2-Methylcyclohexanol

Product Name: 2-Methylcyclohexanol
CAS No.: 583-59-5
Chemical Name: 2-Methylcyclohexanol
Synonyms: 2-METHYLHEXALIN;HEXAHYDRO-O-CRESOL;2-metilcicloesanone;o-methyl-cyclohexano;2-METHYLCYCLOHEXANOL;O-METHYLCYCLOHEXANOL;2-methyl-cyclohexano;2-METHYLCYCLOHEXAN-1-OL;Cyclohexanol, o-methyl-;Cyclohexanol, 2-methyl-
CBNumber: CB8728571
Molecular Formula: C7H14O
Formula Weight: 114.19
MOL File: 583-59-5.mol

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2-Methylcyclohexanol Property

Melting point:: -38 °C
Boiling point:: 171-173 °C(lit.)
Density: 0.93 g/mL at 25 °C(lit.)
refractive index: n20/D 1.463
Flash point:: 138 °F
form: Liquid
pka: 15.33±0.40(Predicted)
Specific Gravity: 0.930 (20/4℃)
color: Clear colorless
Odor: at 100.00?%. mild coconut oil
Water Solubility: slightly soluble
BRN: 1847535
Dielectric constant: 13.5
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
LogP: 1.818 (est)
CAS DataBase Reference: 583-59-5(CAS DataBase Reference)
NIST Chemistry Reference: Cyclohexanol, 2-methyl-(583-59-5)
EPA Substance Registry System: Cyclohexanol, 2-methyl- (583-59-5)

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Safety

Hazard Codes: Xn
Risk Statements: 20-36-20/22
Safety Statements: 24/25
RIDADR: UN 2617 3/PG 3
WGK Germany: 1
RTECS: GW0220000
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29061200

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H332Harmful if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 153087
Product name: 2-Methylcyclohexanol, mixture of cis and trans
Purity: 99%
Packaging: 250ml
Price: $108
Updated: 2023/06/20

Sigma-Aldrich

Product number: 153087
Product name: 2-Methylcyclohexanol, mixture of cis and trans
Purity: 99%
Packaging: 1l
Price: $314
Updated: 2023/06/20

TCI Chemical

Product number: M0194
Product name: 2-Methylcyclohexanol (cis- and trans- mixture)
Purity: >98.0%(GC)
Packaging: 25mL
Price: $18
Updated: 2023/06/20

TCI Chemical

Product number: M0194
Product name: 2-Methylcyclohexanol (cis- and trans- mixture)
Purity: >98.0%(GC)
Packaging: 500mL
Price: $72
Updated: 2023/06/20

Alfa Aesar

Product number: A12877
Product name: 2-Methylcyclohexanol, cis + trans, 97%
Packaging: 500ml
Price: $89.4
Updated: 2023/06/20

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2-Methylcyclohexanol Chemical Properties,Usage,Production

Chemical Properties

colourless viscous liquid with an aromatic odour. Less dense than water and insoluble in water. Hence floats on water.

Uses

2-Methylcyclohexanol is used in the preparation of acetic acid-(2-methyl-cyclohexyl ester) by reaction with acetic anhydride. Further, it is used to study the effect of organic solvents on epoxide hydrolase.

Reactions

2-methylcyclohexanol undergoes a dehydration reaction when reacted with conc. Sulfuric acid to form a mixture of 1-metyl and 3-methylcyclohexene.

Reactivity Profile

2-METHYLCYCLOHEXANOL is an alcohol. Flammable and/or toxic gases are generated by the combination of these materials with alkali metals, nitrides, and strong reducing agents. Contact with strong oxidizers may cause fires and explosions. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. They exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. Special Hazards of Combustion Products: Irritating vapors and toxic gases, such as carbon monoxide, may be formed when involved in fire (USCG, 1999).

Purification Methods

Dry 2-methylcyclohexanol with Na2SO4 and fractionate it under vacuum. Note: The cis-isomer has b 165o/760mm, and the trans-isomer has b 166.5o/760mm. [Eliel & Haber J Org Chem 23 2041 1958, Beilstein 6 III 61, 6 IV 100.]

2-Methylcyclohexanol Preparation Products And Raw materials

Raw materials

Preparation Products

1-METHYL-1-CYCLOHEXANECARBOXYLIC ACID

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583-59-5

583-59-3

583595

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