ChemicalBook > CAS DataBase List > Ethyl 3-methyl-3-phenylglycidate

Ethyl 3-methyl-3-phenylglycidate

Product Name
Ethyl 3-methyl-3-phenylglycidate
CAS No.
77-83-8
Chemical Name
Ethyl 3-methyl-3-phenylglycidate
Synonyms
ALDEHYDE C-16;Strawberry;ETHYL METHYL PHENYL GLYCIDATE;FEMA 2444;ETHYL 2,3-EPOXY-3-PHENYLBUTYRATE;Fraeseol;c-16aldehyde;bayberry aldehyde;STRAWBERRY ALDEHYDE;2,3-epoxy-3-phenyl-butanoicaciethylester
CBNumber
CB9126747
Molecular Formula
C12H14O3
Formula Weight
206.24
MOL File
77-83-8.mol
More
Less

Ethyl 3-methyl-3-phenylglycidate Property

Boiling point:
272-275 °C(lit.)
Density 
1.087 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.505(lit.)
FEMA 
2444 | ETHYL METHYLPHENYLGLYCIDATE
Flash point:
>230 °F
storage temp. 
2-8°C
form 
clear liquid
color 
Colorless to Light orange to Yellow
Odor
at 100.00 %. sweet fruity strawberry floral honey fatty
Odor Type
fruity
biological source
synthetic
JECFA Number
1577
BRN 
12299
LogP
2.43
CAS DataBase Reference
77-83-8(CAS DataBase Reference)
NIST Chemistry Reference
Glycidic acid, 3-methyl-3-phenyl, ethyl ester(77-83-8)
EPA Substance Registry System
Ethyl methylphenylglycidate (77-83-8)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
10-36/37/38
Safety Statements 
16-26-36/37/39
RIDADR 
UN 1993 3/PG 3
WGK Germany 
2
RTECS 
MW5250000
TSCA 
Yes
HS Code 
29189090
Hazardous Substances Data
77-83-8(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 5470 mg/kg
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W244406
Product name
Ethyl 3-methyl-3-phenylglycidate
Purity
≥98%, FCC, FG
Packaging
sample-k
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W244406
Product name
Ethyl 3-methyl-3-phenylglycidate
Purity
≥98%, FCC, FG
Packaging
1kg
Price
$81.1
Updated
2024/03/01
Sigma-Aldrich
Product number
W244406
Product name
Ethyl 3-methyl-3-phenylglycidate
Purity
≥98%, FCC, FG
Packaging
5kg
Price
$311
Updated
2024/03/01
Sigma-Aldrich
Product number
W244406
Product name
Ethyl 3-methyl-3-phenylglycidate
Purity
≥98%, FCC, FG
Packaging
10Kg
Price
$373
Updated
2023/06/20
Sigma-Aldrich
Product number
W244406
Product name
Ethyl 3-methyl-3-phenylglycidate
Purity
≥98%,FCC,FG
Packaging
1SAMPLE-K
Price
$50
Updated
2021/12/16
More
Less

Ethyl 3-methyl-3-phenylglycidate Chemical Properties,Usage,Production

Chemical Properties

clear yellow liquid

Chemical Properties

Ethyl 3-Methyl-3-phenylglycidate exists as two optically active pairs of cis- and trans-isomers; each isomer has a characteristic odor . The commercial product is a racemic mixture of all four isomers and has a strong, sweetish, strawberry odor. The cis/trans ratio obtained in the Darzens condensation of acetophenone (R==CH3) and ethyl chloroacetate depends on the base used in the reaction.

Chemical Properties

Ethyl methylphenylglycidate on dilution has a strong fruity odor suggestive of strawberry. It has a characteristic, slightly acid taste reminiscent of strawberry.

Chemical Properties

Perennial, herbaceous plant; grows wild or cultivated in central–southern Europe, North America and Asia. The plant grows 10 to 20 cm (4 to 8 in.) in height and has thick rhizomes; radical leaves with long, small, white flowers blossoming from April to July; and fleshy, ovoidal, red berries covered with numerous achenes. The only part used is the berries. Strawberry has a sweet–sour taste and a characteristic odor.

Occurrence

Has apparently not been reported to occur in nature.

Uses

Ethyl 3-Methyl-3-phenylglycidate, also known as “strawberry aldehyde”, is commonly used in the flavor industry for artificial fruit flavors, in particular strawberry.

Uses

Perfumery, flavors.

Uses

Ethyl 3-methyl-3-phenylglycidate is a synthetic flavoring agent that is a glycidic acid ester. It is a colorless to pale yellow liquid with a strong fruit odor suggestive of strawberries. It is unstable to alkali and moderately stable to weak organic acids. It should be stored in glass, tin, or aluminum containers. It is soluble in fixed oils and in propylene glycol. It is used in flavors for strawberry note and has application in candy, beverages, and ice cream at 6–20 ppm. It is also termed aldehyde c-16.

