solution was adjusted to 7?8 with saturated sodium bicarbonate solution and subsequently diluted with the addition of dichloromethane (DCM). The organic phase was washed twice with saturated brine and then concentrated to give a yellow oily liquid. Finally, the product was purified by silica gel column chromatography (eluent ratio of chloroform:methanol=15:1) to give a yellow powdery solid product in 62.3% yield.

References

[1] Patent: CN107082754, 2017, A. Location in patent: Paragraph 0119; 0124
[2] Organic Process Research and Development, 2003, vol. 7, # 4, p. 521 - 532
[3] Tetrahedron Letters, 2014, vol. 55, # 30, p. 4149 - 4151
[4] ACS Chemical Neuroscience, 2017, vol. 8, # 8, p. 1681 - 1687
[5] Patent: WO2017/189866, 2017, A1. Location in patent: Paragraph 0210

O-BENZYL-L-SERINE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

O-BENZYL-L-SERINE Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-021-61259138 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44734
Advantage
61
GL Biochem (Shanghai) Ltd
Tel
21-61263452 13641803416
Fax
86-21-61263399
Email
ymbetter@glbiochem.com
Country
China
ProdList
9981
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9878
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
Advantage
64
Chemsky (shanghai) International Co.,Ltd
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
15402
Advantage
60
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
More
Less

View Lastest Price from O-BENZYL-L-SERINE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
O-Benzyl-L-serine 4726-96-9
Price
US $1.00-22.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100000KG
Release date
2024-08-09
Hebei Fengqiang Trading Co., LTD
Product
O-BENZYL-L-SERINE 4726-96-9
Price
US $100.00/bag
Min. Order
1bag
Purity
99
Supply Ability
5000
Release date
2023-08-25
Career Henan Chemical Co
Product
O-BENZYL-L-SERINE 4726-96-9
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
Customized
Release date
2018-12-22

4726-96-9, O-BENZYL-L-SERINERelated Search:


  • H-ser(Obzl)-OH
  • o-(phenylmethyl)-l-serin
  • O-BENZYL-L-SERINE
  • SERINE(BZL)-OH
  • (S)-2-AMINO-3-BENZYLOXYPROPIONIC ACID
  • O-Benzyl-L-serine >=99.0% (NT)
  • L-Ser(Bzl)-OH
  • O-Benzyl-L-serine≥ 99% (HPLC)
  • (2S)-2-amino-3-(benzyloxy)propanoic acid
  • (2S)-2-ammonio-3-phenylmethoxypropanoate
  • L-SERINE BENZYL ETHER
  • BENZYL-L-SERINE
  • H-SER(BZL)-OH
  • H-L-SER(BZL)-OH
  • O-BENZYL-L-SERINE CRYSTALLINE
  • O-Benzyl-L-serine,99%
  • O-Benzyl-L-serine, (S)-2-Amino-3-benzyloxypropanoic acid
  • (S)-2-Amino-3-(benzyloxy)propanoic acid
  • 3-(Benzyloxy)alanine
  • 3-(Benzyloxy)-L-alanine
  • O-(Phenylmethyl)-L-serine
  • L-O-Benzylserine
  • O-benzyl-L-aerine
  • O-Benzyl-L-serine&gt
  • L-Serine, O-(phenylmethyl)-
  • O-Benzyl-<sc>L</sc>-serine
  • O-Benzyl-L-serine 98%
  • 4726-96-9
  • Peptide Synthesis
  • Specialty Synthesis
  • Serine
  • Amino Acid Derivatives
  • Amino Acids and Derivatives
  • Amino Acid Derivatives
  • Amino Acid Derivatives
  • Amino Acids