4-(CHLOROMETHYL)BENZYL ALCOHOL 99
- Product Name
- 4-(CHLOROMETHYL)BENZYL ALCOHOL 99
- CAS No.
- 16473-35-1
- Chemical Name
- 4-(CHLOROMETHYL)BENZYL ALCOHOL 99
- Synonyms
- 1-(Chloromethyl)-4-(hydroxymethyl)benzene;Pulesafu impurity 13;Plerixafor Impurity 44;p-hydroxymethylbenzyl chloride;4-(hydroxymethyl)benzyl chloride;BenzeneMethanol, 4-(chloroMethyl)-;4-(CHLOROMETHYL)BENZYL ALCOHOL 99;4-(ChloroMethyl)benzyl alcohol 99%;4-
(ChloroMethyl) benzyl alcohol;Benzenemethanol, 4-(chloromethyl)- (9CI, ACI) - CBNumber
- CB8504524
- Molecular Formula
- C8H9ClO
- Formula Weight
- 156.61
- MOL File
- 16473-35-1.mol
4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Property
- Melting point:
- 58-60 °C (lit.)
- Boiling point:
- 276℃
- Density
- 1.195
- Flash point:
- 123℃
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- wooly solid
- pka
- 14.27±0.10(Predicted)
- color
- White
- InChI
- InChI=1S/C8H9ClO/c9-5-7-1-3-8(6-10)4-2-7/h1-4,10H,5-6H2
- InChIKey
- OGALXJIOJZXBBP-UHFFFAOYSA-N
- SMILES
- C1(CO)=CC=C(CCl)C=C1
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 1759 8/PG 2
- WGK Germany
- 3
- HS Code
- 2906290090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 526126
- Product name
- 4-(Chloromethyl)benzyl alcohol
- Purity
- 99%
- Packaging
- 1g
- Price
- $36.5
- Updated
- 2025/07/31
- Product number
- 526126
- Product name
- 4-(Chloromethyl)benzyl alcohol
- Purity
- 99%
- Packaging
- 5g
- Price
- $106
- Updated
- 2025/07/31
- Product number
- C1877
- Product name
- [4-(Chloromethyl)phenyl]methanol
- Purity
- min. 98.0 %
- Packaging
- 5G
- Price
- $87
- Updated
- 2025/07/31
- Product number
- C1877
- Product name
- [4-(Chloromethyl)phenyl]methanol
- Purity
- min. 98.0 %
- Packaging
- 25G
- Price
- $261
- Updated
- 2025/07/31
- Product number
- C588013
- Product name
- (4-(Chloromethyl)phenyl)methanol
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Chemical Properties,Usage,Production
Uses
4-(Chloromethyl)benzyl alcohol may be used in the synthesis of 4-(chloromethyl)benzyl acetate.
General Description
4-(Chloromethyl)benzyl alcohol can be synthesized from 4-(chloromethyl)benzoyl chloride.
Synthesis
1642-81-5
16473-35-1
Example 1: (1) Synthesis of [4-(chloromethyl)benzyl]alcohol: To a solution of tetrahydrofuran containing 4-(chloromethyl)benzoic acid (60 mL THF), 1M borane-THF solution (90 mL) was slowly added. The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, methanol (50 mL) was added to quench the reaction. Subsequently, the solvent was removed by rotary evaporator and the obtained residue was purified by silica gel column chromatography (eluent: hexane/ethyl acetate = 4/1 to 3/1) to afford 4-(chloromethyl)benzyl alcohol (8.84 g, 96% yield) as a colorless solid.
References
[1] Patent: WO2003/106403, 2003, A1. Location in patent: Page 23
[2] Patent: US5387709, 1995, A
[3] Patent: WO2015/51045, 2015, A2. Location in patent: Page/Page column 161-162
[4] Patent: US2016/215288, 2016, A1. Location in patent: Paragraph 0602; 0611
[5] Bioorganic and Medicinal Chemistry Letters, 2007, vol. 17, # 16, p. 4481 - 4486
4-(CHLOROMETHYL)BENZYL ALCOHOL 99 Preparation Products And Raw materials
Raw materials
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View Lastest Price from 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 manufacturers
- Product
- (4-Chloromethyl-phenyl)-methanol 16473-35-1
- Price
- US $3.00-9.00/KG
- Min. Order
- 0.1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2025-06-19
- Product
- 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 16473-35-1
- Price
- US $100.00/bag
- Min. Order
- 1bag
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2023-09-15
- Product
- 4-(CHLOROMETHYL)BENZYL ALCOHOL 99 16473-35-1
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1000KG
- Release date
- 2018-12-16