Preparation

By reaction of acetophenone and the ethyl ester of monochloroacetic acid in the presence of an alkaline condensing agent.

Definition

ChEBI: Phenylmethylglycidic ester is a carboxylic acid and an epoxide.

Composition

Strawberry aroma has been the subject of extensive investigation. Several components have been identified, of which only 7% appear to be responsible for the aroma. Strawberry aroma varies widely with the strawberry variety. The most valuable part, aroma, is from wild strawberry.

Aroma threshold values

Detection: 2 ppm

Taste threshold values

Taste characteristics at 1 and 5% sucrose: sweet, ripe, strawberry jam and preserve notes.

Taste threshold values

Taste characteristics at 50 ppm: sweet, berry, strawberry, fruity, tutti-frutti and floral nuances

General Description

Clear, colorless to yellowish liquid with a strawberry-like odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Esters, such as Ethyl 3-methyl-3-phenylglycidate, react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Fire Hazard

Ethyl 3-methyl-3-phenylglycidate is probably combustible.

Trade name

Strawberry pure (Givaudan)

Safety Profile

Mddly toxic by ingestion. Mutation data reported. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALDEHYDES.

Synthesis

Ethyl 3-methyl-3-phenylglycidate is synthesized by Acetophenone by condensation with Ethyl monochloroacetate in an alkaline solution, using sodium as a condensing agent.

Solubility in organics

Poorly soluble in Propylene glycol, Glycerin and mineral oil, soluble in alcohol, miscible with most perfume and flavor oils.

Ethyl 3-methyl-3-phenylglycidate Preparation Products And Raw materials

Raw materials

Xylene Acetophenone Sodium ethoxide Propiophenone Sodium amide Ethyl chloroacetate

