DIETHYLSILANE

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Description Sources

Product Name: DIETHYLSILANE
CAS No.: 542-91-6
Chemical Name: DIETHYLSILANE
Synonyms: (C2H5)2SiH2;3-Silapentane;diethyl-silan;DIETHYLSILANE;diethylsilicon;Silane, diethyl-;Diethylsilane,97%;Diethylsilane,98+%;Diethylsilanealso high purity;Diethylsilane,highpuritymin99%
CBNumber: CB8680635
Molecular Formula: C4H12Si
Formula Weight: 88.22
MOL File: 542-91-6.mol

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DIETHYLSILANE Property

Melting point:: -132°C
Boiling point:: 56 °C (lit.)
Density: 0.681 g/mL at 25 °C (lit.)
refractive index: n20/D 1.391(lit.)
Flash point:: −20 °F
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Miscible with terahydrofuran, diethyl ether, 1,4-dioxane and benzene.
form: liquid
Specific Gravity: 0.683
Hydrolytic Sensitivity: 3: reacts with aqueous base
Sensitive: Air Sensitive
Merck: 14,3128
BRN: 1730902
CAS DataBase Reference: 542-91-6(CAS DataBase Reference)
EPA Substance Registry System: Silane, diethyl- (542-91-6)

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Safety

Hazard Codes: F
Risk Statements: 11
Safety Statements: 16-23-24/25
RIDADR: UN 1993 3/PG 2
WGK Germany: 1
TSCA: Yes
HazardClass: 3
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Hazard statements: H225Highly Flammable liquid and vapour
Precautionary statements: P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 423815
Product name: Diethylsilane
Purity: 99%
Packaging: 5ml
Price: $80.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 423815
Product name: Diethylsilane
Purity: 99%
Packaging: 25ml
Price: $308
Updated: 2024/03/01

Alfa Aesar

Product number: L16468
Product name: Diethylsilane, 97+%
Packaging: 5g
Price: $60.3
Updated: 2024/03/01

Alfa Aesar

Product number: L16468
Product name: Diethylsilane, 97+%
Packaging: 25g
Price: $190
Updated: 2024/03/01

Biosynth Carbosynth

Product number: FD61147
Product name: Diethylsilane
Packaging: 10g
Price: $240
Updated: 2021/12/16

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DIETHYLSILANE Chemical Properties,Usage,Production

Description

Diethylsilane is a reagent used in the chemical vapor deposition of SiO2 for microelectronics. It is also used as a precursor to prepare (3-allylsulfanyl-propyl)-diethyl-silane by using (Ph3P)3RhCl as reagent. It can also be used as a reductant in catalytic reduction of secondary amides to imines and secondary amines has been achieved using readily available iridium catalysts such as [Ir(COE)2Cl]2. This system requires low catalyst loading and shows high efficiency and an appreciable level of functional group tolerance. As a reduction agent, it also be used to convert polycarboxylic acids into their corresponding alkanes.

Sources

Levy, R. A., J. M. Grow, and G. S. Chakravarthy. "Low-pressure chemical vapor deposition of silicon dioxide using diethylsilane." Cheminform 24.28(1993):851-854.
https://www.alfa.com/en/catalog/L16468/
https://www.sigmaaldrich.com/catalog/product/aldrich/423815?lang=en&region=US
https://pubs.acs.org/doi/full/10.1021/ja304547s#citing
Nimmagadda, Rama D., and C. Mcrae. Cheminform 37.35(2006):3505-3508.

Uses

Diethylsilane is used as a precursor to prepare (3-allylsulfanyl-propyl)-diethyl-silane by using (Ph3P)3RhCl as reagent. It is also used in the chemical vapor deposition of SiO2 for microelectronics.

Application

Used in the ‘in-situ’ preparation of diborane and haloboranes.

DIETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from DIETHYLSILANE manufacturers

Career Henan Chemical Co

Product: DIETHYLSILANE 542-91-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 97%-99.9%
Supply Ability: 100kg
Release date: 2019-12-25

542-91-6, DIETHYLSILANERelated Search:

TETRAETHYLSILANE DI-TERT-BUTYLDICHLOROSILANE 1,3-DICHLORO-1,1,3,3-TETRAISOPROPYLDISILOXANE Triethylsilyl trifluoromethanesulfonate Chlorotriethylsilane TRI-N-HEXYLCHLOROSILANE Triisopropylsilane TRIBUTYLSILANE Dichlorodiethylsilane TRI-N-PROPYLSILANE TRI-N-PROPYLCHLOROSILANE Triethylsilane Triisopropylsilyl chloride TRIHEXYLSILANE CHLOROTRIBENZYLSILANE TRIETHYLBROMOSILANE Tributylchlorosilane Dimethyldiethylsilane

(C2H5)2SiH2

diethyl-silan

Silane, diethyl-

DIETHYLSILANE

Diethylsilanealso high purity

Diethylsilane, high purity min 99%

3-Silapentane

Diethylsilane,98+%

Diethylsilane,97%

Diethylsilane,highpuritymin99%

diethylsilicon

542-91-6

C4H12Si1

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