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Silicon nitride

Description References
Product Name
Silicon nitride
CAS No.
12033-89-5
Chemical Name
Silicon nitride
Synonyms
Si3N4 SILICON NITRIDE;silicon(iv) nitride, electronic grade;E 05;E 10;β-Si3N4;α-Si3N4;SI3N4 B7;SI3N4 M11;ALPHA HYDROXY;E 05 (nitride)
CBNumber
CB8744847
Molecular Formula
N4Si3
Formula Weight
140.2833
MOL File
12033-89-5.mol
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Silicon nitride Property

Melting point:
1900 °C
Density 
3.44 g/mL at 25 °C (lit.)
RTECS 
VW0650000
refractive index 
2.8
form 
powder
color 
Pale gray
Specific Gravity
3.44
Resistivity
10*6 (ρ/μΩ.cm)
Water Solubility 
Insoluble water.
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
Crystal Structure
Hexagonal
Merck 
14,8497
Stability:
Stable.
CAS DataBase Reference
12033-89-5(CAS DataBase Reference)
EPA Substance Registry System
Silicon nitride (Si3N4) (12033-89-5)
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Safety

Hazard Codes 
Xi
Risk Statements 
37
Safety Statements 
22-24/25
WGK Germany 
3
10
TSCA 
Yes
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
NISTRM8983
Product name
Silicon nitride
Purity
NIST? RM 8983
Packaging
4.5G
Price
$1130
Updated
2024/03/01
Sigma-Aldrich
Product number
NIST1900
Product name
Silicon nitride powder - specific surface area standard
Purity
NIST? SRM? 1900
Packaging
4g
Price
$743
Updated
2024/03/01
Sigma-Aldrich
Product number
GF99991300
Product name
Silicon nitride
Purity
powder, weight 200?g, 10 max. part. size (micron), condition alpha si3n4 (85% minimum)
Packaging
1EA
Price
$381
Updated
2024/03/01
Sigma-Aldrich
Product number
248622
Product name
Silicon nitride
Purity
predominantly β-phase, ≤10micron primary particle size
Packaging
100g
Price
$108
Updated
2024/03/01
Sigma-Aldrich
Product number
248622
Product name
Silicon nitride
Purity
predominantly β-phase, ≤10micron primary particle size
Packaging
500g
Price
$434
Updated
2024/03/01
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Silicon nitride Chemical Properties,Usage,Production

Description

Silicon nitride (molecular formula Si3N4) is a kind of chemical compound comprised of both silicon and nitrogen elements. It appears as a white solid with a high melting point. It is chemically stable upon the presence of dilute HF and hot H2SO4. It has a series of properties such as high strength among a wide temperature range, high fracture toughness, high hardness, outstanding wear resistance and chemical property. It has a strikingly high thermal shock resistance. It has a wide applications in various kinds of fields. In automobile industry, it is an important materials for engine parts. It can also be applied to the manufacturing of bearings due to its high shock resistance. For example, in spacecraft, silicon nitride ceramic is capable of surviving the severe thermal shock generated in the hydrogen/oxygen rocket engines. It can also be used as abrasive and cutting tools due to its harness and resistance to wear. In electronics, it can be used as an insulator and chemical barrier during the production of integrated circuits. There are several method for the manufacturing the silicon nitride. 1. The powdered silicon is subject to a heating reaction of 1300-1400 °C in the atmosphere of nitrogen. 2 Diimide route which involves the reaction of SiCl and NH3. 3 Silicon dioxide is subject to carbothemral reduction at 1300-1400 °C under the presence of nitrogen.

References

https://en.wikipedia.org/wiki/Silicon_nitride
http://accuratus.com/silinit.html

Chemical Properties

slightly beige powder

Physical properties

Gray amorphous powder or crystals. Resistant to thermal shock. Good oxidation resistance up to 1500°C but decomposes into nitrogen and silicon above 1850°C. Excellent corrosion resistance to molten nonferrous metals such as Al, Pb, Zn, Cd, Bi, Rb, and Sn, and molten salts like NaCl-KCl, NaF, and silicate glasses. However, corroded by molten Mg, Ti, V, Cr, Fe, and Co, cryolite, KOH, and Na2 O.

Uses

As high tempereture engineering material for use in gas turbines, diesel engines.

Uses

Silicon nitride (Si3N4), resistant to oxidation, is an excellent coating for metals, as well as an adhesive and abrasive, and it is used in high-temperature crucibles. It has proven useful as heat-resistant substance for the nozzles on rocket engines.

Uses

Silicon Nitride is used in preparation of thermal conductive Poly(Me Methacrylate)/Silicon Nitride nanocomposites via click chemistry.

General Description

Silicon nitride based ceramics possess high fracture toughness, hardness and wear resistance, resistance to corrosion, thermal stability. Two known polymorphs of silicon nitride exist, alpha and beta Si3N4, both have hexagonal structure. A study shows that a third state, cubic spinel structure, has also been synthesized.

Flammability and Explosibility

Non flammable

Silicon nitride Preparation Products And Raw materials

Raw materials

Preparation Products

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Silicon nitride Suppliers

ZHEJIANG YAMEI NANO TECHNOLOGY CO., LTD.
Tel
400-8200386 13456373028
Fax
0573-84615678
Email
2533928531@qq.com
Country
China
ProdList
321
Advantage
58
Anhui Kerun Nano Technology Co., Ltd.
Tel
0564-3636590 15956460423
Email
623125725@qq.com
Country
China
ProdList
185
Advantage
58
Ningbo Luofei Nanotechnology Co. , Ltd.
Tel
400-8809926 18958272021
Email
2943541784@qq.com
Country
China
ProdList
140
Advantage
58
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Shanghai Liantian Material Technology Co., Ltd.
Tel
021-1337006-6691 13370066691
Email
3692356620@qq.com
Country
China
ProdList
139
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
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View Lastest Price from Silicon nitride manufacturers

Hebei Andu Technology Com.,Ltd
Product
Silicon nitride 12033-89-5
Price
US $3.60/kg
Min. Order
1kg
Purity
≥99%
Supply Ability
3000tons/month
Release date
2024-07-30
Sense Chemicals (Shanghai) Co., Ltd.
Product
Silicon nitride 12033-89-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton/month
Release date
2022-10-17
henan kanbei chemical co.,ltd
Product
Silicon nitride 12033-89-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-26

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