Preparation Products

More
Less

Ethyl 3-methyl-3-phenylglycidate Suppliers

Americas 1 Australia 1 Belgium 1 China 233 Europe 5 France 2 Germany 10 India 27 Italy 1 Japan 5 Singapore 2 Slovakia 1 Spain 2 Switzerland 2 The Netherlands 1 United Kingdom 10 United States 71 Global 375
BOC Sciences
Tel
1-631-485-4226; 16314854226
Email
info@bocsci.com
Country
United States
ProdList
14055
Advantage
65
Alfa Chemistry
Tel
Fax
1-516-927-0118
Email
Info@alfa-chemistry.com
Country
United States
ProdList
24072
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Global Essence USA, Inc.
Tel
--
Fax
--
Email
info@globalessence.com
Country
United States
ProdList
540
Advantage
58
Riverside Aromatics Ltd.
Tel
--
Fax
--
Email
info@riversidearomatics.com
Country
United States
ProdList
275
Advantage
58
PearlChem Corporation
Tel
--
Fax
--
Email
info@pearlchemcorp.com
Country
United States
ProdList
131
Advantage
58
Frutarom (F&F Ingredients)
Tel
--
Fax
--
Email
info@frutarom.com
Country
United States
ProdList
280
Advantage
58
Citrus and Allied Essences Ltd.
Tel
--
Fax
--
Email
galloca@citrusandallied.com
Country
United States
ProdList
90
Advantage
58
H.Interdonati inc.
Tel
--
Fax
--
Email
flavorplus@aol.com
Country
United States
ProdList
105
Advantage
58
Augustus Oils Ltd
Tel
--
Fax
--
Email
essentials@augustus-oils.ltd.uk
Country
United States
ProdList
1404
Advantage
58
Taytonn ASCC Pte Ltd
Tel
--
Fax
--
Email
info@taytonnascc.com
Country
United States
ProdList
742
Advantage
58
Lluch Essence S.L.
Tel
--
Fax
--
Email
web@lluche.com
Country
United States
ProdList
2352
Advantage
58
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
Ungerer & Company
Tel
--
Fax
--
Email
cowens@UngererAndCompany.com
Country
United States
ProdList
79
Advantage
58
Garuda Chemicals
Tel
--
Fax
--
Email
manufacturing@garudachem.com
Country
United States
ProdList
70
Advantage
56
Elan Chemical Inc.
Tel
--
Fax
--
Email
sales@elan-chemical.com
Country
United States
ProdList
114
Advantage
65
H.Interdonati, Inc. & FlavorPlus Division
Tel
--
Fax
--
Country
United States
ProdList
25
Advantage
58
Vigon International, Inc.
Tel
--
Fax
--
Email
jpassamonte@vigoninternational.com
Country
United States
ProdList
1268
Advantage
64
United States Biological
Tel
--
Fax
--
Email
chemicals@usbio.net
Country
United States
ProdList
6214
Advantage
80
Vigon International
Tel
--
Fax
--
Email
sales@vigon.com
Country
United States
ProdList
1776
Advantage
58
The Good Scents Company
Tel
--
Fax
--
Email
goodscnt@thegoodscentscompany.com
Country
United States
ProdList
160
Advantage
58
Sunaux International
Tel
--
Fax
--
Email
johnjft@sunaux.com
Country
United States
ProdList
581
Advantage
58
Berje Inc.
Tel
--
Fax
--
Email
tlauzurica@berjeinc.com
Country
United States
ProdList
958
Advantage
58
Global Essence Inc.
Tel
--
Fax
--
Email
info@globalessenceuk.com
Country
United States
ProdList
758
Advantage
58
R C Treatt and Co Ltd
Tel
--
Fax
--
Email
enquiries@treatt.com
Country
United States
ProdList
1690
Advantage
58
H. Interdonati, Inc.
Tel
--
Fax
--
Email
flavorplus@hinterdonati.com
Country
United States
ProdList
261
Advantage
58
Prodasynth
Tel
--
Fax
--
Email
info@prodasynth.com
Country
United States
ProdList
423
Advantage
58
ACS International GmbH
Tel
--
Fax
--
Email
info@acsint.com
Country
United States
ProdList
214
Advantage
58
The Lermond Company
Tel
--
Fax
--
Email
info@lermond.com
Country
United States
ProdList
763
Advantage
58
The John D. Walsh Company, Inc
Tel
--
Fax
--
Email
info@johndwalsh.com
Country
United States
ProdList
1139
Advantage
58
Elan Inc.
Tel
--
Fax
--
Email
dpimentel@elan-chemical.com
Country
United States
ProdList
116
Advantage
58
Pyrazine Specialties, Inc.
Tel
--
Fax
--
Country
United States
ProdList
1265
Advantage
30
Fleurchem, Inc.
Tel
--
Fax
--
Email
info@fleurchem.com
Country
United States
ProdList
790
Advantage
58
Azelis UK Ltd.
Tel
--
Fax
--
Email
fi@azelis.co.uk
Country
United States
ProdList
822
Advantage
58
Ernesto Ventós S.A.
Tel
--
Fax
--
Email
info@ventos.com
Country
United States
ProdList
2257
Advantage
58
ECSA Chemicals
Tel
--
Fax
--
Email
marketing@ecsa.ch
Country
United States
ProdList
1735
Advantage
58
Ultra International Limited
Tel
--
Fax
--
Email
ultra@ultrainternational.com
Country
United States
ProdList
473
Advantage
58
Beijing Lys Chemicals Co, LTD.
Tel
--
Fax
--
Email
jiayanyong@lyschem.com
Country
United States
ProdList
710
Advantage
58
Penta International Corporation
Tel
--
Fax
--
Email
lisaa@pentamfg.com
Country
United States
ProdList
5042
Advantage
58
Indukern, S.A. F&F Ingredients Division
Tel
--
Fax
--
Email
info@indukern.es
Country
United States
ProdList
1321
Advantage
58
OQEMA
Tel
--
Fax
--
Email
fandf@oqema.co.uk
Country
United States
ProdList
578
Advantage
58
Moellhausen S.P.A.
Tel
--
Fax
--
Country
United States
ProdList
1676
Advantage
58
M&U International LLC
Tel
--
Fax
--
Email
sales@mu-intel.com
Country
United States
ProdList
2011
Advantage
58
PerfumersWorld Ltd.
Tel
--
Fax
--
Email
pwenquiries@perfumersworld.com
Country
United States
ProdList
723
Advantage
58
WholeChem, LLC
Tel
--
Fax
--
Email
info@wholechem.com
Country
United States
ProdList
814
Advantage
58
Pell Wall Perfumes
Tel
--
Fax
--
Email
//pellwall.com/contact-us/
Country
United States
ProdList
559
Advantage
58
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
Frontier Scientific, Inc.
Tel
--
Fax
--
Email
sales@frontiersci.com
Country
United States
ProdList
6222
Advantage
86
More
Less

View Lastest Price from Ethyl 3-methyl-3-phenylglycidate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Ethyl 3-Methyl-3-Phenylglycidate 77-83-8
Price
US $99.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-14
Hebei Mujin Biotechnology Co.,Ltd
Product
Ethyl 3-methyl-3-phenylglycidate 77-83-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-04
Hebei Mujin Biotechnology Co.,Ltd
Product
Ethyl 3-methyl-3-phenylglycidate 77-83-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-24

77-83-8, Ethyl 3-methyl-3-phenylglycidateRelated Search:

