9-phenylanthracene
- Product Name
- 9-phenylanthracene
- CAS No.
- 602-55-1
- Chemical Name
- 9-phenylanthracene
- Synonyms
- NSC 90796;9-phenylantracene;9-PHENYLANTHRACENE;Phenylanthracene,98%;anthracene,9-phenyl-;9-Phenylanthracene97%;9-Phenylanthracene>9-Phenylanthracene,98%;9-Phenylanthracene 97%;9-PHENYLANTHRACENE OEKANAL
- CBNumber
- CB8778824
- Molecular Formula
- C20H14
- Formula Weight
- 254.33
- MOL File
- 602-55-1.mol
9-phenylanthracene Property
- Melting point:
- 153-155 °C (lit.)
- Boiling point:
- 417 °C (lit.)
- Density
- 1.1180 (estimate)
- refractive index
- 1.7040 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- form
- Solid
- color
- Off-white to pale brown
- Sensitive
- Light Sensitive
- BRN
- 1910570
- CAS DataBase Reference
- 602-55-1(CAS DataBase Reference)
- EPA Substance Registry System
- Anthracene, 9-phenyl- (602-55-1)
N-Bromosuccinimide Price
- Product number
- P18004
- Product name
- 9-Phenylanthracene
- Purity
- 98%
- Packaging
- 5g
- Price
- $183.6
- Updated
- 2024/03/01
- Product number
- P18004
- Product name
- 9-Phenylanthracene
- Purity
- 98%
- Packaging
- 1g
- Price
- $86.3
- Updated
- 2023/06/20
- Product number
- P0138
- Product name
- 9-Phenylanthracene
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $113
- Updated
- 2024/03/01
- Product number
- P0138
- Product name
- 9-Phenylanthracene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $394
- Updated
- 2024/03/01
- Product number
- H64419
- Product name
- 9-Phenylanthracene, 98%
- Packaging
- 1g
- Price
- $23.8
- Updated
- 2021/12/16
9-phenylanthracene Chemical Properties,Usage,Production
Chemical Properties
Pale Yellow Plates
Uses
9-Phenylanthracene is used to synthesize organic light-emitting material intermediates.
Preparation
The synthesis of 9-phenylanthracene involved mixing phenylboronic acid (2.13 g, 17.49 mmol), 9-bromoanthracene (3 g, 11.66 mmol), Pd(PPh3)4 (140 mg, 0.12 mmol), K2CO3 (16 mL, 2 M), and ethanol (8 mL) in a 100 mL flask with anhydrous toluene (32 mL). The mixture was refluxed for 48 h under nitrogen. After cooled to room temperature, the reaction mixture was quenched with dilute hydrochloric acid solution and extracted with CH2Cl2. The organic extracts were dried over anhydrous MgSO4 and concentrated by rotary evaporation. The crude product was further purified by silica gel column chromatography (CH2Cl2/petroleum ether (1:4,v/v)) to get a white powder (2.43 g, 81.9 %). 1H NMR (500 MHz, CDCl3) δ 8.53 (s, 1H), 8.08 (d, J = 8.5 Hz, 2H), 7.70 – 7.67 (m, 2H), 7.63 – 7.54 (m, 3H), 7.50 – 7.45 (m, 4H), 7.37 (ddd, J = 8.7, 6.5, 1.2 Hz, 2H). EI-MS (m/z): Calculated for C20H14: 254.33. Found [M+]: 253.02.
Synthesis of 9-phenylanthracene
Synthesis Reference(s)
Journal of the American Chemical Society, 79, p. 393, 1957 DOI: 10.1021/ja01559a042
Purification Methods
Chromatograph it on alumina in *C6H6 and recrystallise it from AcOH or toluene. [Beilstein 5 H 725, 5 II 639, 5 III 2462.]
9-phenylanthracene Preparation Products And Raw materials
Raw materials
Preparation Products
9-phenylanthracene Suppliers
- Tel
- --
- Fax
- --
- info@acros.com
- Country
- Belgium
- ProdList
- 6772
- Advantage
- 81
View Lastest Price from 9-phenylanthracene manufacturers
- Product
- 9-phenylanthracene 602-55-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-04-07
- Product
- 9-Phenylanthracene 602-55-1
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1000KG
- Release date
- 2024-11-10
- Product
- 9-PHENYLANTHRACENE 602-55-1
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.00%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-16