ChemicalBook > CAS DataBase List > 4-(CHLOROMETHYL)BENZYL ALCOHOL 99

4-(CHLOROMETHYL)BENZYL ALCOHOL 99

Product Name
4-(CHLOROMETHYL)BENZYL ALCOHOL 99
CAS No.
16473-35-1
Chemical Name
4-(CHLOROMETHYL)BENZYL ALCOHOL 99
Synonyms
1-(Chloromethyl)-4-(hydroxymethyl)benzene;Pulesafu impurity 13;Plerixafor Impurity 44;p-hydroxymethylbenzyl chloride;4-(hydroxymethyl)benzyl chloride;BenzeneMethanol, 4-(chloroMethyl)-;4-(CHLOROMETHYL)BENZYL ALCOHOL 99;4-(ChloroMethyl)benzyl alcohol 99%;4-(ChloroMethyl)benzyl alcohol;Benzenemethanol, 4-(chloromethyl)- (9CI, ACI)
CBNumber
CB8504524
Molecular Formula
C8H9ClO
Formula Weight
156.61
MOL File
16473-35-1.mol
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4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Property

Melting point:
58-60 °C (lit.)
Boiling point:
276℃
Density 
1.195
Flash point:
123℃
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
wooly solid
pka
14.27±0.10(Predicted)
color 
White
InChI
InChI=1S/C8H9ClO/c9-5-7-1-3-8(6-10)4-2-7/h1-4,10H,5-6H2
InChIKey
OGALXJIOJZXBBP-UHFFFAOYSA-N
SMILES
C1(CO)=CC=C(CCl)C=C1
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 1759 8/PG 2
WGK Germany 
3
HS Code 
2906290090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
526126
Product name
4-(Chloromethyl)benzyl alcohol
Purity
99%
Packaging
1g
Price
$36.5
Updated
2025/07/31
Sigma-Aldrich
Product number
526126
Product name
4-(Chloromethyl)benzyl alcohol
Purity
99%
Packaging
5g
Price
$106
Updated
2025/07/31
TCI Chemical
Product number
C1877
Product name
[4-(Chloromethyl)phenyl]methanol
Purity
min. 98.0 %
Packaging
5G
Price
$87
Updated
2025/07/31
TCI Chemical
Product number
C1877
Product name
[4-(Chloromethyl)phenyl]methanol
Purity
min. 98.0 %
Packaging
25G
Price
$261
Updated
2025/07/31
TRC
Product number
C588013
Product name
(4-(Chloromethyl)phenyl)methanol
Packaging
50mg
Price
$45
Updated
2021/12/16
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4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Chemical Properties,Usage,Production

Uses

4-(Chloromethyl)benzyl alcohol may be used in the synthesis of 4-(chloromethyl)benzyl acetate.

General Description

4-(Chloromethyl)benzyl alcohol can be synthesized from 4-(chloromethyl)benzoyl chloride.

Synthesis

1642-81-5

16473-35-1

Example 1: (1) Synthesis of [4-(chloromethyl)benzyl]alcohol: To a solution of tetrahydrofuran containing 4-(chloromethyl)benzoic acid (60 mL THF), 1M borane-THF solution (90 mL) was slowly added. The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, methanol (50 mL) was added to quench the reaction. Subsequently, the solvent was removed by rotary evaporator and the obtained residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 4/1 to 3/1) to afford 4-(chloromethyl)benzyl alcohol (8.84 g, 96% yield) as a colorless solid.

References

[1] Patent: WO2003/106403, 2003, A1. Location in patent: Page 23
[2] Patent: US5387709, 1995, A
[3] Patent: WO2015/51045, 2015, A2. Location in patent: Page/Page column 161-162
[4] Patent: US2016/215288, 2016, A1. Location in patent: Paragraph 0602; 0611
[5] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 16, p. 4481 - 4486

4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Suppliers

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View Lastest Price from 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
(4-Chloromethyl-phenyl)-methanol 16473-35-1
Price
US $3.00-9.00/KG
Min. Order
0.1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2025-06-19
Hebei Fengqiang Trading Co., LTD
Product
4-(CHLOROMETHYL)BENZYL ALCOHOL 99 16473-35-1
Price
US $100.00/bag
Min. Order
1bag
Purity
99
Supply Ability
5000
Release date
2023-09-15
Career Henan Chemical Co
Product
4-(CHLOROMETHYL)BENZYL ALCOHOL 99 16473-35-1
Price
US $1.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1000KG
Release date
2018-12-16

16473-35-1, 4-(CHLOROMETHYL)BENZYL ALCOHOL 99Related Search:

1,2-Bis(chloromethyl)benzene 4-Methylbenzyl chloride P-XYLENE 4-CHLOROMETHYLBENZALDEHYDE; >95%DISCONTINUED 10/25/01 1,4-Benzenedimethanol 1,3-Bis(chloromethyl)benzene 1,2-BIS(TOSYLOXY)ETHANE Ethyl 4-chloromethylbenzoate 4-(Chloromethyl)benzoic acid Methyl 4-(chloromethyl)benzoate Methyl 4-chlorocarbonylbenzoate 4-Chloroformylphthalic anhydride 5-CHLOROMETHYLFLUORESCEIN DIACETATE 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 2,4-DIFLUOROPHENYL 4-(CHLOROMETHYL)BENZOATE CHEMBRDG-BB 5401661 5-(AND-6)-CHLOROMETHYL-2',7'-DICHLORODIHYDROFLUORESCEIN DIACETATE 5-(CHLOROMETHYL)MECONIN

  • 4-(CHLOROMETHYL)BENZYL ALCOHOL 99
  • BenzeneMethanol, 4-(chloroMethyl)-
  • 1-(Chloromethyl)-4-(hydroxymethyl)benzene
  • 4-<WBR>(ChloroMethyl)<WBR>benzyl alcohol
  • 4-(ChloroMethyl)benzyl alcohol 99%
  • p-hydroxymethylbenzyl chloride
  • 4-(hydroxymethyl)benzyl chloride
  • Plerixafor Impurity 44
  • Benzenemethanol, 4-(chloromethyl)- (9CI, ACI)
  • Pulesafu impurity 13
  • 16473-35-1
  • ClCH2C6H4CH2OH
  • Alcohols
  • C7 to C8
  • Oxygen Compounds
  • 16473-35-1