ChemicalBook > CAS DataBase List > 2-Methylcyclohexanol

2-Methylcyclohexanol

Product Name
2-Methylcyclohexanol
CAS No.
583-59-5
Chemical Name
2-Methylcyclohexanol
Synonyms
2-METHYLHEXALIN;HEXAHYDRO-O-CRESOL;2-metilcicloesanone;o-methyl-cyclohexano;2-METHYLCYCLOHEXANOL;O-METHYLCYCLOHEXANOL;2-methyl-cyclohexano;2-METHYLCYCLOHEXAN-1-OL;Cyclohexanol, o-methyl-;Cyclohexanol, 2-methyl-
CBNumber
CB8728571
Molecular Formula
C7H14O
Formula Weight
114.19
MOL File
583-59-5.mol
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2-Methylcyclohexanol Property

Melting point:
-38 °C
Boiling point:
171-173 °C(lit.)
Density 
0.93 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.463
Flash point:
138 °F
form 
Liquid
pka
15.33±0.40(Predicted)
Specific Gravity
0.930 (20/4℃)
color 
Clear colorless
Odor
at 100.00?%. mild coconut oil
Water Solubility 
slightly soluble
BRN 
1847535
Dielectric constant
13.5
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
LogP
1.818 (est)
CAS DataBase Reference
583-59-5(CAS DataBase Reference)
NIST Chemistry Reference
Cyclohexanol, 2-methyl-(583-59-5)
EPA Substance Registry System
Cyclohexanol, 2-methyl- (583-59-5)
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Safety

Hazard Codes 
Xn
Risk Statements 
20-36-20/22
Safety Statements 
24/25
RIDADR 
UN 2617 3/PG 3
WGK Germany 
1
RTECS 
GW0220000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29061200
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H332Harmful if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
153087
Product name
2-Methylcyclohexanol, mixture of cis and trans
Purity
99%
Packaging
250ml
Price
$115
Updated
2025/07/31
Sigma-Aldrich
Product number
153087
Product name
2-Methylcyclohexanol, mixture of cis and trans
Purity
99%
Packaging
1l
Price
$320.15
Updated
2025/07/31
TCI Chemical
Product number
M0194
Product name
2-Methylcyclohexanol (cis- and trans- mixture)
Purity
>98.0%(GC)
Packaging
25mL
Price
$22
Updated
2025/07/31
TCI Chemical
Product number
M0194
Product name
2-Methylcyclohexanol (cis- and trans- mixture)
Purity
>98.0%(GC)
Packaging
500mL
Price
$89
Updated
2025/07/31
Frontier Specialty Chemicals
Product number
JK383365
Product name
2-Methylcyclohexanol,99%,mixtureofcisandtrans
Packaging
1000g
Price
$110
Updated
2021/12/16
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2-Methylcyclohexanol Chemical Properties,Usage,Production

Chemical Properties

colourless viscous liquid with an aromatic odour. Less dense than water and insoluble in water. Hence floats on water.

Uses

2-Methylcyclohexanol is used in the preparation of acetic acid-(2-methyl-cyclohexyl ester) by reaction with acetic anhydride. Further, it is used to study the effect of organic solvents on epoxide hydrolase.

Reactions

2-methylcyclohexanol undergoes a dehydration reaction when reacted with conc. Sulfuric acid to form a mixture of 1-metyl and 3-methylcyclohexene.

Reactivity Profile

2-METHYLCYCLOHEXANOL is an alcohol. Flammable and/or toxic gases are generated by the combination of these materials with alkali metals, nitrides, and strong reducing agents. Contact with strong oxidizers may cause fires and explosions. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. They exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. Special Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon monoxide, may be formed when involved in fire (USCG, 1999).

Purification Methods

Dry 2-methylcyclohexanol with Na2SO4 and fractionate it under vacuum. Note: The cis-isomer has b 165o/760mm, and the trans-isomer has b 166.5o/760mm. [Eliel & Haber J Org Chem 23 2041 1958, Beilstein 6 III 61, 6 IV 100.]

2-Methylcyclohexanol Preparation Products And Raw materials

Raw materials

Preparation Products

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