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BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE

Product Name
BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE
CAS No.
5074-71-5
Chemical Name
BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE
Synonyms
DFTPP;DECAFLUOROTRIPHENYLPHOSPHINE;Bis(pentafL;MASSMARK 443;ULTRAMARK 443;dftpp solution;SPECTRASYNQ 443;DFTPP, 100MG, NEAT;* Ultramark (TM) 443;DFTPP@50 μg/mL in Acetone
CBNumber
CB9102288
Molecular Formula
C18H5F10P
Formula Weight
442.19
MOL File
5074-71-5.mol
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BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Property

Melting point:
55-60 °C (lit.)
Boiling point:
105°C/0.3mm
Flash point:
>230 °F
storage temp. 
room temp
solubility 
Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.
form 
Powder
color 
white
Sensitive 
air sensitive
BRN 
6253897
CAS DataBase Reference
5074-71-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn,T,F
Risk Statements 
36/37/38-20/21/22-40-63-43-23/24/25-45-67-66-36/38-11-36
Safety Statements 
26-36/37/39-22-36/37-24/25-23-53-16-9
RIDADR 
UN 1593 6.1/PG 3
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
No
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
47941
Product name
DFTPP solution
Purity
certified reference material, 1000?μg/mL in acetone
Packaging
1mL
Price
$41.9
Updated
2024/03/01
Sigma-Aldrich
Product number
442543
Product name
Decafluorotriphenylphosphine
Purity
analytical standard
Packaging
100mg
Price
$33.84
Updated
2024/03/01
Sigma-Aldrich
Product number
48724-U
Product name
Decafluorotriphenylphosphine solution
Purity
certified reference material, 25?mg/mL in dichloromethane
Packaging
1mL
Price
$64.5
Updated
2022/05/15
Sigma-Aldrich
Product number
48082
Product name
Decafluorotriphenylphosphine solution
Purity
certified reference material, 2000?μg/mL in dichloromethane
Packaging
1mL
Price
$36
Updated
2022/05/15
TCI Chemical
Product number
B4560
Product name
Bis(pentafluorophenyl)phenylphosphine
Purity
>98.0%(GC)
Packaging
200mg
Price
$59
Updated
2024/03/01
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BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.

General Description

Decafluorotriphenylphosphine (DFTPP) is commonly used as a check standard for the calibration of mass spectrum detector (MSD) prior to the analysis of samples under investigation.

BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Preparation Products And Raw materials

Raw materials

Preparation Products

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BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Suppliers

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  • 5074-71-5
  • C6H5PC6F52
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  • Catalysis and Inorganic Chemistry
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