ChemicalBook > CAS DataBase List > (S)-1-(3-BROMOPHENYL)ETHANOL

(S)-1-(3-BROMOPHENYL)ETHANOL

Product Name
(S)-1-(3-BROMOPHENYL)ETHANOL
CAS No.
134615-22-8
Chemical Name
(S)-1-(3-BROMOPHENYL)ETHANOL
Synonyms
(S)-1-(3-Bromophenyl)ethano;(S)-1-(3-BROMOPHENYL)ETHANOL;(-)-1-(3-Bromophenyl)ethanol;(1S)-1-(3-Bromophenyl)ethanol;(S)-3-Bromo-α-methylbenzyl alcohol;(S)-α-Methyl-3-bromobenzyl alcohol;(S)-α-Methyl-3-bromobenzenemethanol;(S)-3-Bromo-my-methylbenzyl alcohol;(S)-3-BROMO-ALPHA-METHYLBENZYL ALCOHOL;Benzenemethanol, 3-bromo-α-methyl-, (αS)-
CBNumber
CB8731601
Molecular Formula
C8H9BrO
Formula Weight
201.06
MOL File
134615-22-8.mol
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(S)-1-(3-BROMOPHENYL)ETHANOL Property

Boiling point:
264℃
Density 
1.470
Flash point:
114℃
storage temp. 
2-8°C
form 
Liquid
pka
14.35±0.20(Predicted)
color 
Clear colorless
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
36/37/39-26
HS Code 
29062900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
B999045
Product name
(S)-1-(3-Bromophenyl)ethanol
Packaging
100mg
Price
$65
Updated
2021/12/16
TRC
Product number
B999045
Product name
(S)-1-(3-Bromophenyl)ethanol
Packaging
50mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB64817
Product name
3-Bromo-a-methylbenzyl alcohol
Packaging
250mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB64817
Product name
3-Bromo-a-methylbenzyl alcohol
Packaging
500mg
Price
$110
Updated
2021/12/16
AK Scientific
Product number
6219AA
Product name
(S)-1-(3-Bromophenyl)ethanol
Packaging
250mg
Price
$147
Updated
2021/12/16
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(S)-1-(3-BROMOPHENYL)ETHANOL Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Synthesis

2142-63-4

52780-14-0

134615-22-8

General procedure for the synthesis of 1-(3-bromophenyl)ethanol and (S)-1-(3-bromophenyl)ethanol from 3'-bromoacetophenone: under dry argon protection, the catalyst [0.4 mol% (complexes 12-22) or 0.2 mol% (dinuclear complex 24)] and 3'-bromoacetophenone (2.5 mmol) were added to a three necked Schlenk flask. The mixture was stirred at 82 °C for 15 min before adding 5 mL of a 0.06 M solution of base (Cs2CO3) in 2-propanol (0.3 mmol). The reaction progress was monitored by an HP-6890 gas chromatograph. In all reactions, only the corresponding alcohols and ketones were detected as products. Conversion rates and enantiomeric excess values (e.e. values) were determined by gas chromatography using a Supelco β-DEX 120 chiral capillary column.

References

[1] Molecular Catalysis, 2018, vol. 456, p. 75 - 86
[2] Tetrahedron Letters, 2018, vol. 59, # 8, p. 719 - 722
[3] Angewandte Chemie, 1995, vol. 107, # 18, p. 2165 - 2166
[4] Angewandte Chemie, 1995, vol. 107, # 18, p. 2165 - 2166
[5] Journal of Organometallic Chemistry, 1997, vol. 547, # 1, p. 97 - 101

(S)-1-(3-BROMOPHENYL)ETHANOL Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-1-(3-BROMOPHENYL)ETHANOL Suppliers

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View Lastest Price from (S)-1-(3-BROMOPHENYL)ETHANOL manufacturers

Career Henan Chemical Co
Product
(S)-1-(3-BROMOPHENYL)ETHANOL 134615-22-8
Price
US $9.80/KG
Min. Order
1g
Purity
≥99%
Supply Ability
100kg
Release date
2020-01-12

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