Cyclohexylboronic acid pinacol ester
- Product Name
- Cyclohexylboronic acid pinacol ester
- CAS No.
- 87100-15-0
- Chemical Name
- Cyclohexylboronic acid pinacol ester
- Synonyms
- 1,3,2-Dioxaborolane, 2-cyclohe;Cyclohexane acid pinacol ester;Cyclohexylboronic acid pinacol este;CYCLOHEXYLBORONIC ACID PINACOL ESTER;CYCLOHEXYLBORONIC ACID ACID PINACOL ESTER;REF DUPL: Cyclohexylboronic acid pinacol ester;2-Cyclohexyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;1,3,2-Dioxaborolane, 2-cyclohexyl-4,4,5,5-tetraMethyl-;2-Cyclohexyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)cyclohexane
- CBNumber
- CB8491026
- Molecular Formula
- C12H23BO2
- Formula Weight
- 210.12
- MOL File
- 87100-15-0.mol
Cyclohexylboronic acid pinacol ester Property
- Boiling point:
- 244.7±9.0 °C(Predicted)
- Density
- 0.93±0.1 g/cm3(Predicted)
- refractive index
- 1.4460 to 1.4500
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Liquid
- color
- Colorless
- InChI
- InChI=1S/C12H23BO2/c1-11(2)12(3,4)15-13(14-11)10-8-6-5-7-9-10/h10H,5-9H2,1-4H3
- InChIKey
- OUEVCDGYTKLNMJ-UHFFFAOYSA-N
- SMILES
- O1C(C)(C)C(C)(C)OB1C1CCCCC1
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- HazardClass
- IRRITANT
- HS Code
- 29310099
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- C3101
- Product name
- 2-Cyclohexyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Purity
- >97.0%(GC)(T)
- Packaging
- 1g
- Price
- $30
- Updated
- 2025/07/31
- Product number
- C3101
- Product name
- 2-Cyclohexyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
- Purity
- >97.0%(GC)(T)
- Packaging
- 5g
- Price
- $104
- Updated
- 2025/07/31
- Product number
- C991713
- Product name
- Cyclohexylboronicacid,pinacolester
- Packaging
- 250mg
- Price
- $55
- Updated
- 2021/12/16
- Product number
- 009774
- Product name
- Cyclohexylboronic acid pinacol ester
- Purity
- 96%
- Packaging
- 1g
- Price
- $71
- Updated
- 2021/12/16
- Product number
- 39915
- Product name
- 2-Cyclohexyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane,97%(GC)
- Purity
- 97%(GC)
- Packaging
- 1G
- Price
- $36.96
- Updated
- 2021/12/16
Cyclohexylboronic acid pinacol ester Chemical Properties,Usage,Production
Uses
Cyclohexylboronic acid, pinacol ester
Synthesis
76-09-5
4441-56-9
87100-15-0
The general procedure for the synthesis of 2-cyclohexyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane from pinacol and cyclohexylboronic acid is as follows: a mixture of cyclohexylboronic acid (1.0 eq.), pinacol (1.0 eq.), and anhydrous MgSO4 (4.0 eq.) in ethyl ether (Et2O, 0.5 M) was stirred for 16 h at room temperature. After completion of the reaction, the reaction mixture was filtered and the solvent was removed under vacuum. The crude product was purified by distillation or fast column chromatography to give pure 2-cyclohexyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane.
References
[1] Journal of the American Chemical Society, 2012, vol. 134, # 27, p. 11298 - 11298
[2] Synthesis (Germany), 2016, vol. 48, # 19, p. 3241 - 3253
[3] Journal of the American Chemical Society, 2018, vol. 140, # 44, p. 14677 - 14686
[4] Journal of the American Chemical Society, 2017, vol. 139, # 28, p. 9519 - 9522
[5] Synlett, 2018, vol. 29, # 8, p. 1092 - 1094
Cyclohexylboronic acid pinacol ester Preparation Products And Raw materials
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Preparation Products
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View Lastest Price from Cyclohexylboronic acid pinacol ester manufacturers
- Product
- Cyclohexylboronic acid pinacol ester 87100-15-0
- Price
- US $3.00-9.00/KG
- Min. Order
- 0.1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2025-07-02
- Product
- Cyclohexylboronic acid pinacol ester 87100-15-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
- Product
- Cyclohexylboronic acid pinacol ester 87100-15-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09