NICKELOCENE
- Product Name
- NICKELOCENE
- CAS No.
- 1271-28-9
- Chemical Name
- NICKELOCENE
- Synonyms
- Nickelocene,99%;BIS(CYCLOPENTADIENYL)NICKEL;di(cyclopenta-1,3-dien-1-yl)nickel;bis(B7;Nikelocen;NICKELOCENE;Nickelocene>Nickelocene(NiCp2);nickelbiscyclopentadiene;DI(CYCLOPENTADIENYL)NICKEL
- CBNumber
- CB9136861
- Molecular Formula
- C10H10Ni10*
- Formula Weight
- 188.88
- MOL File
- 1271-28-9.mol
NICKELOCENE Property
- Melting point:
- 171-173 °C(lit.)
- storage temp.
- 2-8°C
- Water Solubility
- Insoluble in water
- form
- crystal
- color
- dark green
- Sensitive
- Air & Moisture Sensitive
- CAS DataBase Reference
- 1271-28-9(CAS DataBase Reference)
- NIST Chemistry Reference
- Nickelocene(1271-28-9)
- EPA Substance Registry System
- Nickelocene (1271-28-9)
Safety
- Hazard Codes
- F,T
- Risk Statements
- 49-11-22-43
- Safety Statements
- 53-36/37/39-45
- RIDADR
- UN 1325 4.1/PG 2
- WGK Germany
- 3
- RTECS
- QR6500000
- F
- 10-23
- TSCA
- Yes
- HazardClass
- 4.2
- PackingGroup
- I
- HS Code
- 29319090
- Toxicity
- mouse,LD50,intraperitoneal,86mg/kg (86mg/kg),Proceedings of the Western Pharmacology Society. Vol. 11, Pg. 39, 1968.
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H228Flammable solid
H302Harmful if swallowed
H317May cause an allergic skin reaction
H350May cause cancer
- Precautionary statements
-
P201Obtain special instructions before use.
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- N7524
- Product name
- Bis(cyclopentadienyl)nickel(II)
- Packaging
- 5g
- Price
- $71.6
- Updated
- 2024/03/01
- Product number
- D1574
- Product name
- Nickelocene
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $52
- Updated
- 2024/03/01
- Product number
- D1574
- Product name
- Nickelocene
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $147
- Updated
- 2024/03/01
- Product number
- 087899
- Product name
- Bis(cyclopentadienyl)nickel, dry
- Packaging
- 2g
- Price
- $44
- Updated
- 2024/03/01
- Product number
- 087899
- Product name
- Bis(cyclopentadienyl)nickel, dry
- Packaging
- 50g
- Price
- $301.65
- Updated
- 2024/03/01
NICKELOCENE Chemical Properties,Usage,Production
Chemical Properties
GREEN TO DARK GREEN CRYSTALS OR CRYST. POWDER
Chemical Properties
Nickelocene is a solid crystalline substance of dark green color, insoluble in water or carbon tetrachloride, slightly soluble in alcohol and liquid ammonia, and readily soluble in nonpolar organic solvents.
Uses
Nickelocene is obtained through reacting nickel halides with sodium cyclopentadienide. It is used as a catalyst or as a complexing agent.
Uses
This metal alkyl may be used to synthesize hybrid organic-inorganic polymeric molecular layer deposition (MLD). Bis(cyclopentadienyl) nickel (Cp 2 Ni) may be used as a Ni precursor for the atomic layer deposition (ALD) of NiO/carbon nanotubes hybrids.
Uses
Catalyst, complexing agent.
General Description
Dark liquid in an 8-10% solution in toluene. Insoluble in water.
Air & Water Reactions
Highly flammable. The neat material is sensitive to air. . Insoluble in water.
Reactivity Profile
Organometallics, such as NICKELOCENE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases.
Hazard
Toxic by inhalation and skin contact, a carcinogen (OSHA).
Health Hazard
ACUTE/CHRONIC HAZARDS: NICKELOCENE can be absorbed through the skin.
Fire Hazard
NICKELOCENE is flammable.
Safety Profile
Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal and intramuscular routes. Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL COMPOUNDS.
Purification Methods
Dissolve the complex in Et2O, filter and evaporate in a vacuum. Purify it rapidly by recrystallisation from pet ether using a solid CO2/Me2CO bath, m 171-173o(in an evacuated tube). Also purify it by vacuum sublimation. [Wilkinson et al. J Am Chem Soc 76 1970 1954, Beilstein 16 IV 1831.]
NICKELOCENE Preparation Products And Raw materials
Raw materials
Preparation Products
NICKELOCENE Suppliers
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View Lastest Price from NICKELOCENE manufacturers
- Product
- NICKELOCENE 1271-28-9
- Price
- US $7.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2018-12-16