ChemicalBook > CAS DataBase List > Methyl 3-methyl-2-butenoate

Methyl 3-methyl-2-butenoate

Product Name
Methyl 3-methyl-2-butenoate
CAS No.
924-50-5
Chemical Name
Methyl 3-methyl-2-butenoate
Synonyms
methyl 3-methylbut-2-enoate;METHYL 3,3-DIMETHYLACRYLATE;3,3-Dimethylacrylate;3,3-DIMETHYL ACRYLIC ACID METHYL ESTER;Methyl senecioate;Methyl 3-methyl-2-bu;Methyl 3,3-DiMethylacr;Methyl dimethylacrylate;Methyl 3-methylcrotonate;Methyl 3,3-dimethacrylate
CBNumber
CB8489089
Molecular Formula
C6H10O2
Formula Weight
114.14
MOL File
924-50-5.mol
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Methyl 3-methyl-2-butenoate Property

Melting point:
-41°C
Boiling point:
70-75 °C60 mm Hg(lit.)
Density 
0.935 g/mL at 20 °C
refractive index 
n20/D 1.4364(lit.)
Flash point:
99 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
Water Solubility 
Soluble in chloroform. Insoluble in water,
Sensitive 
Light Sensitive
λmax
216nm(CH3CN)(lit.)
BRN 
1741592
LogP
1.715 (est)
CAS DataBase Reference
924-50-5(CAS DataBase Reference)
NIST Chemistry Reference
2-Butenoic acid, 3-methyl-, methyl ester(924-50-5)
EPA Substance Registry System
2-Butenoic acid, 3-methyl-, methyl ester (924-50-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
10
Safety Statements 
16-29-33
RIDADR 
UN 3272 3/PG 3
WGK Germany 
1
F 
8
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29161900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
368571
Product name
Methyl 3-methyl-2-butenoate
Purity
97%
Packaging
5g
Price
$62.4
Updated
2024/03/01
Sigma-Aldrich
Product number
368571
Product name
Methyl 3-methyl-2-butenoate
Purity
97%
Packaging
25g
Price
$164.4
Updated
2024/03/01
TCI Chemical
Product number
M2052
Product name
Methyl 3,3-Dimethylacrylate
Purity
>98.0%(GC)
Packaging
25g
Price
$110
Updated
2024/03/01
Alfa Aesar
Product number
L19731
Product name
Methyl 3,3-dimethylacrylate, 98%
Packaging
10g
Price
$62.65
Updated
2024/03/01
Alfa Aesar
Product number
L19731
Product name
Methyl 3,3-dimethylacrylate, 98%
Packaging
50g
Price
$253
Updated
2024/03/01
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Methyl 3-methyl-2-butenoate Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

Methyl 3,3-dimethylacrylate is an important raw material and intermediate used in organic synthesis, pharmaceuticals agrochemicals and dyestuff fields.

Synthesis Reference(s)

Journal of the American Chemical Society, 71, p. 3214, 1949 DOI: 10.1021/ja01177a079

General Description

Methyl 3-methyl-2-butenoate is an α,β-unsaturated ester. It is reported as overripe fruity, ethereal odorant, responsible for the aroma of snake fruit. Rate coefficients for the reaction between the NO3 radical and methyl 3-methyl-2-butenoate has been evaluated.

Methyl 3-methyl-2-butenoate Preparation Products And Raw materials

Raw materials

Sodium hypochlorite 2,5-Hexanedione Isobutylene Chloroform 1,3,5-trioxane 1,4-Dioxane 3,3-Dimethylacrylic acid Phosphite III Ethyl chloroacetate

Preparation Products

methyl(±)cis，trans-2，2-dimethyl-3-(2-methyl-1-propenyl cyclopropane carboxylate) Ciclopirox
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Methyl 3-methyl-2-butenoate Suppliers

Americas 1 Belgium 1 China 282 Europe 1 Germany 5 India 4 Japan 1 Russia 1 Switzerland 1 The Netherlands 1 United Kingdom 5 United States 30 Global 333
HBCChem, Inc.
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View Lastest Price from Methyl 3-methyl-2-butenoate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
Methyl 3-methyl-2-butenoate 924-50-5
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-22
Hebei Mujin Biotechnology Co.,Ltd
Product
Methyl 3-methyl-2-butenoate 924-50-5
Price
US $60.00/KG
Min. Order
25KG
Purity
99.99%
Supply Ability
200ton
Release date
2023-08-15
Hebei Yanxi Chemical Co., Ltd.
Product
3,3-Dimethylacrylic Acid Methyl Ester 924-50-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99.00%
Supply Ability
20tons
Release date
2023-09-19

924-50-5, Methyl 3-methyl-2-butenoateRelated Search:

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  • 924-50-5
  • 924-50-0
  • CH32CCHCOOCH3
  • META - METH
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