ChemicalBook > CAS DataBase List > 3-Pyridinemethanamine,6-fluoro-(9CI)

3-Pyridinemethanamine,6-fluoro-(9CI)

Product Name
3-Pyridinemethanamine,6-fluoro-(9CI)
CAS No.
205744-17-8
Chemical Name
3-Pyridinemethanamine,6-fluoro-(9CI)
Synonyms
(6-Fluoropyridin-3-yl);2-fluoro-5-pyridylmethylamine;6-Fluoro-3-pyridineMethanaMine;3-Pyridinemethanamine, 6-fluoro-;3-(Aminomethyl)-6-fluoropyridine;2-fluoro-5-(aminomethyl)pyridine;5-(Aminomethyl)-2-fluoropyridine;3-Pyridinemethanamine,6-fluoro-(9CI)
CBNumber
CB91300803
Molecular Formula
C6H7FN2
Formula Weight
126.13
MOL File
205744-17-8.mol
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3-Pyridinemethanamine,6-fluoro-(9CI) Property

Boiling point:
63-65 °C(Press: 0.56 Torr)
Density 
1.180±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
7.73±0.29(Predicted)
Appearance
Colorless to light yellow Liquid
InChI
InChI=1S/C6H7FN2/c7-6-2-1-5(3-8)4-9-6/h1-2,4H,3,8H2
InChIKey
KYRWSLUCAPNJPI-UHFFFAOYSA-N
SMILES
C1=NC(F)=CC=C1CN
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Safety

HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC
Product number
F598268
Product name
6-Fluoro-3-pyridinemethanamine
Packaging
100mg
Price
$110
Updated
2021/12/16
Apolloscientific
Product number
PC403115
Product name
(6-Fluoropyridin-3-yl)methylamine
Packaging
250mg
Price
$99
Updated
2021/12/16
SynQuest Laboratories
Product number
3H30-3-3V
Product name
(6-Fluoropyridin-3-yl)methanamine
Packaging
250mg
Price
$159
Updated
2021/12/16
Apolloscientific
Product number
PC403115
Product name
(6-Fluoropyridin-3-yl)methylamine
Packaging
1g
Price
$247
Updated
2021/12/16
SynQuest Laboratories
Product number
3H30-3-3V
Product name
(6-Fluoropyridin-3-yl)methanamine
Packaging
1g
Price
$396
Updated
2021/12/16
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3-Pyridinemethanamine,6-fluoro-(9CI) Chemical Properties,Usage,Production

Uses

6-Fluoro-3-pyridinemethanamine is a useful compound for the study of herbicidal activity of 2-cyano-3-[[(6-fluoro-3-pyridinyl)methyl]amino]acrylates.

Synthesis

3939-12-6

205744-17-8

General procedure for the synthesis of (6-fluoropyridin-3-yl)methanamine from 6-fluoro-3-cyanopyridine: 6-fluoro-3-cyanopyridine (300 mg, 2.46 mmol) was dissolved in 2 mol/L ammonia/methanol solution (30 mL), nickel Ruanne (0.5 g) was added at room temperature and the reaction was carried out for 12 h under hydrogen atmosphere. Upon completion of the reaction, the reaction mixture was filtered through diatomaceous earth and washed with methanol (5 mL x 2). The filtrate was concentrated to dryness and the residue was purified by silica gel column chromatography (eluent ratio of dichloromethane: methanol = 100:4) to give 262 mg of yellow oily solid in 85% yield.

References

[1] Patent: CN106916101, 2017, A. Location in patent: Paragraph 0149; 0150
[2] Journal of Medicinal Chemistry, 2017, vol. 60, # 19, p. 7965 - 7983

3-Pyridinemethanamine,6-fluoro-(9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-Pyridinemethanamine,6-fluoro-(9CI) manufacturers

Career Henan Chemical Co
Product
3-Pyridinemethanamine,6-fluoro-(9CI) 205744-17-8
Price
US $2.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
ask
Release date
2020-01-08

205744-17-8, 3-Pyridinemethanamine,6-fluoro-(9CI)Related Search:

A77 1726 2-FLUORO-5-METHYLPYRIDINE-3-BORONIC ACID PINACOL ESTER Pyridine, 2-fluoro-5-methoxy- (9CI) 2-Fluoro-5-((3-oxoisobenzofuran-1(3H)-ylidene)methyl)benzonitrile 2-Fluoro-5-iodobenzonitrile 5-BROMO-2-FLUORONICOTINIC ACID 2-Fluoro-5-iodonitrobenzene 2-Fluoro-5-Iodoaniline 2-CHLORO-9-(6-FLUOROPYRIDIN-3YLMETHYL)ADENINE 3-Pyridinecarboxamide,6-fluoro-(9CI) RARECHEM AL BW 1079

  • (6-Fluoropyridin-3-yl)
  • 5-(Aminomethyl)-2-fluoropyridine
  • 3-Pyridinemethanamine,6-fluoro-(9CI)
  • 6-Fluoro-3-pyridineMethanaMine
  • 2-fluoro-5-(aminomethyl)pyridine
  • 3-(Aminomethyl)-6-fluoropyridine
  • 3-Pyridinemethanamine, 6-fluoro-
  • 2-fluoro-5-pyridylmethylamine
  • 205744-17-8
  • PYRIDINE