Chlorodimethylphenylsilane Methyl acrylate Benzyl bromide Benzyltrimethylammonium chloride Tri(o-tolyl)phosphine Ethyl 3,3-dimethylacrylate Basic Violet 1 Glycidyl phenyl ether Methylparaben Benzyltriethylammonium chloride Ethyl butyrate Benzyl chloride Methanol Acetonitrile Ethyl oleate Ethyl isobutyrate Silicone oil (high temperature) Paraquat dichloride

  • 2,3-epoxy-3-phenyl-butanoicaciethylester
  • 2,3-Epoxy-3-phenylbutyric acid, ethyl ester
  • 3-methyl-3-phenyl-oxiranecarboxylicacid,ethylester
  • 3-methyl-3-phenyl-oxiranecarboxylicacidethylester
  • 3-methyl-3-phenyl-oxiranecarboxylicaciethylester
  • alpha,beta-Epoxy-beta-methylhydrocinnamic acid, ethyl ester
  • alpha,beta-epoxy-beta-methylhydrocinnamicacid,ethylester
  • alpha,beta-epoxy-beta-methyl-hydrocinnamicaciethylester
  • c-16aldehyde
  • EMPG
  • Ethyl 2,3-epoxy-3-methyl-3-phenylpropionate
  • Ethyl 3-methyl-3-phenyl-2-oxiranecarboxylate
  • Ethyl alpha,beta-epoxy-beta-methylhydrocinnamate
  • Ethyl ester of 2,3-epoxy-3-phenylbutanoic acid
  • ethyl2,3-epoxy-3-methyl-3-phenylpropionate
  • ethyl3-methyl-3-phenylglycidate,mixtureofcisandtrans
  • ethylalpha,beta-epoxy-beta-methylhydrocinnamate
  • ethylalpha,beta-epoxy-beta-methylphenylpropionate
  • 3-Methyl-3-phenyl glycidic acid ethyl ester
  • ETHYL 3-METHYL-3-PHENYLGLYCIDATE 98+% &
  • Strawberry
  • Ethyl α,β-epoxy-β-methylhydrocinnamate
  • α,β-Epoxy-β-methylhydrocinnamic acid, ethyl ester
  • ETHYL 2,3-EPOXY-3-PHENYLBUTYRATE
  • ETHYL 3-METHYL-3-PHENYLGLYCIDATE
  • ETHYL 3-METHYL-2,3-EPOXY-HYDROCINAMIC ACID
  • ETHYL 3-PHENYL-2,3-EPOXYBUTYRATE
  • ETHYL METHYL PHENYL GLYCIDATE
  • ETHYL-A B-EPOXY-B-METHYLHYDROCINNAMATE
  • ETHYL BETA-METHYL-BETA-PHENYLGLYCIDATE
  • FEMA 2444
  • GLYCIDIC ACID, 3-METHYL-3-PHENYL:ETHYL ESTER
  • 3-phenyl-2,3-epoxybutyic acid ethyl ester
  • ethyl 3-methyl-3-phenylglycidate, cis + trans
  • ALDEHYD C 16 SOG. ERDBEER
  • Ethyl 2,3-epoxy-3-phenylbutyrat
  • ETHYL 3-METHYL-3-PHENYLGLYCIDATE, 98%, MIXTURE OF CIS AND TRANS
  • 3-Phenyl-2,3-epoxybutyric acid ethyl ester
  • Ethyl 3-methyl-3-phenylglycidate,Aldehyde C-16
  • Ethyl 3-Methyl-3-phenylglycidate (Mixture of isoMers)
  • (2S,3R)-3-methyl-3-phenyl-2-oxiranecarboxylic acid ethyl ester
  • 3-methyl-3-phenylglycidate
  • ethylbeta-methylphenylglycidate
  • ethylesterof2,3-epoxy-3-phenylbutanoicacid
  • Fraeseol
  • Hydrocinnamic acid, alpha,beta-epoxy-beta-methyl-, ethyl ester
  • hydrocinnamicacid,α,β-epoxy-β-methyl-,ethylester
  • methyl-3phenyl-3glycidated’ethyle
  • Oxiranecarboxylic acid, 3-methyl-3-phenyl-, ethyl ester
  • Oxiranecarboxylicacid,3-methyl-3-phenyl-,ethylester
  • STRAWBERRY ALDEHYDE
  • 3-Methyl-3-phenylglycidic Acid Ethyl Ester Ethyl 2,3-Epoxy-3-phenylbutyrate 2,3-Epoxy-3-phenylbutyric Acid Ethyl Ester
  • ETHYL 2,3-EPOXY-3-PHENYLBUTYRATE FOR SYN
  • bayberry aldehyde
  • ALDEHYDE C-16
  • ethyl 3-Methyl-3-phenyloxirane-2-carboxylate
  • Yang Meiquan
  • 2-Oxiranecarboxylicacid, 3-Methyl-3-phenyl-, ethyl ester