ChemicalBook > CAS DataBase List > N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE

N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE

Product Name
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
CAS No.
129986-67-0
Chemical Name
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
Synonyms
N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE;N-METHOXY-N-METHYL-2-(TRIPHENYLPHOSPHORANYLIDENE)ACETAMIDE;(N-methoxymethylaminocarbonylmethylene)triphenylphosphoran;N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide 98%;N-methoxy-N-methyl-2-(triphenyl-l5-phosphanylidene)acetamide;[N-METHOXYMETHYLAMINOCARBONYLMETHYLENE]-TRIPHENYLPHOSPHORANE;N-methoxy-N-methyl-2-(triphenyl-l5-phosphaneylidene)acetamide;Acetamide, N-methoxy-N-methyl-2-(triphenylphosphoranylidene)-;N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide, 98 %
CBNumber
CB8445261
Molecular Formula
C22H22NO2P
Formula Weight
363.39
MOL File
129986-67-0.mol
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N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Property

Melting point:
183 °C
Boiling point:
495.6±28.0 °C(Predicted)
Density 
1.18±0.1 g/cm3(Predicted)
storage temp. 
-20°C Freezer, Under inert atmosphere
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Solid
color 
Off White to Pale Yellow
BRN 
4198472
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
9
HS Code 
29241900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
376876
Product name
N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide
Purity
98%
Packaging
5g
Price
$131
Updated
2024/03/01
Sigma-Aldrich
Product number
376876
Product name
N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide
Purity
98%
Packaging
25g
Price
$612
Updated
2024/03/01
TRC
Product number
M337775
Product name
N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide
Packaging
100mg
Price
$55
Updated
2021/12/16
TRC
Product number
M337775
Product name
N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide
Packaging
500mg
Price
$100
Updated
2021/12/16
Matrix Scientific
Product number
089543
Product name
N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)-acetamide
Packaging
5g
Price
$103
Updated
2021/12/16
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N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Chemical Properties,Usage,Production

Chemical Properties

White to off-white powder

Uses

Reactant for:

  • Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines
  • Phosphine-catalyzed asymmetric addition reactions
  • Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction
  • Wittig olefination
  • Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent

N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE Suppliers

Epsilon Chimie
Tel
--
Fax
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Email
pierre.cornec@epsilon-chimie.com
Country
France
ProdList
687
Advantage
0
Epsilon Chimie
Tel
--
Fax
--
Email
pierre.cornec@epsilon-chimie.com
Country
France
ProdList
538
Advantage
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129986-67-0, N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDERelated Search:


  • N-METHOXY-N-METHYL(TRIPHENYL-PHOSPHORANYLIDENE)ACETAMIDE
  • N-METHOXY-N-METHYL-2-(TRIPHENYLPHOSPHORANYLIDENE)ACETAMIDE
  • [N-METHOXYMETHYLAMINOCARBONYLMETHYLENE]-TRIPHENYLPHOSPHORANE
  • N-Methoxy-N-methyl-2-(triphenylphosphoranylidene)acetamide, 98 %
  • (N-methoxymethylaminocarbonylmethylene)triphenylphosphoran
  • N-Methoxy-N-methyl(triphenylphosphoranylidene)acetamide 98%
  • N-methoxy-N-methyl-2-(triphenyl-l5-phosphanylidene)acetamide
  • Acetamide, N-methoxy-N-methyl-2-(triphenylphosphoranylidene)-
  • N-methoxy-N-methyl-2-(triphenyl-l5-phosphaneylidene)acetamide
  • 129986-67-0
  • C6H53PCHCONOCH3CH3
  • C22H22NO2P
  • C-C Bond Formation
  • Olefination
  • Synthetic Reagents
  • Wittig Reagents