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Tizanidine hydrochloride

Description References
Product Name
Tizanidine hydrochloride
CAS No.
64461-82-1
Chemical Name
Tizanidine hydrochloride
Synonyms
AB-021;Gibonz;Zanpeak;TERNELIN;SIRDALUD;ZANAFLEX;Enchinin;Astonelin;DS-103-282;TIZANIDINE HCL
CBNumber
CB8480703
Molecular Formula
C9H9Cl2N5S
Formula Weight
290.17
MOL File
64461-82-1.mol
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Tizanidine hydrochloride Property

Melting point:
280 °C
Flash point:
9℃
storage temp. 
Inert atmosphere,Room Temperature
solubility 
H2O: ~29 mg/mL
form 
solid
color 
white
Merck 
14,9485
CAS DataBase Reference
64461-82-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36-37/39
RIDADR 
UN1230 - class 3 - PG 2 - Methanol, solution
WGK Germany 
3
RTECS 
DK9910000
HS Code 
2934990002
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
T-085
Product name
Tizanidine hydrochloride
Purity
500?μg/mL in methanol, certified reference material, Cerilliant?
Packaging
1mL
Price
$98.5
Updated
2024/03/01
Sigma-Aldrich
Product number
1667905
Product name
Tizanidine hydrochloride
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
200mg
Price
$732
Updated
2024/03/01
TCI Chemical
Product number
T2527
Product name
Tizanidine Hydrochloride
Purity
>98.0%(HPLC)(T)
Packaging
5g
Price
$64
Updated
2024/03/01
TCI Chemical
Product number
T2527
Product name
Tizanidine Hydrochloride
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$192
Updated
2024/03/01
Alfa Aesar
Product number
J67149
Product name
Tizanidine hydrochloride
Purity
99%
Packaging
5g
Price
$93.9
Updated
2023/06/20
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Tizanidine hydrochloride Chemical Properties,Usage,Production

Description

As an adrenergic agonist with muscle relaxant activity, tizanidine hydrochloride belongs to the hydrochloride salt form of tizanidine, which is commonly used in the treatment of spasticity, a condition where muscles in human body spasm, cramp, or become tight induced by a variety of medical problems such as multiple sclerosis, spinal cord injury, Lou Gehrig's disease, spastic diplegia, back pain or certain other injuries to the spine or central nervous system. Besides, as a sleep aid and an anticonvulsant, tizanidine hydrochloride has off-label usage for migraine headaches and is effective for some symptoms of fibromyalgia.
As a short-acting muscle relaxer, the antinociceptive effect of tizanidine hydrochloride functions by blocking excess nerve impulses (pain sensations) of the nerve cells that are sent to the brain and control muscle movement, ultimately resulting in muscle relaxation and spasticity alleviation.

References

https://en.wikipedia.org/wiki/Tizanidine
http://www.webmd.com/drugs/2/drug-1024/tizanidine-oral/details
http://bodyandhealth.canada.com/drug/getdrug/pal-tizanidine
https://pubchem.ncbi.nlm.nih.gov/compound/114869#section=Top
https://www.drugs.com/tizanidine.html

Chemical Properties

Off-White to pale Yellow Solid

Originator

Nimzox,Rapross Pharmaceuticals Pvt. Ltd.,India

Uses

An α2-adrenergic agonist; centrally active myotonolytic. A muscle relaxant (skeletal).

Uses

Tizanidine (Zanaflex) is a drug that is used as a muscle relaxant. It is a centrally acting α-2 adrenergic agonist. It is used to treat the spasms, cramping, and tightness of muscles caused by medical problems such as multiple sclerosis, spastic diplegia,

Uses

Anticoagulant

Definition

ChEBI: Tizanidine hydrochloride is a benzothiadiazole.

Manufacturing Process

14 ml of benzoyl chloride are added to a solution of 11.5 g of ammonium thiocyanate in 150 ml of acetone in an ice bath and the mixture is then stirred for 10 min. This solution is heated to the boil at reflux together with 19 g of 4-amino-5-chloro-2,1,3-benzothiadiazole. The solution is cooled to room temperature and diluted with a 4-fold quantity of water. The precipitate is filtered off and rapidly brought to a boil together with 150 ml of a 2 N aqueous sodium hydroxide solution and kept at the boil for 5 min. The solution is cooled to room temperature, is acidified weakly with glacial acetic acid, the precipitate is filtered off, washed with ether and recrystallized from methanol. The N-(5-chloro-2,1,3-benzothiadiazol-4-yl)thiourea, obtained and this is boiled for 1 h together with 9 g of methyl iodide in 150 ml of methanol. After concentrating by evaporation, crude S-methyl-N-(5-chloro-2,1,3- benzothiadiazol-4-yl)isothiuronium iodide is obtained. 9.8 g of S-methyl-N-(5- chloro-2,1,3-benzothiadiazol-4-yl)isothiuronium iodide are heated to the boil at reflux for 1 h together with 50 ml of methanol and 1.8 ml of ethylene diamine. The solvent is then removed by evaporation and the moist residue is boiled at reflux for 1 h together with 20 ml of n-amyl alcohol. The mixture is subsequently shaken with 50 ml of chloroform and 150 ml of water until all the material is dissolved. 40 ml of a 2 N aqueous sodium hydroxide solution are added to the aqueous phase and extraction is effected with 200 ml of chloroform. The organic phase is dried and concentrated by evaporation. After recrystallizing the residue from methanol with the addition of some active charcoal, 4-(2-imidazolin-2-yl-amino)-5-chloro-2,1,3-benzothiadiazole, having a melting point of 221-223°C, is obtained. The 4-(2-imidazolin-2-yl-amino)-5-chloro-2,1,3-benzothiadiazole hydrochloride may be obtained by the teaction of 4-(2-imidazolin-2-yl-amino)-5-chloro- 2,1,3-benzothiadiazole with hydrochloric acid.

brand name

Tizanidine is INN and BAN.

Therapeutic Function

Muscle relaxant, Spasmolytic

Biological Activity

α 2 -adrenergic receptor agonist. Antinociceptive upon epidural administration in rats (IC 50 = 48 nM). Also binds to imidazoline receptor.

storage

Desiccate at RT

Tizanidine hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Tizanidine hydrochloride Suppliers

Sichuan Credit Chemwerth Pharmaceutical Co., Ltd.
Tel
028-8512-3105 13111882551
Fax
+86 (28) 8512-3105
Country
China
ProdList
15
Advantage
50
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8843
Advantage
52
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
China Langchem Inc.
Tel
0086-21-58956006
Fax
0086-21-58956100
Country
China
ProdList
7811
Advantage
57
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View Lastest Price from Tizanidine hydrochloride manufacturers

Baoji Guokang Bio-Technology Co., Ltd.
Product
Tizanidine hydrochloride 64461-82-1
Price
US $1300.00/KG
Min. Order
1KG
Purity
99
Supply Ability
1T
Release date
2021-06-05
XI'AN TIANGUANGYUAN BIOTECH CO., LTD.
Product
Tizanidine Hydrochloride;Tizanidine hcl 64461-82-1
Price
US $100.00/Kg/Bag
Min. Order
10g
Purity
99%
Supply Ability
500kg
Release date
2021-06-29
Hebei Weibang Biotechnology Co., Ltd
Product
Tizanidine hydrochloride 64461-82-1
Price
US $10.00/KG
Min. Order
100KG
Purity
99%
Supply Ability
100 mt
Release date
2021-09-26

64461-82-1, Tizanidine hydrochlorideRelated Search:


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