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POLY(METHYL METHACRYLATE)

Product Name
POLY(METHYL METHACRYLATE)
CAS No.
9010-88-2
Chemical Name
POLY(METHYL METHACRYLATE)
Synonyms
METHYL METHACRYLATE POLYMER;POLY(METHYL METHACRYLATE), ISOTACTIC;LUCITE;Eudragit E 30D;Polyacrylic Resin III;METHYL METHACRYLATE RESIN;POLYBEAD(R) PMMA MICROSPHERES;POLY(METHYL METHACRYLATE) 600;POLYMETHYL METHACRYLATE BEADS;POLY(METHYL METHACRYLATE) 2'000
CBNumber
CB5169353
Molecular Formula
C10H16O4
Formula Weight
200.23
MOL File
9010-88-2.mol
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POLY(METHYL METHACRYLATE) Property

Melting point:
150 °C
Density 
1.2 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.49
solubility 
alcohols and aliphatic hydrocarbons: insoluble
form 
powder
EPA Substance Registry System
Ethyl acrylate methyl methacrylate polymer (9010-88-2)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/22
Safety Statements 
36
WGK Germany 
3
RTECS 
TR0400000
Autoignition Temperature
580 °F
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
182249
Product name
Poly(methyl methacrylate-co-ethyl acrylate)
Purity
ethyl acrylate <5wt. %, average M
Packaging
25g
Price
$88
Updated
2024/03/01
Sigma-Aldrich
Product number
182249
Product name
Poly(methyl methacrylate-co-ethyl acrylate)
Purity
ethyl acrylate <5wt. %, average M
Packaging
1kg
Price
$202.2
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0977199
Product name
ETHYL ACRYLATE-METHYL METHACRYLATE LATEX
Purity
95.00%
Packaging
5MG
Price
$501.7
Updated
2021/12/16
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POLY(METHYL METHACRYLATE) Chemical Properties,Usage,Production

Uses

Poly(methyl methacrylate-co-ethyl acrylate) (PMMAEA) copolymers may be used to prepare single phase mixture with phenolic derivative. PMMAEA may be used to form latex interpenetrating polymer networks (LIPNs). Membranes of PMMAEA were reportedly used for separation of heavy metal ions from aqueous solutions.

Preparation

Acrylic acid is H2C=CH-COOH and methacrylic acid is H2C=C(CH3)COOH. These compounds and their methyl esters are both quite reactive and difficult to store and handle. The monomer used to form poly(methyl methacrylate), 2-hydroxy-2-methylpropanenitrile, is prepared by the following reaction:

2-Hydroxy-2-methylpropanenitrile is then reacted with methanol (or other alcohol) to yield methacrylate ester. Free-radical polymerization is initiated by peroxide or azo catalysts and produce poly(methyl methacrylate) resins having the following formula:

Key properties are good resistance to heat, light, and weathering. This polymer is unaffected by most detergents, cleaning agents, and solutions of inorganic acids, alkalies, and aliphatic hydrocarbons. Poly(methyl methacrylate) has light transmittance of 92% with a haze of 1–3% and its clarity is equal to glass.

Industrial uses

Poly(methyl methacrylate), the polymerizedmethyl ester of methacrylic acid, is thermoplastic.The method of polymerization may be variedto achieve specific physical properties, orthe monomer may be combined with other components.Sheet materials may be prepared bycasting the monomer in bulk. Suspension polymerizationof the monomeric ester may be usedto prepare molding powders.
Conventional poly(methyl methacrylate) isamorphous; however, reports have been publishedof methyl methacrylate polymers of regularconfiguration, which are susceptible tocrystallization. Both the amorphous and crystallineforms of such crystallization-susceptible polymers possess physical properties that aredifferent from those of the conventional polymer,and suggest new applications.

Industrial uses

Polymethyl methacrylate is a clear solid, hardbut easily scratched. Its dielectric properties areonly moderate, and its use is restricted to undemandingconditions at normal ambient temperatures,usually in a molded form, where appearanceis important.

POLY(METHYL METHACRYLATE) Preparation Products And Raw materials

Raw materials

Preparation Products

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POLY(METHYL METHACRYLATE) Suppliers

HangZhou YuHao Chemical Technology Co., Ltd.
Tel
0571-82693216
Fax
0571-82880190
Email
info@yuhaochemical.com
Country
China
ProdList
2031
Advantage
58
Chizhou Kailong Import and Export Trade Co., Ltd.
Tel
Fax
-
Email
xg01_gj@163.com
Country
China
ProdList
9503
Advantage
50
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51471
Advantage
80
Shenzhen Sendi Biological Technology Co., Ltd.
Tel
18124570582 TEL:0755-23574479 2355327139
Fax
0755-23229476 QQ: 2355327139
Email
siliao02@yccreate.com
Country
China
ProdList
6120
Advantage
58
Shanghai Orgchem Co.,Ltd.
Tel
+86-21-5877 1921
Fax
+86-21-5877 1925
Email
info@chemofchina.com
Country
China
ProdList
9661
Advantage
55
Wuhan FengyaoTonghui Chemical Products Co., Ltd.
Tel
027-87466105 15377573527
Email
2678564200@qq.com
Country
China
ProdList
17997
Advantage
58
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400-6387771-6037 18920794737
Email
sales@heowns.com
Country
China
ProdList
20499
Advantage
60
Chengdu Saint - Kay Biotechnology Co., Ltd.
Tel
028-85157043 15882256948
Email
676046971@qq.com
Country
China
ProdList
4392
Advantage
58
Hubei Dechao Chemical Co., Ltd.
Tel
027-87290866 18071515590
Fax
027-87290866
Email
375787773@qq.com
Country
China
ProdList
116
Advantage
58
Hubei Zhonglong Kangsheng Fine Chemical Co., Ltd.
Tel
15926260361
Fax
QQ:1930063008
Email
1930063008@qq.com
Country
China
ProdList
5094
Advantage
58
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View Lastest Price from POLY(METHYL METHACRYLATE) manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
POLY(METHYL METHACRYLATE) 9010-88-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2020-04-26

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